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利用差示扫描量热仪(Pyrid-Diamond DSC),研究乙二醇(EG)和丙三醇水溶液加入0.1%、0.5%质量分数,20nm、40nm、60nm粒径的HA纳米微粒后的过冷度、水合性质,分析HA纳米微粒对线性多元醇水溶液这些特性的影响。实验表明,纳米微粒加入后,线性多元醇水溶液过冷度显著降低,并随纳米微粒粒径增大而减小。水合实验的结果表明,HA纳米微粒对多元醇水溶液的水合性质影响显著,与未加入HA纳米微粒的线性多元醇溶液相比,纳米低温保护剂结晶焓降低,结合水含量增大。 相似文献
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A differential scanning calorimeter was used to study the thermal behaviors of polyalcohols aqueous solutions, such as supercooling degree of heterogeneous nucleating temperature, hydration properties. The experimental results show that the variation of supercooling and hydration behavior does not have obvious rules at the low concentrations. However, the supercooling degree and the content of unfrozen water increased with the solution concentration at the high concentrations. The difference of hydration properties shows the important effects of function groups (methyl groups and hydroxyl groups). 相似文献
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