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1.
Manfred Müller 《辐射效应与固体损伤》2013,168(2):147-161
Abstract X-ray energy spectra induced by 1 MeV protons and the energy spectra of the backscattered protons have been examined in the <100> and <110> directions of Ni crystals containing 1 at.% Si. The channeling method was used to investigate interactions between the radiation-induced defects and the silicon atoms. From the measured minimum yields and from the shape of the angular scans the fraction of silicon atoms is determined, which are displaced into the <100> and <110> channels due to proton or helium irradiations and subsequent annealing treatments. In undamaged crystals about 98 % of the silicon atoms are on normal lattice sites. After irradiation a dose dependent fraction of the silicon atoms is displaced 0.05 nm away from the substitutional position indicating the formation of a mixed dumbbell consisting of one selfinterstitial atom and one silicon atom. However, the experimental data can also be interpreted by the assumption of a NiSi2 complex, in which the silicon atoms are displaced 0.08 nm from the lattice site. Subsequent annealing from 50 K to 160 K does not change the configuration and the concentration of the silicon complexes. At room temperature the silicon atoms in the complex are positioned 0.04 nm from the lattice position. The silicon complexes were totally am ihilated at 400 K. 相似文献
2.
Spatial competition facility location models: Definition,formulation and solution approach 总被引:2,自引:0,他引:2
Models are presented for locating a firm's production facilities and determining production levels at these facilities so as to maximize the firm's profit. These models take into account the changes in price at each of the spatially separated markets that would result from the increase in supply provided by the new facilities and also from the response of competing firms. Two different models of spatial competition are presented to represent the competitive market situation in which the firm's production facilities are being located. These models are formulated as variational inequalities; recent sensitivity analysis results for variational inequalities are used to develop derivatives of the prices at each of the spatially separated markets with respect to the production levels at each of the new facilities. These derivatives are used to develop a linear approximation of the implicit function relating prices to productions. A heuristic solution procedure making use of this approximation is proposed. 相似文献
3.
Two methods are proposed, one for the location of saddle points and one for the calculation of steepest-descent paths on multidimensional surfaces. Both methods are based on a constrained simplex optimization technique that avoids the evaluation of gradients or second derivative matrices. Three chemical reactions of increasing structural complexity are studied within the PRDDO SCF approximation. Predicted properties of reaction hypersurfaces are in good overall agreement with those determined by gradient minimization and gradient following algorithms in connection with various ab initio SCF methods. Computational efforts required by the new procedures are discussed. 相似文献
4.
单链四苯酚基卟啉在CTAB胶束微环境中的去质子化现象 总被引:4,自引:1,他引:4
叶绿素分子的光能转化功能的实现与其聚集状态、所处微环境性质及条件密切相关[1,2].如何设计控制叶琳类分子在膜介质中的增溶位置,对于研究叶琳在膜体系中的跨膜电子传递、光能转化过程具有重要意义.本文研究了长链双亲卟啉──单链四苯酚基叶琳THPPH2在CTAB胶束中的去质子化,该过程能控制叶琳环在胶束中的增溶位置,使其由内核转移到胶束表面.1实验部分1·1仪器和测试条件岛津UV-240型紫外可见光谱仪(带有恒温夹套),狭缝宽2nm,石英池厚1cm,所用试剂皆为分析纯.UV光谱测试均在恒温条件下进行.1.2溶液的配制含一个十六… 相似文献
5.
运用量子化学密度泛函B3LYP方法,在6-311++G(d,p)基组水平上对邻位和间位取代1-氯葸醌的分子内卤键进行了研究.用电子定域函数和“分子中的原子,,理论对分子内卤键的性质进行了电子密度拓扑分析.通过对计算得到的密度矩阵进行σ-π兀分离,得到了π-键的键径和分子图,并讨论了。电荷密度和兀电荷密度对卤键的影响.结果表明,键鞍点和环鞍点处的电子密度拓扑性质均可作为衡量分子内卤键强度的量度.键鞍点和环鞍点处的电荷密度P越大,键鞍点与环鞍点的距离越大,卤键强度越大.除σ电荷密度外,π电荷密度对分子内卤键的性质也有明显影响. 相似文献
6.
Masakatsu Shintomi Yuuichi Tazuke Haruyuki Takahashi 《Molecular Crystals and Liquid Crystals》2013,570(2):27-32
Abstract Magnetic and neutron studies are done about iron-intercalated titanium diselenide, FexTiSe2 with 0<x≤0.5. A neutron diffraction measurement shows that Fe-atoms are located between neighboring selenium layers. Magnetic measurements show that FexTiSe2 are spin glasses for 0. 15≤x≤0.22 and antiferromagnets for 0.25≤x≤0.5. T-x magnetic phase diagram is determined. This diagram is slightly different from that determined by Huntley et al. The difference may be caused by a formation of Fe-clusters in their samples. The x-dependence of the parameters of paramagnetic susceptibilities is determined. 相似文献
7.
