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1.
《合成通讯》2013,43(11):1447-1453
Abstract An efficient preparation of 1‐[79Br]bromo‐2‐fluoroethylene, [79Br]BrHC?CHF, was carried out by a three‐step procedure: (a) natural 1‐bromo‐2‐fluoroethylene, BrHC?CHF, was iodinated to 1‐fluoro‐2‐iodoethylene, FHC?CHI; (b) 1‐fluoro‐2‐iodoethylene was 79Br2‐brominated to 1,2‐di[79Br]bromo‐1‐fluoro‐2‐iodoethane, [79Br]BrFCHCH[79Br]BrI; and (c) 1,2‐di[79Br]bromo‐1‐fluoro‐2‐iodoethane was dehalogenated to 1‐[79Br]bromo‐2‐fluoroethylene, [79Br]BrHC?CHF. The yield of isolated product, on a 2‐mmol scale, was 62% with respect to 79Br2. 相似文献
2.
Long-period fibre gratings inside standard single-mode optical communication fibres are successfully fabricated with infrared femtosecond laser pulses. The refractive index perturbations are well confined within the fibre core by choosing the proper laser focusing parameters and translation speed of the fibre during the direct laser writing process. With the self-focusing effect considered and at a constant average irradiation dose of 1.62 × 10^3 J/(cm^2μm), the threshold intensity for fabricating long-period gratings with infrared femtosecond laser pulses is determined to be 5.13 × 10^13 W/cm2. 相似文献
3.
Matching for a wavefunction the WKB expansion at large distances and Taylor expansion at small distances leads to a compact, few-parametric uniform approximation found in Turbiner and Olivares-Pilon (2011). The ten low-lying eigenstates of H2+ of the quantum numbers (n,m,Λ,±) with n=m=0 at Λ=0,1,2, with n=1, m=0 and n=0, m=1 at Λ=0 of both parities are explored for all interproton distances R. For all these states this approximation provides the relative accuracy ?10−5 (not less than 5 s.d.) locally, for any real coordinate x in eigenfunctions, when for total energy E(R) it gives 10-11 s.d. for R∈[0,50] a.u. Corrections to the approximation are evaluated in the specially-designed, convergent perturbation theory. Separation constants are found with not less than 8 s.d. The oscillator strength for the electric dipole transitions E1 is calculated with not less than 6 s.d. A dramatic dip in the E1 oscillator strength f1sσg−3pσu at R∼Req is observed. The magnetic dipole and electric quadrupole transitions are calculated for the first time with not less than 6 s.d. in oscillator strength. For two lowest states (0,0,0,±) (or, equivalently, 1sσg and 2pσu states) the potential curves are checked and confirmed in the Lagrange mesh method within 12 s.d. Based on them the Energy Gap between 1sσg and 2pσu potential curves is approximated with modified Pade Re−R[Pade(8/7)](R) with not less than 4-5 figures at R∈[0,40] a.u. Sum of potential curves E1sσg+E2pσu is approximated by Pade 1/R[Pade(5/8)](R) in R∈[0,40] a.u. with not less than 3-4 figures. 相似文献
4.
V. S. Antonov V. S. Letokhov A. N. Shibanov 《Applied Physics A: Materials Science & Processing》1981,25(1):71-76
The paper presents the results of studies into ion desorption from the surface of adenine and anthracene molecular crystals
and anthracene molecules adsorbed on a metal as the surface is irradiated by an uv laser at λ=249, 308, and 337 nm. A sharp
increase in molecular ion yield has been revealed with a decrease in radiation wavelength down to 249 nm. At this wavelength
the effect of molecular ion desorption is observed at the radiation intensity of 20∶50 kW/cm2 and pulse duration of 20 ns, it cannot be explained by thermal mechanisms. The initial velocity distribution of photoions
is nonthermal by character, with maximum velocity of 2·105 cm/s in case of adenine. The mechanisms responsible for the effect observed are discussed. 相似文献
5.
