Evolution and properties of antiphase boundaries in silicate minerals

Experimental and observational evidence is reviewed for the mechanisms and kinetics of antiphase domain coarsening in silicate minerals. The expected rate law has the form (domain size)ⁿ ≈ annealing time, but the ideal value of n=2 has been observed in only one of three cases. Values of n≈8 or 10 are interpreted as implying adsorption of impurity atoms onto the antiphase boundaries. Diffusion of these impurities can then provide the rate determining step for boundary migration. Local ordering at the boundaries can also provide some stabilising influence, though this does not appear to affect the coarsening rate law. If the stabilisation is sufficient it might result in the development of an incommensurate superstructure, either as a stable phase or as a metastable phase under non-equilibrium conditions. The effective width of these boundaries appears to be ～ 25°, or approximately two unit cells, and their maximum effective interaction length appears to be ～ 4 times this width.     

An approach of dynamic mesh adaptation for simulating 3‐dimensional unsteady moving‐immersed‐boundary flows

In this paper, we present an approach of dynamic mesh adaptation for simulating complex 3‐dimensional incompressible moving‐boundary flows by immersed boundary methods. Tetrahedral meshes are adapted by a hierarchical refining/coarsening algorithm. Regular refinement is accomplished by dividing 1 tetrahedron into 8 subcells, and irregular refinement is only for eliminating the hanging points. Merging the 8 subcells obtained by regular refinement, the mesh is coarsened. With hierarchical refining/coarsening, mesh adaptivity can be achieved by adjusting the mesh only 1 time for each adaptation period. The level difference between 2 neighboring cells never exceeds 1, and the geometrical quality of mesh does not degrade as the level of adaptive mesh increases. A predictor‐corrector scheme is introduced to eliminate the phase lag between adapted mesh and unsteady solution. The error caused by each solution transferring from the old mesh to the new adapted one is small because most of the nodes on the 2 meshes are coincident. An immersed boundary method named local domain‐free discretization is employed to solve the flow equations. Several numerical experiments have been conducted for 3‐dimensional incompressible moving‐boundary flows. By using the present approach, the number of mesh nodes is reduced greatly while the accuracy of solution can be preserved.     

Evolution of helium bubbles in nickel-based alloy by post-implantation annealing

Nickel-based alloys have been considered as candidate structural materials used in generation IV nuclear reactors serving at high temperatures. In the present study, alloy 617 was irradiated with 180-keV helium ions to a fluence of 3.6×10¹⁷ ions/cm² at room temperature. Throughout the cross-section transmission electron microscopy (TEM) image, numerous over-pressurized helium bubbles in spherical shape are observed with the actual concentration profile a little deeper than the SRIM predicted result. Post-implantation annealing was conducted at 700 ℃ for 2 h to investigate the bubble evolution. The long-range migration of helium bubbles occurred during the annealing process, which makes the bubbles of the peak region transform into a faceted shape as well. Then the coarsening mechanism of helium bubbles at different depths is discussed and related to the migration and coalescence (MC) mechanism. With the diffusion of nickel atoms slowed down by the alloy elements, the migration and coalescence of bubbles are suppressed in alloy 617, leading to a better helium irradiation resistance.     

A discrete model of Ostwald ripening based on multiple pairwise interactions

A discrete multi-particle model of Ostwald ripening based on direct pairwise interactions is developed for particles with incoherent interfaces as an alternative to the classical LSW mean field theory. The rate of matter exchange depends on the average surface-to-surface interparticle distance, a characteristic feature of the system which naturally incorporates the effect of volume fraction of second phase. The multi-particle diffusion is described through the definition of an interaction volume containing all the particles involved in the exchange of solute. At small volume fractions this is proportional to the size of the central particle, at higher volume fractions it gradually reduces as a consequence of diffusion screening described on a geometrical basis. The topological noise present in real systems is also included. For volume fractions below about 0.1 the model predicts broad and right-skewed stationary size distributions resembling a lognormal function. Above this value, a transition to sharper, more symmetrical but still right-skewed shapes occurs. An excellent agreement with experiments is obtained for 3D particle size distributions of solid–solid and solid–liquid systems with volume fraction 0.07, 0.30, 0.52 and 0.74. The kinetic constant of the model depends on the cube root of volume fraction up to about 0.1, then increases rapidly with an upward concavity. It is in good agreement with the available literature data on solid–liquid mixtures in the volume fraction range from 0.20 to about 0.75.     

Linguistic modelling and information coarsening based on prototype theory and label semantics

The theory of prototypes provides a new semantic interpretation of vague concepts. In particular, the calculus derived from this interpretation results in the same calculus as label semantics proposed by Lawry. In the theory of prototypes, each basic linguistic label L has the form ‘about P’, where P is a set of prototypes of L and the neighborhood size of the underlying concept is described by the word ‘about’ which represents a probability density function δ on [0,+∞). In this paper we propose an approach to vague information coarsening based on the theory of prototypes. Moreover, we propose a framework for linguistic modelling within the theory of prototypes, in which the rules are concise and transparent. We then present a linguistic rule induction method from training data based on information coarsening and data clustering. Finally, we apply this linguistic modelling method to some benchmark time series prediction problems, which show that our linguistic modelling and information coarsening methods are potentially powerful tools for linguistic modelling and uncertain reasoning.     

粗化过程中颗粒界面形状演化的三维多相场法研究

利用多相场模型对液-固两相体系中固相颗粒的粗化过程进行了三维模拟,对粗化过程中的界面形状分布进行了统计分析,研究了不同固相体积分数下颗粒连接状态对界面形状演化及粗化速率的影响.模拟结果表明:当颗粒间存在大量连接时,粗化速率随固相分数的变化速率比颗粒无连接时变缓,且随着粗化进行,高曲率的双曲形界面所占比例不断降低,低曲率的椭球形界面所占比例逐渐增多;无论固相颗粒间是否发生连接,界面形状演化经历一定阶段后,三维界面形状分布均呈现自相似性,但随着固相体积分数的增加,界面形状分布呈现自相似性所需的时间延长.     

Structural evolution of cylindrical‐phase diblock copolymer thin films

We have measured the time evolution of the self‐assembly process in perpendicular‐oriented cylindrical‐phase diblock copolymer thin films using statistical analysis of high‐resolution scanning electron microscope (SEM) images. Within minutes of annealing above the polymer glass‐transition temperature, microphase separation between polymer blocks results in formation of uniform nanometer‐scale domains whose relative position is initially largely uncorrelated. On further annealing, the cylindrical polymer domains organize into a two‐dimensional hexagonal lattice whose characteristic grain size increases slowly with time (～t^1/4). © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1970–1975, 2004     

The Becker–Döring Equations and the Lifshitz–Slyozov Theory of Coarsening

In this paper the relation between the kinetic set of Becker–Döring (BD) equations and the classical Lifshitz–Slyozov (LS) theory of coarsening is studied. A model that resembles the LS theory but keeps some of the nucleation effects is derived. For this model a solution is described that shows how the kinetic effects explain the particular solution selected in the LS theory. By means of a renormalization procedure, a discrete group of transformations is shown to play an important role in describing the structure of the solution near the critical size of the LS theory.     

Possible stretched exponential parametrization for humidity absorption in polymers

Polymer thin films have irregular transient current characteristics under constant voltage. In hydrophilic and hydrophobic polymers, the irregularity is also known to depend on the humidity absorbed by the polymer sample. Different stretched exponential models are studied and it is shown that the absorption of humidity as a function of time can be adequately modelled by a class of these stretched exponential absorption models.