Solving the phase problem remains central to crystallographic structure determination. A six‐dimensional search method of molecular replacement (FSEARCH) can be used to locate a low‐resolution molecular envelope determined from small‐angle X‐ray scattering (SAXS) within the crystallographic unit cell. This method has now been applied using the higher‐resolution envelope provided by combining SAXS and WAXS (wide‐angle X‐ray scattering) data. The method was tested on horse hemoglobin, using the most probable model selected from a set of a dozen bead models constructed from SAXS/WAXS data using the program GASBOR at 5 Å resolution (qmax = 1.25 Å−1) to phase a set of single‐crystal diffraction data. It was found that inclusion of WAXS data is essential for correctly locating the molecular envelope in the crystal unit cell, as well as for locating heavy‐atom sites. An anomalous difference map was calculated using phases out to 8 Å resolution from the correctly positioned envelope; four distinct peaks at the 3.2σ level were identified, which agree well with the four iron sites of the known structure (Protein Data Bank code 1ns9). In contrast, no peaks could be found close to the iron sites if the molecular envelope was constructed using the data from SAXS alone (qmax = 0.25 Å−1). The initial phases can be used as a starting point for a variety of phase‐extension techniques, successful application of which will result in complete phasing of a crystallographic data set and determination of the internal structure of a macromolecule to atomic resolution. It is anticipated that the combination of FSEARCH and WAXS techniques will facilitate the initial structure determination of proteins and provide a good foundation for further structure refinement. 相似文献
8.
Kazimierz Str 《Acta Crystallographica. Section A, Foundations and Advances》2007,63(6):447-454
Automatically generated orientation‐location parts, or coordinate triplets describing the geometric elements, differ frequently from the corresponding parts of the symmetry‐operation symbols listed in International Tables for Crystallography [(1983), Vol. A, Space‐Group Symmetry, edited by Th. Hahn. Dordrecht: Reidel]. An effective algorithm enabling the derivation of standard orientation‐location parts from any symmetry matrix is described and illustrated. The algorithm is based on a new concept alternative to the `invariant points of reduced operation'. First, the geometric element that corresponds to a given symmetry operation is oriented and located in a nearly convention free manner. The application of the direction indices [uvw] or Miller indices (hkl) gives a unique orientation provided the convention about the positive direction is defined. The location is fixed by the specification of a unique point on the geometric element, i.e. the point closest to the origin. Next, both results are converted into the standard orientation‐location form. The standardization step can be incorporated into other existing methods of derivation of the symmetry‐operation symbols. A number of standardization examples are given. 相似文献
9.
Philip J. Withers Mark R. Daymond Michael W. Johnson 《Journal of Applied Crystallography》2001,34(6):737-743
Much of crystallography is concerned with the accurate location of the centre of diffraction peak profiles. Simple analytical expressions are derived for estimating the precision of diffraction peak location that can be achieved for Gaussian diffraction peaks with a flat background, in terms of the standard deviation, integrated intensity and peak height (H) to background (B) ratio. Two formulations are derived using standard methods: one for the case of very low background, the other for significant backgrounds. It is found that in cases of significant background, peak position is less well determined by a factor of [1+2(21/2)B/H]1/2 compared with the case of no background. The applicability of the expression has been demonstrated by Monte Carlo simulation of Gaussian profiles and by the analysis of real data collected at a large number of neutron and synchrotron sources, largely as part of the VAMAS TWA20 project. While the solution is presented for Gaussian peak shapes, it is believed to be approximately correct for a wide range of other common diffraction peak shapes (Lorentzian, Voigtian etc.). The method is applied to the assessment of the variation in optimal measuring time as a function of the depth of the gauge volume for residual strain scanning measurements. 相似文献
10.
A tabu search procedure for multicommodity location/allocation with balancing requirements 总被引:2,自引:0,他引:2
Teodor G. Crainic Michel Gendreau Patrick Soriano Michel Toulouse 《Annals of Operations Research》1993,41(4):359-383
We propose a tabu search heuristic for the location/allocation problem with balancing requirements. This problem typically arises in the context of the medium term management of a fleet of containers of multiple types, where container depots have to be selected, the assignment of customers to depots has to be established for each type of container, and the interdepot container traffic has to be planned to account for differences in supplies and demands in various zones of the geographical territory served by a container shipping company. It is modeled as a mixed integer program, which combines zero-one location variables and a multicommodity network flow structure. Extensive computational results on a set of benchmark problems and comparisons with an efficient dual ascent procedure are reported. These show that tabu search is a competitive approach for this class of problems. 相似文献