Insight into shear‐induced modification for improving processability of polymers: Effect of shear rate on the evolution of entanglement state

Many experimental results have revealed that the re‐entanglement kinetics of disentangled polymers is much slower than that predicted by tube theory. This retarded recovery of fully entangled state is of practical significance that shear‐induced modification may offer a way to improve processability for a polymer by reducing viscosity. This work tried to figure out the shear‐rate dependence variation of viscosity in the view of evolution of entanglement state through disentanglement and re‐entanglement, aiming to provide fundamental insights into application prospect of shear‐induced modification in preparing “in‐pellet” disentangled polymers prior to final processing. High‐density polyethylene was sheared on a parallel‐plate rotational rheometer with a linearly increased shear rate. Results showed that higher shear rate could induce further disentanglement, resulting in a lower viscosity with a reduction rate up to 93.7%, larger molecular weight between entanglements M_e , and longer re‐entanglement time. Additionally, less entanglement would give a larger lamellar thickness of sheared samples after nonisothermal crystallization. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 598–606     

Shedding vortex simulation method based on viscous compensation technology research

Owing to the influence of the viscosity of the flow field, the strength of the shedding vortex decreases gradually in the process of backward propagation. Large-scale vortexes constantly break up, forming smaller vortexes. In engineering, when numerical simulation of vortex evolution process is carried out, a large grid is needed to be arranged in the area of outflow field far from the boundary layer in order to ensure the calculation efficiency. As a result, small scale vortexes at the far end of the flow field cannot be captured by the sparse grid in this region, resulting in the dissipation or even disappearance of vortexes. In this paper, the effect of grid scale is quantified and compared with the viscous effect through theoretical derivation. The theoretical relationship between the mesh viscosity and the original viscosity of the flow field is established, and the viscosity term in the turbulence model is modified. This method proves to be able to effectively improve the intensity of small-scale shedding vortexes at the far end of the flow field under the condition of sparse grid. The error between the simulation results and the results obtained by using fine mesh is greatly reduced, the calculation time is shortened, and the high-precision and efficient simulation of the flow field is realized.     

The Effect of Viscosity on the Diffusion and Termination Reaction of Organic Radical Pairs

The effect of viscosity on the diffusion efficiency (F_dif) of an organic radical pair in a solvent cage and the termination mechanism, that is, the selectivity of disproportionation (Disp) and combination (Comb) of the geminated caged radical pair and the diffused radicals encountered, were investigated quantitatively by following the photolysis of dimethyl 2,2′-azobis(2-methylpropionate) (V-601) in the absence and presence of PhSD. F_dif and Disp/Comb selectivity outside the cage [Disp_(dif)/Comb_(dif)] are highly sensitive to the viscosity. In contrast, the Disp/Comb selectivity inside the cage [Disp_(cage)/Comb_(cage)] is rather insensitive. The difference in viscosity dependence between Disp_(cage)/Comb_(cage) and Disp_(dif)/Comb_(dif) is explained by the spin state of the radical pair inside and outside the cage and the spin state dependent configurational changes of the radical pair upon their collision. Given that the configurational change of the radicals associates the displacement and reorganization of solvents around the radicals, the termination outside the cage, which requires larger change than that inside the cage, is highly viscosity dependent. Furthermore, while the bulk viscosity of each solvent shows good correlation with F_dif and Disp/Comb selectivity, microviscosity is the better parameter predicting F_dif and Disp_(dif)/Comb_(dif) selectivity regardless of the solvents.     

