Nano-Ni粉体对Fe/WC涂层组织和性能的影响

在Fe/WC喷涂材料中添加不同量的Nano-Ni粉体,采用亚音速火焰喷涂技术在Q235基体上制备涂层,利用光学显微镜、扫描电子显微镜、X射线衍射仪等设备进行显微组织、表面形貌观察及物相分析,利用MM-W1磨损试验机和HXD-1000TM型显微硬度仪对涂层的性能进行测试.结果表明:Nano-Ni粉体可以细化涂层组织,提高涂层的致密性,随着Nano-Ni粉体添加量的增大,相应的力学性能均得到提高,在涂层形成过程中Nano-Ni粉体与喷涂材料中的其他成分形成了一些新相,如Fe-Ni固溶体和CeNi3,这些新相为改善涂层组织和提高涂层的力学性能起到积极作用.     

十六烷基膦酸表面修饰纳米镍粉及其复合材料的制备和性能

以十六烷基膦酸作为修饰剂, 对纳米镍粉进行表面改性处理, 通过溶液共混的方法制备改性镍粉与聚丙烯的聚合物基复合材料. 利用X射线光电子能谱(XPS)、 X射线衍射(XRD)及透射电子显微镜(TEM)等测试手段研究改性镍粉的表面形态; 利用扫描电子显微镜(SEM)研究复合材料断面形貌; 利用介电频谱分析系统对复合材料的介电常数和介电损耗等进行了测试. 结果表明, 纳米镍粉表面形成厚度为2~4 nm的十六烷基膦酸包覆层, 使纳米镍粉由亲水性变为亲油性; 聚丙烯基复合材料中, 改性镍粉均匀分散; 复合材料的介电常数在镍填充量为40%时, 可以达到纯聚丙烯的近10倍.     

Preparation and magnetic properties of nano-Ni coated cenosphere composites

Ni coated cenosphere composites are successfully fabricated by heterogeneous precipitation method using metal salts, ammonium hydro-carbonate and cenospheres as the raw materials. The cenosphere particles are characterized by scanning electron microscope (SEM)/energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and vibrating sample magnetometer (VSM) during and after the coating process. All results show that relatively uniform, smooth and compact Ni layer has been successfully coated onto cenospheres under the given conditions, furthermore, the nanometer Ni crystallite has a face-centered cubic structure. Magnetic property of Ni coated cenosphere composites can be adjusted by controlling the synthesis conditions and content of magnetic metal. The low density Ni coated cenosphere composites may be utilized for electromagnetic wave shielding and microwave absorbing materials.