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1.
Summary The detachment of a rubber matrix from a rigid inclusion under monotonic loading and at subsequent relaxation is investigated within two dimensional analysis. Examined are stress–strain experimental data acquired with the help of a test bed equipped with a digital image-acquisition device. The influence of the interfacial bonding strength and the particle size on the detachment process is analyzed. The influence of the interfacial bonding strength is visible in the stress–strain diagram of loading and in the recorded images. The relaxation test reveals no influence of the bonding strength on the stress-relaxation. However, the image analysis indicates a secondary transient creep of the contour of detachment, which depends on the interfacial bonding. 相似文献
2.
Jon Samseth Richard J. Spontak Kell Mortensen 《Journal of Polymer Science.Polymer Physics》1993,31(4):467-474
Poly(siloxaneimide) (PSI) segmented copolymers exhibit organized microdomains if the blocks are sufficiently incompatible. As with neat diblock and triblock copolymers, the processing route employed to prepare films of PSI materials is expected to influence the dimensions and/or morphology of the resultant microstructure. In this work, small-angle neutron scattering (SANS) is utilized to characterize the disordered microstructure found in films of a series of PSI copolymers which are subjected to solvent casting and various thermal treatments. Microstructural dimensions such as the periodicity and correlation length are deduced from the Teubner-Strey (TS) model for disordered microemulsions. The scattering intensity of each copolymer up to q = 5.0 nm?1, where q is the scattering vector, is found to scale as q?2.8+?0.1. Results indicate that processing the materials as cast films or as melt-pressed films allowed to cool slowly has a small, but discernible, effect on microstructural characteristics. SANS profiles of films quenched from elevated temperatures reveal a clear transition in microdomain periodicity, which correlates well with the glass transition temperature of the imide microphase in these and other materials of similar chemical structure. © 1993 John Wiley & Sons, Inc. 相似文献
3.
Roger M. Smith 《Chromatographia》1982,16(1):155-157
Summary The pungent principles of ginger and grains of paradise are examined using a reversed-phase HPLC column. An electrochemical detector is used to selectively detect the phenolic gingerols and shogaols. The retention indices of the compounds are compared using methanowater and acetonitrile-water as eluents.Presented at the 14th International Symposium on Chromatography London, September, 1982 相似文献
4.
Y. BallesterosM.J. Gonzalez de la Huebra M.C. QuintanaP. Hernandez L. Hernandez 《Microchemical Journal》2003,74(2):193-202
The electrochemical behaviour of kinetin (6-furfurylaminopurine) on a carbon paste modified with OV-17 silicone electrode, is studied. The determination of kinetin is possible working in square wave voltammetric techniques, reaching limits of determination of 38.7 ng ml−1. The proposed method was successfully applied to determine the cytokinin in extracts of apples (previously spiked with kinetin) and the obtained results were in accordance with the results obtained with HPLC-UV. 相似文献
5.
《Electroanalysis》2003,15(21):1719-1722
Composite‐electroplating of zinc particles with polytetrafluoroethylene at a zinc substrate resulted in a working electrode which could be used at high negative potentials (to ?2.5 V vs. Ag/AgCl) without significant hydrogen evolution. The electrodes were characterized by SEM and CV and were used to detect organochloride compounds in a water‐acetonitrile mixture, by potential step methods. 相似文献
6.
