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排序方式: 共有279条查询结果,搜索用时 18 毫秒
1.
Improving the performance and reducing the manufacturing costs are the main directions for the development of organic solar cells in the future. Here, the strategy that uses chemical structure modification to optimize the photoelectric properties is reported. A new narrow bandgap (1.30 eV) chlorinated non-fullerene electron acceptor (Y15), based on benzo[d][1,2,3] triazole with two 3-undecyl-thieno[2′,3′:4,5] thieno[3,2-b] pyrrole fused -7-heterocyclic ring, with absorption edge extending to the near-infrared (NIR) region, namely A-DA'D-A type structure, is designed and synthesized. Its electrochemical and optoelectronic properties are systematically investigated. Benefitting from its NIR light harvesting, the fabricated photovoltaic devices based on Y15 deliver a high power conversion efficiency (PCE) of 14.13%, when blending with a wide bandgap polymer donor PM6. Our results show that the A-DA'D-A type molecular design and application of near-infrared electron acceptors have the potential to further improve the PCE of polymer solar cells (PSCs).  相似文献   
2.
Unfilled natural rubber compounds composed of conventional (CV), semi-efficient (SEV), efficient (EV) and sulfur donor (SD) vulcanization systems were heat aged to promote sulfur reversion. Rheometry, hardness, strain-strain characteristics including Mooney-Rivlin analysis, equilibrium solvent swell and Double Quantum (DQ) Nuclear Magnetic Resonance (NMR) were used to monitor crosslink density changes. A loss of crosslink density was observed by rheometry, C1, equilibrium swelling and by DQ NMR as a function of cure extent. No chain scission reactions were operating in the time/temperature conditions used. All crosslink distributions were unimodal and the network homogeneity followed the order of EV > SD > SEV > CV. The crosslink distribution narrowed during the curing process for the CV and SEV systems. Non-oxidative maturation reactions were advantageous in promoting a more random distribution of crosslinks in the polymer matrix.  相似文献   
3.
The rational selection of organic reactions in polymer synthesis is an important research content of polymer science. In recent years, multicomponent reaction as an efficient and green synthesis method has attracted the wide attention of researchers, injecting new and powerful vitality into the field of polymer synthesis. In the study of multicomponent reaction, researchers found the intersection of multicomponent reaction and click chemistry and put forward the concept of Multicomponent Click Reaction (MCR-Click), which is a kind of Multicomponent Reaction with high activity, atomic economy, and some green chemical properties. The application of MCR in polymer chemistry is reviewed in this paper. It is expected that this reaction will arouse the attention of polymer chemists and play a new role in polymer science.  相似文献   
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以氧化石墨和TiO2溶胶为前驱物,结合絮凝与水热技术制备了TiO2纳米晶/石墨烯复合物,表征了产物的结构、形貌、孔隙率、光谱吸收性质. 结果表明:TiO2纳米晶的存在一定程度上阻止了石墨烯片层的重组,TiO2纳米晶/石墨烯复合物较单纯TiO2材料具有更强的吸光性能、对亚甲基蓝分子更强的吸附性能以及更高的电荷分离效率. 在紫外光和太阳光下,TiO2纳米晶/石墨烯复合物对亚甲基蓝的光催化降解效率均高于P25和纯TiO2.  相似文献   
6.
Optimality conditions for weak efficient, global efficient and efficient solutions of vector variational inequalities with constraints defined by equality, cone and set constraints are derived. Under various constraint qualifications, necessary optimality conditions for weak efficient, global efficient and efficient solutions in terms of the Clarke and Michel–Penot subdifferentials are established. With assumptions on quasiconvexity of constraint functions sufficient optimality conditions are also given.  相似文献   
7.
This paper discusses a mean–variance portfolio selection problem under a constant elasticity of variance model. A backward stochastic Riccati equation is first considered. Then we relate the solution of the associated stochastic control problem to that of the backward stochastic Riccati equation. Finally, explicit expressions of the optimal portfolio strategy, the value function and the efficient frontier of the mean–variance problem are expressed in terms of the solution of the backward stochastic Riccati equation.  相似文献   
8.
We study an important problem faced by Blood Centers, of selecting screening tests for donated blood to reduce the risk of “transfusion-transmitted infectious diseases” (TTIs), including the human immunodeficiency virus (HIV), hepatitis viruses, human T-cell lymphotropic virus, syphilis, West Nile Virus, and Chagas’ Disease. This decision has a significant impact on health care quality in both developed and developing countries. The budget-constrained decision-maker needs to construct a portfolio of screening tests, from a set of available tests, each with given efficacy (sensitivity and specificity) and cost, to administer to each unit of donated blood so as to minimize the “risk” of a TTI for blood classified as “infection-free.” While doing this, it is critical, for a viable blood system, that the decision-maker does not falsely (i.e., through screening error) discard too much of the infection-free blood (“waste”). We construct mathematical models of this decision problem, considering the various objective functions (minimization of the TTI risk or the weighted TTI risk) and various constraints (on budget and wasted blood) relevant in practice. Our work generates insights on the test selection problem. We show, for example, that a reduction in risk does not necessarily come at the expense of an increase in waste. This underscores the importance of considering these different metrics in decision-making through an optimization-based model. Our work also highlights the importance of generating region-specific testing schemes that explicitly take into account the regional prevalence and co-infection rates, along with the impacts of the infections on the society and individuals.  相似文献   
9.
This paper employs cross-frontier analysis, an innovative tool based on data envelopment analysis, to provide new insight into the relationship between organization and efficiency in international insurance markets. We are the first to empirically test the expense preference hypothesis and the efficient structure hypothesis in a large cross-country study. For this purpose, we consider 23,807 firm-years for 21 countries from northern America and the European Union—a dataset not previously analyzed in this context. We find evidence for the efficient structure hypothesis in selected market segments, but we find no evidence for the expense preference hypothesis. Our results provide insight into the competitiveness of stock and mutual insurers from different countries. At the country level, the results can be used to compare different insurance markets. Our findings are especially interesting for the strategic management of insurance companies as well as for regulators and boards of national insurance associations.  相似文献   
10.
At the ultra high frequency level, the notion of price of an asset is very ambiguous. Indeed, many different prices can be defined (last traded price, best bid price, mid price, etc.). Thus, in practice, market participants face the problem of choosing a price when implementing their strategies. In this work, we propose a notion of efficient price which seems relevant in practice. Furthermore, we provide a statistical methodology enabling to estimate this price from the order flow.  相似文献   
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