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Template-directed intramolecular C-glycosidation. cation-mediated synthesis of ketooxetanes from thioglycosides
Authors:Donald Craig   V. Ranjit N. Munasinghe   Jason P. Tierney   Andrew J. P. White   David J. Williams  Christopher Williamson
Affiliation:

a Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, U.K.

b Glaxo Wellcome Research and Development, Temple Hill, Dartford, Kent DA1 5AH, U.K.

Abstract:Bicyclic ketooxetanes may be assembled using cation-mediated cyclisation reactions of thioglycosides possessing silyl enol ether-containing side-chains.
Keywords:C-Glycoside   cyclisation   ketooxetane   stereoselective
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