在氮气介质中WC-Co/Ti6Al4V摩擦副的摩擦磨损性能研究

在THT07-135型高温摩擦磨损试验机上采用销-盘式接触形式,研究了WC-Co硬质合金/Ti6Al4V钛合金摩擦副在氮气介质中的摩擦磨损性能,并与空气介质中的摩擦磨损性能进行对比.结果表明:与空气介质相比,在氮气介质中WC-Co/Ti6Al4V摩擦副的摩擦系数稍低;WC-Co硬质合金比Ti6Al4V钛合金的磨损量低得多,氮气介质具有一定的减磨作用;钛合金材料的主要磨损机理为摩擦副之间产生较强的犁沟与挤压撕裂,而硬质合金的主要磨损机理为磨粒磨损与粘结剥落.     

中空介孔碳化钨微球载钯催化剂对甲酸电催化性能

采用喷雾干燥法和还原炭化处理制备具有中空介孔结构的碳化钨钴复合粉(HTCCS),其中,钴的质量含量为6%。在碳化钨钴复合粉表面的钴和氯化钯发生置换反应,得到纳米Pd/WC复合催化剂。采用X射线粉末衍射(XRD)、扫描电镜(SEM)和透射电镜(TEM)对样品的形貌和晶型结构进行了表征。结果表明, 5.0-6.0nm钯纳米粒子取代钴均匀分布在碳化钨微球表面。采用循环伏安和计时电流法研究了在酸性溶液中Pd/WC催化剂对甲酸的电催化氧化性能,结果表明,Pd/WC催化剂比Pd/C催化剂对甲酸呈现出更高的电催化氧化活性和稳定性。     

Study on tribological behavior and cutting performance of CVD diamond and DLC films on Co-cemented tungsten carbide substrates

The tribological behaviors of diamond and diamond-like carbon (DLC) films play a major role on their machining and mechanical applications. In this study, diamond and diamond-like carbon (DLC) films are deposited on the cobalt cemented tungsten carbide (WC-Co) substrate respectively adopting the hot filament chemical vapor deposition (HFCVD) technique and the vacuum arc discharge with a graphite cathode, and their friction properties are evaluated on a reciprocating ball-on-plate tribometer with counterfaces of silicon nitride (Si₃N₄) ceramic, cemented tungsten carbide (WC) and ball-bearing steel materials, under the ambient air without lubricating condition. Moreover, to evaluate their cutting performance, comparative turning tests are conducted using the uncoated WC-Co and as-fabricated CVD diamond and DLC coated inserts, with glass fiber reinforced plastics (GFRP) composite materials as the workpiece. The as-deposited HFCVD diamond and DLC films are characterized with energy-dispersive X-ray spectroscopy (EDX), scanning electron microscope (SEM), X-ray diffraction spectroscopy (XRD), Raman spectroscopy and 3D surface topography based on white-light interferometry. Furthermore, Rocwell C indentation tests are conducted to evaluate the adhesion of HFCVD diamond and DLC films grown onto WC-Co substrates. SEM and 3D surface topography based on white-light interferometry are also used to investigate the worn region on the surfaces of diamond and DLC films. The friction tests suggest that the obtained friction coefficient curves that of various contacts exhibit similar evolution tendency. For a given counterface, DLC films present lower stable friction coefficients than HFCVD diamond films under the same sliding conditions. The cutting tests results indicate that flank wear of the HFCVD diamond coated insert is lower than that of DLC coated insert before diamond films peeling off.     

纳米硬质合金摩擦磨损与切削性能研究

摩擦磨损性能、磨削性能、切削性能对纳米硬质合金实用化具有极其重要意义。应用摩擦磨损试验机研究了纳米硬质合金WC-7Co和WC-10Co的摩擦磨损性能,利用在线电解修整（Electrolytic in Process Dressing, ELID）磨削技术对纳米硬质合金刀具进行了刃磨,并且对Al/SiCp复合材料进行了切削试验,研究了纳米硬质合金刀具的切削性能与刀具磨损机理。结果表明：纳米硬质合金整体摩擦系数低,耐磨性好,WC-10Co的磨损机理表现为鱼鳞状塑性流动;纳米硬质合金磨削加工性较好,磨削机理以塑性去除为主;纳米硬质合金刀具磨损机理为Al/SiCP复合材料中SiC颗粒对刃口断续冲击,其切削实质是断续切削,刀具磨损形式是刃口破损及晶粒脱落。纳米硬质合金刀具适于低速断续切削。     

Improvement in tribological properties of atmospheric plasma-sprayed WC-Co coating followed by Cu electrochemical impregnation

The WC-Co coating obtained by atmospheric plasma spraying (APS) was modified by Cu electrochemical impregnation. The copper has infiltrated into and filled up the pores in WC-Co coating. The tribological properties of the coating against the stainless steel ball as sliding pairs were investigated with a ball-on-disc (BOD) configuration in air at room temperature. The as-prepared samples were characterized by means of optical microscope, scanning electron microscope and X-ray diffraction. It was found that the frictional behavior of the WC-Co coating followed by Cu electrochemical impregnation was superior to that of WC-Co coating. The wear mechanism of the WC-Co coating followed by Cu electrochemical impregnation was microcutting, whilst that of a WC-Co coating was the fatigue wear. The improvement in tribological properties of the WC-Co coating followed by Cu electrochemical impregnation was attributed to the formation of self-lubricating Cu film on the wear surface which induces the transformation of wear mechanism.     

