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PinHuaLI LeiWANG MinWANG JinCanYAN 《中国化学快报》2004,15(11):1295-1298
A Glaser coupling reaction of terminal alkynes in the presence of nickel chloride withoutany organics and bases in hot water has been developed, which produces the correspondinghomo-coupling products in good yields. 相似文献
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MAO Shao-Yu a② KANG You-Juna MI Jin-Xiaoa② LI Man-Rongb WEI Zan-Bina WU Xue-Yanb ZHAO Jing-Taib a 《结构化学》2006,25(2):173-179
1 INTRODUCTION Considerable research effort on the heavy metal fluoride glasses like barium, zirconium fluoride and a series of rare-earth fluorozirconate compounds du- ring the last two decades was initiated by the broad optical transmission window of these glasses and thereby the potential for ultralow-loss optical fi- bers[1~10]. The fluorozirconate of alkali metals was first reported in 1938[11], and most of the sodium and potassium fluorozirconates were reported amongthe 1940s and 19… 相似文献
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BAO Ren-lie KONG Zu-ping GU Min YUE Bin WENG Lin-hong HE He-yong 《高等学校化学研究》2006,22(6):679-683
IntroductionSynthesis of natural minerals is helpful for tracingthe geological origin of mineral formation and forverifying the quality of minerals. The investigations onthe conditions for mineral formation, such as pressure,temperature, and starting mate… 相似文献
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在浙江新昌早白垩世盆地西侧的馆头组中,存在一些硅质岩石--块状硅质岩、含叠层石硅质岩和木化石硅质岩等,它们以高SiO2、富Fe2O3、低Al2O3和TiO2为特征,REE含量低,而且有弱的Ce亏损,δ^30Si值为-0.4‰--1.5‰,δ^18O值为18.1%-23.1‰。硅质岩的地球化学研究表明它们具有热水硅质岩的特点。结合其它地质资料,作者讨论了这些硅质岩的硅质来源和成因,认为它们系地表水和海水向下渗透,并在一定深度内发生循环然后上涌,火山活动为热水提供热源,SiO2来源于热水流经的地层和岩石。富含SiO2的热水溶液在适当的地方沉淀形成块状或透镜状硅质岩,也可解释古树木和含叠层石灰岩形成木化石硅质岩和含叠层石硅质岩,根据氧同位素地质温度计计算出硅质岩形成时的热水温度为70.8-108.4℃。 相似文献
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设计了一套新的太阳能热泵热水系统,介绍了该系统的工作原理和特点,分析表明,该系统既具有普通太阳能热泵的优点,又能够实现供暖、供冷、全年供应生活热水等多种功能。采用机理建模的方法建立了房间冷负荷、风机盘管、执行器、传感器和循环水系统的传递函数模型。设计了太阳能热泵热水系统的循环水系统PID控制、模糊控制和模糊自适应PID控制三种控制方案,并针对设计的三种控制方案对系统进行了控制仿真。结果表明,从调节时间、超调量和阶跃响应等几个方面综合考虑,由于模糊自适应PID控制能够在线调整控制系统的特性参数,随时适应系统的运行变化,在太阳能热泵热水系统的循环水系统运行控制上具有明显的优势。 相似文献
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Zirconia nanoparticles were synthesized via hydrothermal method without any additives. This work focuses on the effect of preparation conditions1 such as the precursor preparation condition and crystallization time of nanocrystallite in autoclave on the properties of as-prepared products. The results indicated that the amount of tetragonal zirconia varied with the preparation conditions. It increased with the increase of the concentration of KOH solution in precursor producing process and reduced with the prolongation of crystallization time. At the same time, the particle size and morphology were also affected by the preparation conditions. In addition, the self-assembled spindle- like aggregates were observed in present works. 相似文献
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GUO Hong–Xu WENG Wen LI Xi–Zhong 《结构化学》2008,27(12):1455-1458
An organically templated 2-D uranyl sulfate, {(C2H8N)[(UO2)Cl(SO4)(H2O)] }n 1, has been hydrothermally synthesized. The crystal and molecular structures have been determined by X-ray crystallography method and spectral techniques. 1 belongs to monoclinic, space group P21/c with a = 8.3545(17), b = 10.550(2), c = 12.370(3)A, β = 102.64(3)°, V = 1063.9(4)A3, Mr = 464.64, De= 2.901 g/cm^3, F(000) = 836,μ = 15.710 mm^-1, Z= 4, the final R = 0.0286 and wR = 0.0685 for 10164 observed reflections with Ⅰ 〉 2σ(Ⅰ). 1 presents a two-dimensional layer-like structure constructed from infinite anionic [(UO2)Cl(H2O)(SO4)]^- layers with [C2H8N]^+ cations balancing the charge and a number of intermoleeular hydrogen bonds (C-H…O and O-H…Cl) existing in the solid state. The fluorescence properties of 1 have also been discussed. 相似文献