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1.
This study aimed to carry out complete 1H and 13C NMR assignment of 13 protobassic acid saponins, including arganins A–C ( 1 – 3 ) and F ( 4 ), butyrosides B–D ( 5 – 7 ), tieghemelin ( 8 ), 3′-O-glucosyl-arganin C ( 9 ), Mi-saponins A–C ( 10 – 12 ), and mimusopsin ( 13 ), recorded in methanol-d4. This was accomplished by the analysis of high-resolution one-dimensional (1D) NMR (1H and 13C), two-dimensional (2D) NMR (1H–1H COSY, HSQC, and HMBC), and selectively excited 1D TOCSY spectra. Before this study, 1H and 13C NMR data of arganins A–C ( 1 – 3 ) and F ( 4 ) were partially assigned. Our effort leads to their complete assignment, especially the glycon residue, and revises some reported data. Some revisions of the 1H and 13C NMR data in the glycon part of butyroside C ( 6 ), tieghemelin ( 8 ), Mi-saponin A ( 10 ), and mimusopsin ( 13 ) were made. Those data of butyrosides B and D ( 5 & 7 ) and Mi-saponin B ( 11 ), which had not been recorded in methanol-d4, are provided. In addition, the 1H and 13C NMR data of Mi-saponin C ( 12 ) are reported for the first time. These data, being recorded in methanol-d4, should be more friendly for use as a reference for identifying the related triterpenoid saponins.  相似文献   
2.
Some 13C chemical shifts of the CHn groups in the aliphatic side chains of Im-cyt c have been determined for the first time based on the H chemical shifts of their attached protons with the aid of heteronuclear multiple-quantum coherence (HMQC) spectroscopy. Comparison of chemical shifts of these specifically assigned 13C and H resonances from Im-cyt c with those from cyt c indicates that 13C-NMR spectra may provide an opportunity to probe the electronic structure and conformational changes induced by axial ligand substitution.  相似文献   
3.
The 1H and 13C NMR resonances of twenty‐seven 2,2‐dimethyl‐5‐(2‐nitrophenyl‐5‐substituted)‐2,3‐dihydro‐1,3,4‐thiadiazoles, and twenty‐seven 3‐acyl‐5‐(2‐amino‐5‐substituted)‐2,2‐dimethyl‐2,3‐dihydro‐1,3,4‐thiadiazoles were assigned completely using the concerted application of one‐dimensional and two‐dimensional experiments (DEPT, HMQC and HMBC). NOESY experiments, X‐ray crystallography and conformational analysis confirm the preferred conformation of these compounds. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
4.
The complete 1H and 13C NMR assignment of 9 acetamidochalcones, 18 acetamidoflavones, 18 aminoflavones, 9 acetamidoflavonols and 9 aminoflavonols has been performed using one‐ and two‐dimensional NMR techniques including COSY, HMQC and HMBC experiments. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
5.
The effect of divalent cation substitution on the structure and magnetic properties of La1.2Sr1.8-xCaxMn2O7 (x = 0-0.900) is investigated in this paper. Partly replacing divalent cation Sr2+ by Ca2+ ions results in the weakening and then disappearance of long-range ferromagnetic ordering, and the formation of spin canting and low-temperature spin-glass. Based on structural analysis by Rietveld profile fitting, we suggest that this variation of magnetic property be related to a Jahn-Teller-type attice distortion of MnO6 octahedra due to the introduction of the smaller sized Ca2+ ions.  相似文献   
6.
SEPARABILITY OF SPECIFIC VOLUME IN THERMODYNAMIC EQUATION OF STATE   总被引:1,自引:0,他引:1       下载免费PDF全文
耿华运  谭华  吴强 《中国物理》2001,10(5):433-436
A type of system, in which the specific volume can be divided into several parts according to its Hamiltonian, has been obtained in a grand ensemble. The main character of such a system is that its Hamiltonian is absolutely separable. We also discuss the partial specific volume contributed by thermoelectrons in metals under a free-interaction approximation, and the corresponding Wu-Jing parameter is obtained as a simple example.  相似文献   
7.
8.
B离子掺杂TiO2催化剂(TiO2-xBx)光催化活性的研究   总被引:3,自引:0,他引:3  
采用溶胶-凝胶法制备出纳米TiO2和TiO2-xBx催化剂. 光催化实验证明, TiO2-xBx催化剂的紫外、可见光催化活性均高于TiO2. XRD, XPS和Raman结果表明, B离子是以取代式掺杂占据了TiO2的O2-的晶格位置. UV-Vis和PL谱的结果表明, B离子的2p轨道与O的2p轨道形成混合价带, 产生可见光响应, B离子的掺入有效地阻止了光生载流子的复合, 促进了其分离, 是TiO2-xBx催化剂紫外、可见光催化活性提高的主要原因.  相似文献   
9.
In this paper, new explicit and exact travelling wave solutions for a compound KdV-Burgers equation are obtained by using the hyperbola function method and the Wu elimination method, which include new solitary wave solutions and periodic solutions. Particularly important cases of the equation, such as the compound KdV, mKdV-Burgers and mKdV equations can be solved by this method. The method can also solve other nonlinear partial differential equations.  相似文献   
10.
Cobalt(III) tetramethylchiroporphyrin, CoCl(TMCP), is a useful chiral shift reagent for structure attribution, absolute configuration assignment and enantiomeric excess determination of amino acid methyl esters by 1H NMR spectroscopy. However, it has two axial sites available for amine coordination, a structural feature which generates n(n + 1)/2 diastereomeric species and n2 distinct spin systems from a mixture of n amino ester enantiomers, making the analysis of complex amino acid samples exceedingly difficult by classical 1‐D or 2‐D NMR methods when n > 3. The 1‐D TOCSY experiment is shown to be a powerful tool for the selective excitation and detection of every single component of a mixture of four amino acid methyl esters bound to CoCl(TMCP): those of(S)‐Leu, (S)‐Asp, (R)‐Asp and (S)‐Glu, for example. The potential utility of this methodology for the determination of amino acid enantiomers in carbonaceous meteorites or other extraterrestrial samples is suggested. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
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