等离子喷涂纳米和常规喂料WC—Co涂层在干摩擦和水环境中的摩擦磨损性能研究

采用大气等离子喷涂法分别以纳米和常规喂料制备出2种WC—Co涂层，在SRV摩擦磨损试验机上考察了2种涂层在干摩擦和水环境中的摩擦磨损性能．结果表明：在干摩擦和水环境中，纳米WC—Co涂层的摩擦系数和磨损率均小于常规WC—Co涂层；纳米和常规WC—Co涂层的磨损机制差异不大，在干摩擦下其磨损机制主要以粘着磨损、剥落和磨粒磨损为主；在水环境中，WC—Co涂层与Si3N4配副时的摩擦系数和磨损量较与不锈钢球配副时高，2种摩擦副的磨损机理有所不同，前者主要以剥落和疲劳磨损为主，后者主要以粘着磨损为主，伴有轻微的磨粒磨损．     

微米及纳米WC-Co基BDD污水处理电极的制备研究

硼掺杂金刚石(BDD)是高级氧化法污水处理领域的一种电极材料，其衬底材料的选择是电极涂层制备的核心问题之一，良好的衬底材料可提高膜基结合力，从而延长电极的使用寿命。本文提出以热膨胀系数较小的WC-Co为衬底，采用热丝化学气相沉积(HFCVD)法制备微米、纳米两种表面形貌的BDD电极，并利用场发射扫描电子显微镜(FE-SEM)、拉曼光谱、X射线光电子能谱(XPS)、循环伏安法对两种电极的物理性能、表面状态及电化学性能进行表征，研究结果表明：在沉积速率方面，微米薄膜是纳米薄膜的1.5倍，但纳米薄膜具有更小的残余应力，仅为-0.6 GPa;两种电极在0.5 mol/L的H₂SO₄溶液中均展现较宽的电化学窗口(约为3.7～3.9 V)和极小的背景电流，在K₃[Fe(CN)₆]氧化还原系统中表现出良好的准可逆特性，这些特性均与常规Si、Nb、Ti基BDD电极相似。在此基础上，本文对两种电极开展了苯酚模拟废水处理和加速寿命试验(ALT),结果显示：相同参数下，纳米电极在ALT中使用寿命约为423 h,明显优于微...     

XPS and AES surface analysis of WC-Co-(Cr) cemented carbide after immersion in neutral solution

The binder phase Co in WC-Co cemented carbide is dissolved easily in corrosive media (even in neutral solution), which has limited its application in a wider range. In this paper, the influence of Cr on corrosion resistance of WC-Co immersed in neutral solution was studied, with a focus on the surface chemistry of the corrosion product. The results show that in neutral solution, the corrosion is mainly caused by the selective dissolution of Co and the dominant surface corrosion product after immersion is Co (OH)₂. The corrosion resistance of WC-Co cemented carbide can be improved by the addition of Cr. This can be explained by the formation of more protective chromium containing oxide on the binder phase of WC-Co-Cr alloy, leading to reduced corrosion rate.     

Dynamic torsion testing of nanocrystalline coatings using high-speed photography and digital image correlation

The strength and ductility of microcrystalline and nanocrystalline tungstsen carbide-cobalt (WC-Co) cermets have been evaluated by employing a stored energy Kolsky bar apparatus, high-speed photography and digital image correlation. The test specimens were thin-walled tubular AI7075-T6 substrates 250 μm thick, coated with a 300 μm thick microcrystalline or nanocrystalline WC-Co layer with an average grain size of about 3 μm and 100 nm, respectively. Dynamic torsion experiments reported in this paper reveal a shear modulus of 50 GPa and a shear strength of about 50 MPa for both microcrystalline and nanocrystalline WC-Co coatings. The use of high-speed photography along with digital image correlation has shown that damage to the coating coincides with a significant softening on the stress-strain curve. The coating failed in mode III, and strong interactions between the crack faces were probably responsible for the increase in load after failure of the coating. The overall failure of the coating-substrate system was not brittle but rather progressive and controlled by the ductility of the aluminum substrate. A methodology for investigating damage kinetics and failure has been established. This methodology can be applied to examine the behavior of other advanced materials that can be manufactured as coatings on ductile substrates. Manufacturing coatings free of initial microcracks remains a significant challenge. Research on optimization of the spray deposition parameters should be pursued to produce high-quality nanostructured coatings that can fully exploit the benefits of nano-size grains.     

去钴深度的测定及其对硬质合金性能的影响

研究了原子吸收光谱法和辉光放电光谱仪定量测定硬质合金去钴深度的新技术。实验得到了腐蚀时间与硬质合金去钴深度、表面显微硬度的关系曲线,分析了去钴深度对硬质合金表面形貌的影响。