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1.
The four aromatic amino acids in proteins, namely histidine, phenylalanine, tyrosine, and tryptophan, have strongly overlapping 13C chemical shift ranges between 100 and 160 ppm, and have so far been largely neglected in solid-state NMR determination of protein structures. Yet aromatic residues play important roles in biology through π–π and cation–π interactions. To better resolve and assign aromatic residues' 13C signals in magic-angle-spinning (MAS) solid-state NMR spectra, we introduce two spectral editing techniques. The first method uses gated 1H decoupling in a proton-driven spin-diffusion (PDSD) experiment to remove all protonated 13C signals and retain only non-protonated carbon signals in the aromatic region of the 13C spectra. The second technique uses chemical shift filters and 1H–13C dipolar dephasing to selectively detect the Cα, Cβ and CO cross peaks of aromatic residues while suppressing the signals of all aliphatic residues. We demonstrate these two techniques on amino acids, a model peptide, and the microcrystalline protein GB1, and show that they significantly simplify the 2D NMR spectra and both reveal and permit the ready assignment of the aromatic residues' signals.  相似文献   
2.
A two‐dimensional liquid‐state NMR experiment cleanly separating chemical shifts and scalar couplings information is introduced. This DIAG experiment takes advantage of a drastic reduction of the spectral window in the indirect dimension to be quickly recorded and of a new non‐equidistant modulation of the selective pulse to improve the sensitivity of the broadband homodecoupling Zangger–Sterk sequence element by one order of magnitude. A simple automatic analysis results in 1D spectra displaying singlets and lists of the scalar couplings for first‐order multiplets. This facilitates the analysis of 1D spectra by resolving multiplets based on their differences in chemical shifts and coupling structures.  相似文献   
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提出了一款具有高隔离度的双陷波超宽带多入多出(UWB MIMO)天线。该天线由两个相同的半切超宽带天线单元倒置构成。通过在天线底板刻蚀栅栏型缺陷地解耦结构,使该MIMO天线的隔离度提高至25 dB。此外,在天线半圆形辐射贴片上刻蚀两个方向相反的"L"型缝隙,实现了双陷波的功能,分别抑制了802.16无线城域网WiMAX(3.2~3.7 GHz)和WLAN(5.15~5.85 GHz)信号对天线系统的干扰。实验结果表明,该天线在3~11 GHz工作带宽内的隔离度大于25 dB,包络相关系数(ECC)小于0.004;第一个陷波频段为3.0~3.7 GHz,第二个陷波频段为5.1~5.85 GHz,有效抑制了WiMAX和WLAN的信号干扰。  相似文献   
5.
叶志伟  陈明  魏东  卢文波  刘涛  吴亮 《爆炸与冲击》2021,41(5):055201-1-055201-10
不耦合装药爆破孔壁压力峰值是控制岩体轮廓成形质量及进行非流固耦合爆破振动响应数值模拟分析的重要参数,本文采用实验方法研究了不耦合装药爆破的孔壁压力峰值:利用材质为20钢的无缝薄壁钢管模拟不耦合装药爆破炮孔,以高灵敏度、高精度的应变片为传感器,选用超动态应变仪采集钢管内置柱状炸药卷爆炸过程中钢管外壁产生的环向应变,应用动荷载作用下薄壁圆筒的动力响应计算方法,反演分析采集的钢管外壁环向应变数据,得到了爆破过程中空气冲击波作用于钢管内壁的冲击荷载压力峰值,间接测量了不耦合装药爆炸后的孔壁压力峰值。实验获得了6种不耦合装药工况下的爆破孔壁压力峰值测试数据,并计算了相应工况下实验值较准静态爆生气体压力的增大倍数,拟合结果表明压力增大倍数随不耦合系数的增大近似呈线性增长。同时也分析了部分试验工况下爆炸测试结果不理想的原因,研究成果可为轮廓爆破孔壁压力峰值的测试与计算提供参考。  相似文献   
6.
Single crystal silicon, both with and without oxygen, has been diffused with lithium to concentrations ~1017/cm2, irradiated with 1 to 1.5 MeV electrons, and the ensuing defects studies by EPR measurements. The presence of oxygen strongly affects the properties of these defects. Measurements have indicated the presence of two new defects which involve Li-one in O-containing material and one in O-free material. The defects are observed in their electron-filled state, and indicate a net electron spinof ½. The defect spectra disappear (with time) at room temperature, and can be explained by the formation of other Li-involved defects which lie deeper in the energy bandgap and are not visible by EPR. Electron irradiation at 40 °K followed by annealing at higher temperatures show that both EPR defects described above begin to form at about 200 °K and begin to decrease at about 275 °K-just as does the 250 °K reverse annealing observed generally for n-type Si. Based on these data, and the work of others, it is suggested that both defects form as a result of the motion of Si interstitials which produce a (Li-O-interstitial) complex in O-containing Si, and a (Li-interstitial) complex in O-free Si.  相似文献   
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The 13C nmr assignments for all carbons except the methylene groups were made for artemisinin (1), artemether (2) and desoxyartemisinin (3). The assignments were based on chemical shift theory and confirmed by selective band decoupling experiments.  相似文献   
9.
In this article, we consider the coupled Navier–Stokes and Darcy problem with the Beavers–Joseph interface condition. With suitable restrictions of physical parameters α and ν, we prove the existence and local uniqueness of a weak solution. Then we propose a coupled finite element scheme and a decoupled and linearized scheme based on two‐grid finite element. Under suitable further restrictions, their optimal error estimates are obtained. Finally numerical experiments indicate the validity of the theoretical results as well as the efficiency and effectiveness of the decoupled and linearized two‐grid algorithm. © 2014 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 31: 1009–1030, 2015  相似文献   
10.
针对车载武器系统快速发射需求,提出一种基于GNSS辅助的捷联惯导行进间对准自适应滤波方法。该方法把行进间传递对准分为粗对准与精对准两个阶段。粗对准阶段以GNSS为观测基准完成对捷联惯导姿态的粗捕获,降低初始偏差不确定性对于精对准阶段的影响。在精对准阶段,考虑到车载系统的运动特性,提出一种"水平+方位"行进间对准双滤波器并行的设计思路,利用车载系统在不同时间段的动力学特性,对三轴姿态估计进行分时解耦,实现初始姿态的高精度估计;与此同时,引入协方差成形自适应调节过程,以最小化Frobenius范数为优化指标,实现对行进间对准卡尔曼滤波器的自适应调节,增强系统鲁棒性。数值仿真表明,协方差成形自适应卡尔曼滤波方法能够有效保证系统在全运动剖面内的稳定,结合双滤波器并行方案能够有效解决行进间对准精度不高与稳定性欠佳等问题,水平对准精度优于1.5′(1σ),方位对准精度优于6′(1σ)。  相似文献   
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