全文获取类型
收费全文 | 657篇 |
免费 | 20篇 |
国内免费 | 75篇 |
专业分类
化学 | 210篇 |
晶体学 | 2篇 |
力学 | 128篇 |
综合类 | 1篇 |
数学 | 77篇 |
物理学 | 334篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 23篇 |
2021年 | 25篇 |
2020年 | 19篇 |
2019年 | 24篇 |
2018年 | 26篇 |
2017年 | 22篇 |
2016年 | 22篇 |
2015年 | 39篇 |
2014年 | 50篇 |
2013年 | 48篇 |
2012年 | 44篇 |
2011年 | 34篇 |
2010年 | 30篇 |
2009年 | 43篇 |
2008年 | 41篇 |
2007年 | 45篇 |
2006年 | 31篇 |
2005年 | 21篇 |
2004年 | 19篇 |
2003年 | 8篇 |
2002年 | 21篇 |
2001年 | 6篇 |
2000年 | 9篇 |
1999年 | 11篇 |
1998年 | 7篇 |
1997年 | 8篇 |
1996年 | 5篇 |
1995年 | 7篇 |
1994年 | 8篇 |
1993年 | 4篇 |
1992年 | 10篇 |
1991年 | 13篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 9篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1982年 | 2篇 |
排序方式: 共有752条查询结果,搜索用时 31 毫秒
1.
D.W. Mueller JrA.L. Crosbie 《Journal of Quantitative Spectroscopy & Radiative Transfer》2002,74(1):43-68
Three-dimensional radiative transfer in an anisotropic scattering medium exposed to spatially varying, collimated radiation is studied. The generalized reflection function for a semi-infinite medium with a very general scattering phase function is the focus of this investigation. An integral transform is used to reduce the three-dimensional transport equation to a one-dimensional form, and a modified Ambarzumian's method is applied to formulate a nonlinear integral equation for the generalized reflection function. The integration is over both the polar and azimuthal angles; hence, the integral equation is said to be in the double-integral form. The double-integral, reflection function formulation can handle a variety of anisotropic phase functions and does not require an expansion of the phase function in a Legendre polynomial series. Complicated kernel transformations of previous single-integral studies are eliminated. Single and double scattering approximations are developed. Numerical results are presented for a Rayleigh phase function to illustrate the computational characteristics of the method and are compared to results obtained with the single-integral method. Agreement between the two approaches is excellent; however, as the transform variable increases beyond five the number of quadrature points required for the double-integral method to produce accurate solutions significantly increases. A new interpolation scheme produces accurate results when the transform variable is large. 相似文献
2.
WANG Wen zhen * LIU Xin MENG Yi LIAO Dai zheng * JIANG Zong hui YAN Shi ping WANG Geng lin . Department of Chemistry Nankai University Tianjin P. R. China . State Key Laboratory of Coordination Chemistry Nanjing University Nanjijng P. R. China 《高等学校化学研究》2003,19(1)
IntroductionFive- coordinated complexes with d9- configuredcations have received much attention stereochemi-cally,spectrochemically and biologically,and havebeen comprehensively discussed[1] . Usually thereare two stable configurations for the copper( )complexes with five equal coordinating atoms:anapically elongated square pyramid( SP) and a com-pressed trigonal bipyramid( TBP) ,with an obviousenergetic preference for the latter coordination.When the ligands are rigid and provide angular d… 相似文献
3.
In this paper we show that the Boltzmann weights of the three-dimensional Baxter-Bazhanov model give representations of the braid group if some suitable spectral limits are taken. In the trigonometric case we classify all possible spectral limits which produce braid group representations. Furthermore, we prove that for some of them we get cyclotomic invariants of links and for others we obtain tangle invariants generalizing the cyclotomic ones. 相似文献
4.
Calibration of the relationship between height and phase is of uttermost importance to perform accurate 3D measurements in phase measurement profilometry. This work reports a different approach to this problem by first looking at the analytical expression for this relationship and determining the regime spanned by the fringe analysis method. The conclusions thus ascertained, amply justify confronting the analytical expression with a simple normalization procedure of the experimental data, with a remarkable matching between both results. In light of this, a linear calibration procedure with just one plane is proposed and verified experimentally. 相似文献
5.
