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本文通过水热法,结合气相沉积法和掩膜紫外光刻法,在玻璃基底上成功地制备了一种具有多尺度结构的超亲水-超疏水组合壁面,并对制备的具有不同润湿差异的组合壁面的冷凝效率进行了测试。结果表明壁面的冷凝效率取决于亲疏水区域的宽度和润湿性差异,其中当亲水区域宽度为0.80 mm,接触角约为0°,疏水区域宽度为0.95 mm,接触角为158°时,其冷凝效率相比光滑铜片的冷凝效率可以提高39%。进一步分析表明,液滴在极端润湿模式的组合表面的润湿分界线处具有较高的体积传输速率,且在超亲水区形成的连续微流通道加快了冷凝液滴快速排放,提高了整体表面的自更新能力。本文的研究,将为复杂润湿界面滴状冷凝的优化提供方向。 相似文献
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A novel set of light-responsive polyelectrolytes has been developed and studied, to control and tune surface wettability by introducing various types of substituted R head-groups of azo polyelectrolytes in self-assembled multilayer (SAMU) films. As part of a larger project to develop polymer surfaces where one can exert precise control over properties important to proteins and cells in contact, photo-reversibly, we describe here how one can tune quite reliably the contact angle of a biocompatible SAMU, containing a photo-reversible azo chromophore for eventual directed cell growth. The azo polyelectrolytes described here have different substituted R head-group pairs of shorter-ionized hydrophilic COOH and SO3H, shorter non-ionized hydrophobic H and OC2H5, and larger non-ionized hydrophobic octyl C8H17 and C8F17, and were employed as polyanions to fabricate the SAMU onto silicon substrates by using the counter-charge polycation PDAC. The prepared SAMU films were primarily characterized by measurement of their contact angles with water. The surface wetting properties of the thin films were found to be dependent on the type of substituted R-groups of the azo polyelectrolytes through their degree of ionization, size, hydrophobicity/hydrophilicity, solubility, conformation, and inter-polymeric association and intra-polymeric aggregation. All these factors appeared to be inter-related, and influenced variations in hydrophobic/hydrophilic character to different extents of aggregates/non-aggregates in solution because of solvation effects of the azo polyanions, and were thus manifested when adsorbed as thin films via the SAMU deposition process. For example, one interesting observation is significantly higher contact angles of 79° for SAMU films of larger octyl R groups of PAPEA-C8F17 and PAPEA-C8H17 than for others with contact angles of 64° observed for non-polar R-groups of OC2H5 and H. Furthermore, lower contact angle values of 59° for SAMU films with polar R-groups of COOH and SO3H relative to that of non-polar R-groups are in accordance with their expected order of the hydrophilicity or hydrophobicity. It is possible that the large octyl groups are more effective in shielding the ionic functional groups on the substrate surface, and contributed less to the water drop-molecule interactions with ionic groups of the PDAC and/or AA groups. In addition, higher hydrophobicity of the SAMU films may be due to the incorporation of bulky and hydrophobic groups in these polyelectrolytes, which can produce aggregates on the surfaces of the SAMU films. Through understanding and controlling the complex aggregation behavior of the different substituted R-groups of these azo polyelectrolytes, and hence their adsorption on substrates, it appears possible to finely tune the surface energy of these biocompatible films over a wide range, enhance the photo-switching capabilities of the SAMU films, and tailor other surface properties for the development and application of new devices in diverse areas of microfluidics, specialty coatings, sensors, and biomedical sciences. 相似文献
4.
You Wei 《Journal of Dispersion Science and Technology》2013,34(12):1785-1794
5.
The mechanism of spontaneous imbibition of water by sandstone cores and the relationship between reservoir wettability and imbibition recovery were studied by investigating factors influencing the spontaneous imbibition of different surfactants by oil-wet sandstone cores. Ultimate oil recovery of cores using the cationic surfactant CTAB was higher than that of the cores using the nonionic surfactant TX-100 and the anionic surfactant POE (1) at the same concentration. For CTAB and TX-100, the ultimate oil recovery by spontaneous imbibition increased with increase in surfactant concentration. In regard to imbibition recovery, TX-100 and POE(1) at high temperatures were superior to those at low temperatures. Ultimate oil recovery of the high-permeability core was higher than that of the low-permeability core at room temperature. According to changes in the driving force during the imbibition process, the imbibition curve could be divided into three regions: (1) mainly capillary force, (2) both capillary and gravity forces, and (3) mainly gravity force. The stronger the hydrophilicity of the rock surface, the higher the spontaneous imbibition recovery. 相似文献
6.
