Preparative synthesis of palladium(II) acetate: Reactions, intermediates, and by-products |
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Authors: | I. P. Stolyarov L. I. Demina N. V. Cherkashina |
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Affiliation: | 1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia
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Abstract: | ![]() Comparison of various laboratory procedures for the synthesis of palladium acetate demonstrated that the purest product containing no nitrite or nitrate impurities is formed in up to 90% yields upon the reaction of palladium nitrate with alkali metal acetates in aqueous acetic acid. Other laboratory syntheses are more labor-consuming and do not ensure high purity of the product. The synthesis by-products are described and possible reaction schemes are proposed. |
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