Enhancing the Viscosity-Sensitive Range of a BODIPY Molecular Rotor by Two Orders of Magnitude

Molecular rotors are a class of fluorophores that enable convenient imaging of viscosity inside microscopic samples such as lipid vesicles or live cells. Currently, rotor compounds containing a boron-dipyrromethene (BODIPY) group are among the most promising viscosity probes. In this work, it is reported that by adding heavy-electron-withdrawing −NO₂ groups, the viscosity-sensitive range of a BODIPY probe is drastically expanded from 5–1500 cP to 0.5–50 000 cP. The improved range makes it, to our knowledge, the first hydrophobic molecular rotor applicable not only at moderate viscosities but also for viscosity measurements in highly viscous samples. Furthermore, the photophysical mechanism of the BODIPY molecular rotors under study has been determined by performing quantum chemical calculations and transient absorption experiments. This mechanism demonstrates how BODIPY molecular rotors work in general, why the −NO₂ group causes such an improvement, and why BODIPY molecular rotors suffer from undesirable sensitivity to temperature. Overall, besides reporting a viscosity probe with remarkable properties, the results obtained expand the general understanding of molecular rotors and show a way to use the knowledge of their molecular action mechanism for augmenting their viscosity-sensing properties.     

Viscosity solutions to a parabolic inhomogeneous equation associated with infinity Laplacian

We obtain the existence and uniqueness results of viscosity solutions to the initial and boundary value problem for a nonlinear degenerate and singular parabolic inhomogeneous equation of the form ut- ΔN∞u = f,where ΔN∞denotes the so-called normalized infinity Laplacian given by ΔN∞u =1|Du|2 D2 uD u, Du.     

Intra‐ and inter‐supramolecular complexation of poly(butyl methacrylate)‐co‐2‐(1,2,3‐triazol‐4‐yl)pyridine copolymers induced by CoII,FeII, and EuIII ions monitored by molecular hydrodynamics methods

Poly(butyl methacrylate) copolymers embedding bidentate 2‐(1,2,3‐triazol‐4‐yl)pyridine (trzpy) chelating units as comonomer in the side chains were synthesized by controlled radical addition‐fragmentation transfer (RAFT) polymerization. Intracomplexation and intercomplexation of the macromolecules of the poly(butyl methacrylate) copolymers containing 20 % mol of trzpy units induced by Co^II, Fe^II, and Eu^III ions were studied in the solutions by macromolecular hydrodynamics methods. The sedimentation velocity of extremely diluted copolymer solutions and the dynamic viscosity of moderately diluted solutions were studied in a wide range of the salts concentrations. Differences were observed with respect to the copolymer behavior in the presence of the Co²⁺, Fe²⁺, Eu³⁺ ions. These differences are namely due to the differences in the number of coordination bonds required for complex formation and not explicitly to the nature of the corresponding anions. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 2632–2639     

Geometrical methods for analyzing the optimal management of tipping point dynamics

Natural resources are not infinitely resilient and should not be modeled as being such. Finitely resilient resources feature tipping points and history dependence. This paper provides a didactical discussion of mathematical methods that are needed to understand the optimal management of such resources: viscosity solutions of Hamilton–Jacobi–Bellman equations, the costate equation and the associated canonical equations, exact root counting, and geometrical methods to analyze the geometry of the invariant manifolds of the canonical equations. Recommendations for Resource Managers

• Management of natural resources has to take into account the possible breakdown of resilience and induced regime shifts.
• Depending on the characteristics of the resource and on its present and future economic importance, either for all initial states the same kind of management policy is optimal, or the type of the optimal management policy depends on the initial state.
• Modeling should reflect the finiteness of the data.

     

从科研中提炼出的精细化工专业实验:新型疏水缔合聚合物的制备、表征及性能测定*

结合教师科研项目,推荐一个精细化工专业实验:疏水缔合聚合物的制备、表征及性能测定。通过该实验可以使学生掌握自由基共聚法制备聚合物的基本原理,掌握一些大型仪器的基本操作、聚合物常用的表征手段及结构分析方法,理解疏水缔合聚合物结构与性能之间深层次的理论联系。该实验项目来源于科研,服务于实践,集聚合反应、结构表征、大分子溶液理化性能测试于一体,具有综合性、前沿性、研究性等特点。本实验的开设有利于提高精细化工方向学生的专业实验水平,提升学生的综合探究素质、创新意识及动手能力。     

Dicationic disiloxane ionic liquids

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