IR laser-induced ionization is investigated in condensed methanol (77 K) using a TEA CO2 laser for resonant vibrational excitation and a quadrupole mass spectrometer to analyse the ion spectra produced by laser irradiation. Ions are already detected at laser fluences below 1 J/cm2, far below dielectric breakdown. The fluence dependence of the ion yield is measured for two groups of ions and the total number of ions. A mechanism is proposed for the photochemical production of protonated molecules. The protonated monomer is the species with the highest abundance; however, protonated dimers and other quasimolecular ions and fragment ions are also found. 相似文献
6.
The problem addressed in this paper is to compare the minimum cost of the two randomized control policies in the M/G/1 queueing system with an unreliable server, a second optional service, and general startup times. All arrived customers demand the first required service, and only some of the arrived customers demand a second optional service. The server needs a startup time before providing the first required service until the system becomes empty. After all customers are served in the queue, the server immediately takes a vacation and the system operates the (T, p)-policy or (p, N)-policy. For those two policies, the expected cost functions are established to determine the joint optimal threshold values of (T, p) and (p, N), respectively. In addition, we obtain the explicit closed form of the joint optimal solutions for those two policies. Based on the minimal cost, we show that the optimal (p, N)-policy indeed outperforms the optimal (T, p)-policy. Numerical examples are also presented for illustrative purposes. 相似文献
7.
Using a master equation for the reduced density matrix of open quantum system, the influence of coordinate-dependent microscopical diffusion coefficients on the decay rate from a potential well is studied. For different temperatures, frictions, heights of barrier and ratios of stiffnesses of the potential in the minimum and on the top of the barrier, the quasistationary decay rates are obtained with the sets of coordinate-dependent and -independent microscopical diffusion coefficients, and coordinate-dependent phenomenological diffusion coefficients. 相似文献
8.
We introduce a new solid-state NMR method, which uses very slow sample rotation to visualize NMR spectra whose width exceeds feasible spectrometer bandwidths. It is based on the idea that if we reorient a tensor by a known angle about a known axis, the shifts in the NMR frequencies observed across the spectral width allow us to reconstruct the entire tensor. Called STREAQI (Slow Turning Reveals Enormous Anisotropic Quadrupolar Interactions), this method allows us to probe NMR nuclei that are intractable to current methods. To prove the concept and demonstrate its promise we have implemented the method for several 79Br containing samples with quadrupolar coupling constants in the range of 10-50 MHz. 相似文献
9.
The protonation constants of two nitro-Schiff bases SB1, SB2 and three asymmetric tetradentate diimines H2L1, H2L2 and H2L3 and the stability constants of their ML type binuclear Ni(II) and Fe(III) complexes have been determined potentiometrically. The asymmetric diimines are (2OH) RCHNC6H4CHNR′ (2OH) type compounds [where R = R′ = phenyl for H2L1; R = naphthyl, R′ = phenyl for H2L2 and R = R′ = naphthyl for H2L3]. The effect of tautomeric forms on the acid-base properties of the diimines has been investigated and discussed. In addition, dimeric and binuclear Ni(II) and Fe(III) complexes of the diimines have been synthesized and characterized by physical and spectroscopic techniques. Also, in vitro antimicrobial activities of the diimines and the complexes have been evaluated against three bacteria: Micrococcus luteus (NRLL B-4375), Bacillus cereus (RSKK 863), Escherichia coli (ATCC 11230) and the fungus: Candida albicans (ATCC 10239). 相似文献
10.
A thorough review of 35/37Cl, 79/81Br, and 127I solid-state nuclear magnetic resonance (SSNMR) data is presented. Isotropic chemical shifts (CS), quadrupolar coupling constants, and other available information on the magnitude and orientation of the CS and electric field gradient (EFG) tensors for chlorine, bromine, and iodine in diverse chemical compounds is tabulated on the basis of over 200 references. Our coverage is through July 2005. Special emphasis is placed on the information available from the study of powdered diamagnetic solids in high magnetic fields. Our survey indicates a recent notable increase in the number of applications of solid-state quadrupolar halogen NMR, particularly 35Cl NMR, as high magnetic fields have become more widely available to solid-state NMR spectroscopists. We conclude with an assessment of possible future directions for research involving 35/37Cl, 79/81Br, and 127I solid-state NMR spectroscopy. 相似文献