Novel sponge-like molecularly imprinted mesoporous silica material for selective isolation of bisphenol A and its analogues from sediment extracts

Bisphenol A (BPA) imprinted sponge mesoporous silica was synthesized using a combination of semi-covalent molecular imprinting and simple self-assembly process. The molecularly imprinted sponge mesoporous silica (MISMS) material obtained was characterized by FT-IR, scanning electron microscopy, transmission electron microscopy, and nitrogen adsorption–desorption measurements. The results show that the MISMS possessed a large specific surface area (850.55 m² g⁻¹) and a highly interconnected 3-D porous network. As a result, the MISMS demonstrated a superior specific adsorption capacity of 169.22 μmol g⁻¹ and fast adsorption kinetics (reaching equilibrium within 3 min) for BPA. Good class selectivity for BPA and its analogues (bisphenol F, bisphenol B, bisphenol E and bisphenol AF) was also demonstrated by the sorption experiment. The MISMS as solid-phase extraction (SPE) material was then evaluated for isolation and clean-up of these bisphenols (BPs) from sediment samples. An accurate and sensitive analytical method based on the MISMS–SPE coupled with HPLC–DAD has been successfully established for simultaneous determination of five BPs in river sediments with detection limits of 0.43–0.71 ng g⁻¹ dry weight (dw). The recoveries of BPs for lyophilizated sediment samples at two spiking levels (50 and 500 ng g⁻¹ dw for each BP) were in the range of 75.5–105.5% with RSD values below 7.5%.     

An all-optical bit-error indicating scheme based on self-phase modulation and filtering

In this paper, a novel all-optical bit-error indicating scheme is numerically studied. The bit-error indicating function is achieved by two all-optical processing stages. Firstly, the amplified original bit stream propagates through a high-nonlinear fiber and experiences self-phase modulation which causes intensity-dependent spectrum broadening and split. And then, the bit stream output from the high-nonlinear fiber is filtered by a band-pass filter with the same central wavelength as the original bit stream to generate an error bit indicating signal. The error bit indicating signal, in which only the “Error” bits have the highest peak power, is synchronous with the delayed original bit stream. Therefore, the position of the “Error” bits in the original bit stream can be identified by setting only one judge threshold in the error bit indicating signal. The scheme is demonstrated for an 80 Gb/s bit stream with return-to-zero format by simulation. The results show that the scheme can be used for the all-optical bit-error indicating of the super high bit-rate systems using the return-to-zero format which is favored in the optical time division multiplexing transmission systems.     

数值模拟不等距叶片对贯流风机的影响

贯流风机的通过频率(BPF)是其重要的噪声频率.降低BPF噪声可以降低基频处的声压级,其中一种方法是采用不等距叶片.本文采用3种叶片距分布形式,采用realizable k-ε两方程和大涡模拟(LES)湍流模型模拟了风机的内流场,计算线性欧拉方程(LEE)中声源项得到声源位置及强度,采用基于Lighthill声类比的FW-H积分方程获得了叶轮和蜗舌处偶极子型的离散噪声频谱.比较了不同叶片距对风机性能,噪声特别是BPF噪声的影响.计算结果表明在对性能影响较小的情况下,不等距叶轮可降低BPF噪声和总A声级噪声.     

一种利用小体积偏置探测器的新型锥束X射线CT系统

在传统的CT系统中, 系统的硬件成本和计算量都是非常巨大的. 提出了一种利用偏移放置的面阵探测器的锥束CT系统, 在这种系统中X射线束仅仅覆盖被扫描物体的一半体积, 投影数据在探测器方向上是截断的, 探测器尺寸和投影数据量都减少为传统CT系统的一半. 在这种新型扫描方式下, 现有的CT重建算法都不能处理. 因此, 提出了一种BPF形式的直接反投影重建方法. 该方法不需要对投影数据重排, 直接反投影滤波重建出最终的图像. 因此, 该算法在数学上更简洁, 计算速度更快. 最后, 数值模拟实验和真实CT系统实验结果均验证了该系统和重建算法能够获得高质量的CT图像.     