In this paper, the authors present airflow field characteristics of human upper airway and soft palate movement attitude during
breathing. On the basis of the data taken from the spiral computerized tomography images of a healthy person and a patient
with Obstructive Sleep Apnea-Hypopnea Syndrome (OSAHS), three-dimensional models of upper airway cavity and soft palate are
reconstructed by the method of surface rendering. Numerical simulation is performed for airflow in the upper airway and displacement
of soft palate by fluid-structure interaction analysis. The reconstructed three-dimensional models precisely preserve the
original configuration of upper airways and soft palate. The results of the pressure and velocity distributions in the airflow
field are quantitatively determined, and the displacement of soft palate is presented. Pressure gradients of airway are lower
for the healthy person and the airflow distribution is quite uniform in the case of free breathing. However, the OSAHS patient
remarkably escalates both the pressure and velocity in the upper airway, and causes higher displacement of the soft palate.
The present study is useful in revealing pathogenesis and quantitative mutual relationship between configuration and function
of the upper airway as well as in diagnosing diseases related to anatomical structure and function of the upper airway.
The project supported by the National Natural Science Foundation of China (10672036, 10472025 and 10421002), the Natural Science
Foundation of Liaoning Province (20032109).
English text was polished by Yunming Chen. 相似文献
6.
This paper addresses the problem of determining stowage plans for containers in a ship, that is the so-called master bay plan problem (MBPP). 相似文献
7.
三线性直接分解法分析高维灰色体系 总被引:1,自引:1,他引:1
对于由多个两维测量数据组成的三维阵,本文提出一种新三线性直接分解方法。采用高维PCA分解,从三维阵中直接提取抽象光谱和抽象浓度,再结合QZ算法,唯一地确定混合物中各组分光谱的浓度。该方法可以排除其它未知组分的干扰,适用于高维灰色体系定性定量分析和多点校准。用模拟数据讨论了光谱分离度对该方法的影响,应用于混合维生素B1、B2和B6的荧光分析,求得的光谱和浓度与实验值吻合很好。 相似文献
8.
三维有序大孔杂化材料SiW11O39^8——SiO2和γ—SiW10O36^8——SiO2的制备与表征 总被引:2,自引:1,他引:2
通过溶胶 -凝胶和聚苯乙烯模板等方法制备了含缺位 Keggin阴离子 Si W1 1 O8- 3 9和 γ-Si W1 0 O8- 3 6的三维有序大孔杂化氧化硅复合材料 ,并通过紫外漫反射光谱 ( UV/ DRS)、傅里叶变换红外光谱 ( FTIR)、固体核磁共振波谱 ( MAS NMR)等手段对其结构进行了表征 .结果表明 ,杂化材料中的 Keggin阴离子仍保留其基本骨架结构 ,但其与氧化硅基体之间存在化学作用 .杂化材料的孔道结构用扫描和透射电子显微镜 ( SEM和TEM)进行表征 ,其平均孔径为 ( 335± 5 0 ) nm.对杂化材料孔壁的微孔性通过氮气吸附进行了测定 .此类材料对水溶液中羟基丁二酸的降解反应具有活性 ,光催化过程中未发现 Keggin阴离子自载体中脱落的现象 . 相似文献
9.
YUAN Ji-xin XIONG Jing 《高等学校化学研究》2007,23(2):123-126
Introduction Recently, several efforts have been made for thestudy of coordination polymers assembled from lantha-nide ions and aromatic polycarboxylate ligands becauseof their intriguing structural diversity and potentialapplications in several fields, s… 相似文献
10.
Yong WANG 《数学年刊B辑(英文版)》2022,43(3):443-458
In this paper, the author computes canonical connections and KobayashiNomizu connections and their curvature on three-dimensional Lorentzian Lie groups with some product structure. He defines algebraic Ricci solitons associated to canonical connections and Kobayashi-Nomizu connections. He classifies algebraic Ricci solitons associated to canonical connections and Kobayashi-Nomizu connections on three-dimensional Lorentzian Lie groups with some product structure. 相似文献