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1.
We report the results of a comprehensive reinvestigation of the rotational spectrum of diethyl ether based on broadband millimetre-wave spectra recently recorded at The Ohio State University and in Warsaw, covering the frequency region 108-366 GHz. The data set for the ground vibrational state of trans-trans diethyl ether has been extended to over 2000 lines and improved spectroscopic constants have been determined. Rotational spectra in the first excited vibrational states of the three lowest vibrational modes of trans-trans-diethyl ether, ν20, ν39, and ν12 have been assigned. The v20 = 1 and v39 = 1 states are near 100 cm−1 in vibrational term value and are coupled by a strong c-axis Coriolis interaction, which gives rise to many spectacular manifestations in the rotational spectrum. All of these effects have been successfully fitted for a dataset comprising over 3000 transitions, leading to precise determination of the energy difference between these states, (ΔE/hc)=10.400222(5) cm−1. A newly developed software package for assignment and analysis of broadband spectra is described and made available.  相似文献   
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The ground state (ν = 0) rotational spectrum of 2-fluorobenzonitrile has been reinvestigated in the frequency range 40.0-99.0 GHz. The millimeter-wave spectrometer used is a source-modulated system combined with a free space glass cell. Millimeter-wave radiation has been produced using a Gunn diode and frequency doubler combination. High J and K−1 (J ? 49 and K−1 ? 18) transitions have been measured and accurate rotational and centrifugal distortion constants have been determined. Finally, the experimental values were compared with the corresponding values calculated at the HF/DFT-B3PW91/6-31g(d,p) level of theory. A very good agreement has been found.  相似文献   
4.
Extensive experiments on the K = 3 component of the J = 12-11 rotational transition of acetonitrile CH3C14N, located near 220.7 GHz, were performed at different temperatures in the range 235-350 K. They allow determining the N2-, H2-, and He-broadening coefficients, as well as their temperature dependences. More specific measurements on all the K-components of the involved transition perturbed by N2 at 303 K allow to point out a clear decreasing of the broadening coefficient with increasing K. Narrowing effects are clearly observed, and experimental lines were analysed both with Voigt and speed dependent Voigt profiles; but no exhaustive lineshape study was carried out. All the experimental parameters are compared with results derived from a semiclassical calculation of collisional interactions, including electrostatic, induction, and dispersion energy contributions.  相似文献   
5.
The rotational spectrum of pyruvic acid has been investigated for the first time in the millimeter-wave region, at 160-314 GHz, and also in supersonic expansion, at 10-17.4 GHz. The analysis of the broadband spectra recorded in this work was carried out with the newly developed AABS software package for Assignment and Analysis of Broadband Spectra, and precise spectroscopic constants are reported for the ground state, the first excited state of the low-frequency skeletal torsional mode ν24, and the first excited state of the methyl torsional mode ν23. Limited results have also been obtained for several higher excited states. The dataset for the ground state currently exceeds 1500 lines and for both the A and E internal rotor sublevels spans the complete range of values of Ka at the mid values of J for the measured transitions. The results were analysed with three freely available computer programs employing different strategies for dealing with internal rotation and a comparative discussion of their merits is made.  相似文献   
6.
In the method of tapering the cross section of the interaction structure for broadbanding a gyro-TWT, the different portions of the interaction length of the tapered-cross-section waveguide become effective for different frequency ranges if the magnetic field and beam parameters are profiled to maintain the condition of electron cyclotron resonance throughout the interaction length. In the present paper, the study of profiling the magnetic field and beam parameters in steps of the stepped analytical model of a double-tapered disc-loaded circular waveguide was made throughout the steps of the model. In the observed profile, the magnetic flux density in a typical step relative to its value in first-step decreases from first-step (gun-end) to end-step (collector-end) of the model considering the up-tapering schemes, in which structure parameters increase from gun-end to collector-end. Also, the transverse beam velocity in a typical step relative to its value in first-step decreases from gun-end to collector-end. However, the Larmor radius in a typical step relative to its value in first-step as well as the hollow-beam radius in a typical step relative to its value in first-step, both increase from gun-end to collector-end in the model considering the up-tapering schemes.  相似文献   
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A novel broadband millimeter-wave reflectarray antenna composed of windmill-shaped elements of variable lengths is proposed. Compared to the conventional single-layer reflectarray elements, the windmill-shaped elements can realize much larger phase variation range (over 600°), leading to broader bandwidth. Using this technique, a 15°-beam-steering reflectarray operating at 30 GHz is designed. The computed results demonstrate the agreement of the main beam steering with the design requirement, and a 1-dB gain bandwidth close to 20% is obtained. The validity of the obtained results is verified by comparing the ones generated by Ansoft High Frequency Structure Simulator (HFSS) with those produced by Ansoft Designer. The antenna is useful for millimeter-wave applications. This work was supported by the National Natural Science Foundation of China (No. 90505001), the High-Tech Research and Development Program of China (No. 2006AA01Z275), and the Creative Research Group Program of UESTC.  相似文献   
8.
The radiative transfer equation has been applied to investigate the effects of multiple scattering on communication at the millimeter wavelength in tropical rain. Horizontal linearly polarized incident waves are assumed. The scattering characteristics are calculated using the Mie theory at frequencies of 16, 34.8, 82, 140 and and at rainfall rates of 12.5, 50 and . Some results of the directional patterns of the incoherent intensities at various points in the rain medium are presented. The frequency dependence of the propagation distance, attenuation coefficient and the variation of incoherent specific intensities in tropical rainfall are investigated. The incoherent power at the receiver relative to the coherent power, which is important in assessing the quality of signal in the receiver, is also investigated. It is observed that the maximum incoherent copolarized received power is about in tropical rainfall at rainfall rate. Also the difference between the copolarized incoherent power in tropical and temperate rainfall is about at frequencies higher than , and about for the cross-polarized incoherent power components. It may therefore be safely said that multiple scattering may not result in serious degradation of the coherent wave component even in the most intense tropical precipitation. It also appears that it is independent of regional rainfall climatology.  相似文献   
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Blocking is one of the most important challenges in exploiting millimeter-wave for fifth-generation (5G) cellular communication systems. Compared to blockages caused by buildings or terrains, human body blockage exhibits a higher complexity due to the mobility and dynamic statistics of humans. To support development of outdoor millimeter-wave cellular systems, in this paper we present a novel 3D physical model of human body blockage. Based on the proposed model, the impact of human body blockage on frame-based data transmission is discussed, with respect to the system specifications and environment conditions.  相似文献   
10.
提出一种包含去模糊的空间变换区域卷积神经网络的目标检测算法.首先,基于主动毫米波圆柱扫描成像原理对人体进行三维成像(频率24~30 GHz),建立毫米波图像数据集.然后,估计毫米波图像的模糊核,通过卷积去噪网络获得图像先验知识,将其集成到半二次分裂的优化方法中,以实现非盲目去模糊.最后,由定位网络、网格生成器和采样网络三部分组成空间变换网络,将它融入到特征提取网络中,在去模糊后实现目标检测.通过该非盲目去模糊算法得到的图像的峰值信噪比可达27.49 dB,目标检测算法的平均精度可达80.9%.实验结果表明,与现有的先进方法相比,该方法可以有效地提高图像质量和检测精度,为毫米波图像中隐藏危险品的目标检测提供了新的技术支持.  相似文献   
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