Statistical model for combustion of high-metal magnesium-based hydro-reactive fuel

<正>We investigate experimentally and analytically the combustion behavior of a high-metal magnesium-based hydroreactive fuel under high temperature gaseous atmosphere.The fuel studied in this paper contains 73%magnesium powders.An experimental system is designed and experiments are carried out in both argon and water vapor atmospheres. It is found that the burning surface temperature of the fuel is higher in water vapor than that in argon and both of them are higher than the melting point of magnesium,which indicates the molten state of magnesium particles in the burning surface of the fuel.Based on physical considerations and experimental results,a mathematical one-dimensional model is formulated to describe the combustion behavior of the high-metal magnesium-based hydro-reactive fuel.The model enables the evaluation of the burning surface temperature,the burning rate and the flame standoff distance each as a function of chamber pressure and water vapor concentration.The results predicted by the model show that the burning rate and the surface temperature increase when the chamber pressure and the water vapor concentration increase,which are in agreement with the observed experimental trends.     

二醋酸纤维吸附—超临界流体脱附法研究代替乙炔用金属切割气组成

提出了以二醋酸纤维为吸附剂吸附石油气基质金属切割气中的添加剂,用超临界流体抽提吸附质,用气相色谱衣气相色谱－质谱联用分析的方法,研究了石油基质金属切割气的组成,模拟配制金属切割气样品经实际验证切割性能优于乙炔气。     

电化学石英晶体微天平研究六氰亚铁铜膜修饰电极及其离子效应

利用电化学石英晶体微天平（EQCM）手段，结合循环伏安法．计时电流法对六氰亚铁铜（CuHCF)膜修饰电极及其在不同水溶液中的离子交换机制进行了研究。结果表明；通过循环伏安法，在Pt电极上可以牢固地形成CuHCF膜．在氧化还原过程中，不仅是阳离子，阴离子也参与了在CuHCF膜中的传输。     

受压U形截面柱的塑性后分叉

对压缩到塑性阶段的简支Ｕ形截面柱，本文详细讨论了对应于最低分叉截荷的非对称初始后分叉问题。在分析中考虑了弹性卸载对两条不同后分叉路径的影响，求出了两种不同初始后分叉的载荷与分叉模态值之间的渐近关系式，并求出了渐近展开式中的高阶项。     

AN IMPLICIT SERIES PRECISE INTEGRATION ALGORITHM FOR STRUCTURAL NONLINEAR DYNAMIC EQUATIONS

Nonlinear dynamic equations can be solved accurately using a precise integration method. Some algorithms exist, but the inversion of a matrix must be calculated for these algorithms. If the inversion of the matrix doesn‘t exist or isn‘t stable, the precision and stability of the algorithms will be affected. An explicit series solution of the state equation has been presented. The solution avoids calculating the inversion of a matrix and its precision can be easily controlled. In this paper, an implicit series solution of nonlinear dynamic equations is presented.The algorithm is more precise and stable than the explicit series solution and isn‘t sensitive to the time-step. Finally, a numerical example is presented to demonstrate the effectiveness of the algorithm.     

L-抗坏血酸电喷雾串联质谱行为研究

采用电喷雾串联质谱(ESI-MSn)技术, 结合氢/氘交换方法, 研究了L-抗坏血酸在正、负离子模式下的质谱行为. 实验表明, 电喷雾质谱能够方便地观测到实验条件下L-抗坏血酸的特征裂解方式和相应碎片; 实验发现毛细管温度对L-抗坏血酸的裂解方式产生显著的影响, 从不同毛细管温度下的相应质谱信号强度变化能观察到L-抗坏血酸及其降解产物的热稳定性差异. 因此, 根据串联质谱所观测到的L-抗坏血酸特征碎片离子, 提出了L-抗坏血酸的结构变化及其降解反应的可能机理和基本规律, 为现代质谱技术快速测定复杂基体样品中的痕量抗坏血酸奠定了实验基础.     

拉伸半无限圆孔板的应力集中系数表达式

首次推出拉伸半无限圆孔板孔边最大应力集中系数的显式表达式,此式不但形式简单而且具有良好的精度,目前献中尚无类似表达式。同时指出,Jeffery给出的仅有的几个具体理论值在圆孔比较靠近直线边界时误差较大。此外,采用本新定义的应力集中系数,当圆孔非常靠近直线边界时有一个极限值。