New dual-mode square patch bandpass filter using CSRR slot-type perturbation

A compact dual-mode microstrip bandpass filter using square-patch resonator and a new perturbation element is designed in this letter. This new slot-type element is composed by a complement split-ring resonator (CSRR) with two pairs of etching slots. The nature of coupling between the degenerate modes is investigated with respect to the perturbation size. By proper arranging the orientations of the CSRRs, new coupling characteristics can be obtained. The proposed dual mode bandpass filters are designed, and simulated. The simulation and measure results of proposed bandpass filter are reasonable.     

Molecularly imprinted polymer microspheres prepared by Pickering emulsion polymerization for selective solid-phase extraction of eight bisphenols from human urine samples

The bisphenol A (BPA) imprinted polymer microspheres were prepared by simple Pickering emulsion polymerization. Compared to traditional bulk polymerization, both high yields of polymer and good control of particle sizes were achieved. The characterization results of scanning electron microscopy and nitrogen adsorption–desorption measurements showed that the obtained molecularly imprinted polymer microsphere (MIPMS) particles possessed regular spherical shape, narrow diameter distribution (30–60 μm), a specific surface area (S_BET) of 281.26 m² g⁻¹ and a total pore volume (V_t) of 0.459 cm³ g⁻¹. Good specific adsorption capacity for BPA was obtained in the sorption experiment and good class selectivity for BPA and its seven structural analogs (bisphenol F, bisphenol B, bisphenol E, bisphenol AF, bisphenol S, bisphenol AP and bisphenol Z) was demonstrated by the chromatographic evaluation experiment. The MIPMS as solid-phase extraction (SPE) packing material was then evaluated for extraction and clean-up of these bisphenols (BPs) from human urine samples. An accurate and sensitive analytical method based on the MIPMS-SPE coupled with HPLC-DAD has been successfully established for simultaneous determination of eight BPs from human urine samples with detection limits of 1.2–2.2 ng mL⁻¹. The recoveries of BPs for urine samples at two spiking levels (100 and 500 ng mL⁻¹ for each BP) were in the range of 81.3–106.7% with RSD values below 8.3%.     

固相萃取-超高效液相色谱-高分辨质谱法快速测定食用油中4种酚类环境雌激素残留

建立了固相萃取-超高效液相色谱-高分辨质谱(SPE-UPLC-HRMS)快速测定食用油中4种痕量酚类环境雌激素(双酚S(BPS)、双酚F(BPF)、双酚A(BPA)和4-壬基酚(4-NP))的分析方法。食用油样品经乙腈涡旋提取和SLC玻璃固相萃取小柱净化后,以0.05%(v/v)三乙醇胺和甲醇溶液为流动相进行梯度洗脱,采用Waters ACQUITY UPLC HSS T3色谱柱(100 mm×2.1 mm,1.8μm)进行分离,在电喷雾离子源负离子模式(ESI-)和选择性离子监测(SIM)模式下进行检测,内标法定量。4种目标物在各自的范围内有良好的线性关系,相关系数(r)0.999。方法的检出限(LOD,S/N=3)和定量限(LOD,S/N=10)分别为0.03~0.11μg/kg和0.10~0.36μg/kg。在1.0、10.0和80.0μg/kg 3个加标水平下,4种目标物的加标回收率为86.3%~96.1%,相对标准偏差(RSD)为2.2%~8.8%(n=6)。基质效应实验表明方法在低、中、高3个浓度水平下均无明显的基质干扰。该法简便、快速,能用于食用油中双酚S、双酚F、双酚A和4-壬基酚残留的快速检测。     

Design of a Novel Bandpass Filter in Millimeter-Wave Band

In this paper, a novel Bandpass Filter (BPF) combining microstrip parallel-coupled with end-coupled resonators is proposed. The filter not only allows the cross coupling to be realized but also makes itself compactness. At 35GHz, such a filter is designed and experimental results are discussed.