Annealing effect on adhesion properties of poly(butylene terephthalate)

Injection-molded poly(butylene terephthalate) (PBT) is generally annealed at a temperature above the operating temperature to remove residual internal stress and obtain high-dimensional stability. However, this annealing treatment causes poor adhesion property and affected quality and lifetime for the products. In this study, a plausible mechanism for why such problems are caused by the annealing treatment is proposed using additive free PBT. After PBT was annealed under given conditions, surface structure and adhesion strength with an epoxy adhesive were examined. Surface roughness of the PBT film monotonically increased with increasing annealing time, and the tensile adhesive strength concurrently decreased. In addition, the height difference between hill and valley of the surface after adhesive failure became larger, meaning that the failure took place in the PBT phase beneath the interface with the epoxy region. Based on these findings, it was claimed that the poor adhesion of PBT after the annealing treatment originated from a weak boundary layer, which was formed at the outermost surface of PBT. Finally, the presence of the weak boundary layer was directly confirmed by transmission electron microscopy.     

The nonlinear boundary value problem for a class of integro-differential system

In this paper, using the theory of differential inequalities, we study the nonlinear boundary value problem for a class of integro-differential system. Under appropriate assumptions, the existence of solution is proved and the uniformly valid asymptotic expansions for arbitrary n-th order approximation and the estimation of remainder term are obtained simply and conveniently.     

Interface Shear Stress Analysis of Bond FRP Tendon Anchorage under Different Boundary Conditions

This article describes a study of an analytic interfacial stresses solution of FRP bond tendon anchorage, under different boundary conditions. The analytic solution was obtained with the cohesive zone model (CZM): the concept of the minimum relative interface displacement s _mis introduced and used as the fundamental variable to express all other parameters. The presented analytic solution agrees well with the result of experiment and that of finite element analysis (FEA). Furthermore, the interface shear stress distributions under two kinds of boundary conditions are discussed. It is indicated that the boundary conditions affected distribution of interfacial stress greatly. Under different boundary conditions, at the same load level, the peak interface shear stress corresponding to the first boundary condition is smaller than it is corresponding to the second boundary condition. The FRP tendon anchor under the first boundary condition can alleviate the peak bond stress, resulting in better uniformity in bond stress distribution.     

WEIGHTED HOLOMORPHIC BESOV SPACES AND THEIR BOUNDARY VALUES

We study weighted holomorphic Besov spaces and their boundary values. Under certain restrictions on the weighted function and parameters, we establish the equivalent norms for holomorphic functions in terms of their boundary functions. Some results about embedding and interpolation are also included.     

(+)-樟脑缩苄胺体系的不对称羰基加成反应

本文通过(+)-樟脑缩苄胺(I)与不同醛、酮的不对称加成, 经转氨合成了1,2-取代-2-氨基乙醇(2), 反应的非对映选择性经NMR测定为16-70%de.; 苏式、赤式异构体的含量比由HPLC法测定, 其值接近1, 由于立体位阻的原因加成反应发生在锂化物3的Re面。     

Stress intensity factors for a finite plate with an inclined crack by boundary collocation

In this paper, we combine the Muskhelishvili＇s complex variable method and boundary collocation method, and choose a set of new stress function based on the stress boundary condition of crack surface, the higher precision and less computation are reached. This method is applied to calculating the stress intensity factor for a finite plate with an inclined crack. The influence of θ （the obliquity of crack） on the stress intensity factors, as well as the number of summation terms on the stress intensity factor are studied and graphically represented.     

The nonlinear nonlocal singularly perturbed problems for reaction diffusion equations with a boundary perturbation

The nonlinear nonlocal singularly perturbed initial boundary value problems for reaction diffusion equations with a boundary perturbation is considered. Under suitable conditions, the outer solution of the original problem is obtained. Using the stretched variable, the composing expansion method and the expanding theory of power series the initial layer is constructed. And then using the theory of differential inequalities the asymptotic behavior of solution for the initial boundary value problems is studied. Finally the existence and uniqueness of solution for the original problem and the uniformly valid asymptotic estimation are discussed.     

平面电极上分支加和循环伏安法的研究

本文用固定电极电容电流理论对分支加和循环伏安法消除电容电流影响的原理作了说明;用数值模拟解法导出了平面电极可逆、准可逆和不可逆过程的理论方程;对其中的可逆过程作了实验验证.理论与实验结果一致.