Different experimental methods including ellipsometry, zeta potential measurements, imbibition studies, and contact angle measurements were used to study the mechanism and influencing factors of wettability alteration of water-wet sandstone surface caused by CTAB (hexadecyl trimethyl ammonium bromide). Results show that when the concentration of CTAB reaches a certain level (below CMC), due to the electrostatic attraction between the positively charged head groups of CTAB and the negatively charged sandstone surface, the monolayer of CTAB is formed and hydrophobic chains of CTAB molecules are toward the aqueous phase, making the solid surface oil-wet. When the concentration of CTAB continues to increase (above CMC), due to the hydrophobic interaction, the compact bilayer of CTAB is formed and hydrophilic head groups of CTAB molecules are toward the aqueous phase, rendering the solid surface water-wet. The contact angles between the oil–water interface and the surface treated with CTAB increase with the increase of the concentration of NaCl and CaCl2. Compared to NaCl, the inorganic salt CaCl2 has a greater impact on the contact angle. In addition, the contact angles increase with the increase of temperature and decrease with the increase of pH value of the aqueous solution. 相似文献
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8.
纳米CaCO3的改性、表面结构与流变行为研究 总被引:4,自引:0,他引:4
采用铝锆偶联剂和棕榈酸改性纳米CaCO3 粉体. 借助 XRD, FTIR, 接触角及流变学等测试方法对纳米CaCO3 的表面结构进行表征. XRD 分析表明: 改性纳米 CaCO3保持原样品完整的体相结构, 为方解石型纳米微晶. FTIR 分析证明: 表面改性剂与纳米 CaCO3 表面是以化学键合和物理吸附方式相结合, 粒子表面存在羧基等有机官能团的红外吸收特征. 通过测定苯和水在改性纳米CaCO3粉末压片上的接触角, 计算了改性纳米 CaCO3的表面能和极性分量, 并与未改性纳米CaCO3 进行比较. 结果表明, 经表面改性, 纳米 CaCO3 的表面能和极性分量明显降低, 其在有机溶液中的吸附功增大, 界面张力大大降低; 经棕榈酸改性的纳米 CaCO3 表现出较好的亲油疏水性, 而铝锆偶联剂改性的纳米 CaCO3 同时具有亲水性和亲油性. 以液体石蜡为溶剂, 研究了表面改性对纳米CaCO3悬浮液流变行为的影响. 实验发现: 经过表面处理, 纳米 CaCO3 粉体悬浮液流变行为发生较大的变化, 稳态剪切黏度大大降低, 表现出较小的动态弹性储能模量和黏性损耗模量, 而损耗因子较大. 相似文献
9.
WANG JingXia ZHANG YouZhuan ZHAO TianYi SONG YanLin & JIANG Lei Laboratory of New Materials Key Laboratory of Organic Solid 《中国科学:化学》2010,(2)
The wettability of solid surfaces has attracted extensive interest in both theoretical research and industrial applications. This paper reviews recent research progress in the fabrication and applications of the colloidal crystals with special wettability. Based on the modified equation of Wenzel and Cassie, the colloidal crystals with special wettability have been obtained by either application of the intrinsic rough structure or modification of the surface chemical composition. Some typical applications o... 相似文献
10.
Surface modification of polytetrafluoroethylene film using single liquid electrode atmospheric- pressure glow discharge 下载免费PDF全文
Polytetrafluoroethylene films are treated by room temperature helium atmospheric pressure plasma plumes, which are generated with a home-made single liquid electrode plasma device. After plasma treatment, the water contact angle of polytetrafluoroethylene film drops from 114°to 46°and the surface free energy increases from 22.0 mJ/m2 to 59.1 mJ/m2. The optical emission spectrum indicates that there are reactive species such as O2+ , O and He in the plasma plume. After plasma treatment, a highly crosslinking structure is formed on the film surface and the oxygen element is incorporated into the film surface in the forms of -C-O-C-, -C=O, and -O-C=O groups. Over a period of 10 days, the contact angle of the treated film is recovered by only about 10 , which indicates that the plasma surface modification is stable with time. 相似文献