A study on expansion flow inside a nozzle considering full mechanism chemistry of hydrogen and oxygen was carried out. In this study, a full implicit scheme for turbulent reactive flow was obtained by combining the second order TVD scheme of Yee and Harten (1987, Implicit TVD schemes for hyperbolic conservation laws in curvilinear coordinates. American Institute of Aeronautics and Astronautics Journal, 25(2), 266–274) with the efficient implicit lower-upper scheme of Shuen and Yoon (1989, Numerical study of chemically reacting flows using a lower-upper symmetric successive overrelaxation scheme. American Institute of Aeronautics and Astronautics Journal, 27(12), 1752–1756). The species equations, Navier–Stokes equations and turbulence model were implemented in the numerical scheme and solved in conjunction with full detailed finite rate chemistry. The numerical scheme is verified by comparison with experimental results of a converging–diverging nozzle. Effects of inlet pressure, temperature and fuel-oxidant mass ratio on nozzle flow field were studied. Variation of chemical species under different conditions was investigated by considering a chemical mechanism. Results show that increasing inlet pressure increases the rate of reactions due to increasing the concentration of reactants. For lower inlet pressure the radical H increases slightly in the diverging part of the nozzle, while for higher pressures it decreases along the nozzle. Inlet fuel–oxidant mass ratio affects the variation of all species with a greater effect for a near stoichiometric ratio. It was also shown that a higher inlet temperature provides a more enhanced reaction zone in the diverging part of the nozzle. 相似文献
7.
《Ultrasonics sonochemistry》2014,21(2):549-553
The present work reports a novel dual-pulse ultrasound enhanced electrochemical degradation (US-ECD) process that synchronizes alternatively ultrasound pulses and potential pulses to degrade nitrobenzene in aqueous solution with a high percentage degradation and low energy consumption. In comparison to the test results generated from the conventional US-ECD and original electrochemical degradation (ECD) process, the dual-pulse US-ECD process increased degradation percentages to nitrobenzene by 2% and 17%, respectively, while energy used in the pulse process was only about 46.5% of that was used in the conventional US-ECD process. Test results demonstrated a superior performance of the dual-pulse US-ECD process over those of other conventional ones. Impacts of pulse mode, initial pH value, cell voltage, supporting electrolyte concentration and ultrasonic power on the process performances were investigated. With operation conditions optimized in the study at pH = 3.0, cell voltage = 10 V, ultrasonic power = 48.84 W, electrolyte concentration = 0.1 M and an experiment running time of 30 min, the percentage degradation of nitrobenzene could reach 80% (US pulse time = 50 ms and ECD pulse time = 50 ms). This process provided a reliable and effective technical approach to degrade nitrobenzene in aqueous solution and significantly reduced energy consumption in comparison to the conventional US-ECD or original ECD treatment. 相似文献
8.
The autoxidation of vitamin C has been studied in acetonitrile by electronic spectroscopy. Some interesting data on the role of acetonitrile in autoxidation have been obtained, perhaps for the first time. A parallelism between hydroxyl ions and CH2CN−, the ions from the self-ionization of acetonitrile, has been established. The CH2CN− anion is similar to hydroxyl anions in initiating and propagating the decomposition of ascorbic acid, at least in this system. The intermediates involved in the overall reaction in nonaqueous media have been identified by simple means.__________Published in Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 2, pp. 274–276, March–April, 2005. 相似文献
9.
The electrochemical reduction of nitric oxide in the presence of the excess oxygen was reviewed. It was shown that the selectivity
and activity of the cathodes is strongly dependent on the composition and on the microstructure of the cathode material. A
concept of electrochemical reactor with multilayer electro-catalytic electrode was proposed and successfully designed in Advanced
Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Nagoya, Japan.
The typical values of current efficiency in such electrochemical reactors are of the order of 10–20% at gas composition: 1,000 ppm
NO and 2% O2 balanced in He and at gas flow rate 50 ml/min. The value of current efficiency depends on the functional multi-layer electrode
composition, structure, and operating temperature. Such electrochemical reactors show the value of NO/O2 selectivity (ν
sel) higher than 5 (ν
sel > 5) at intermediate temperature and up to ν
sel = 25 at low temperature operation. It was shown that multilayer electro-catalytic electrode should consist at list from three
main functional layers: cathode, electro-catalytic electrode, covering layer, in order to operate as an electrode with high
selectivity. 相似文献
10.
Yoshimitsu K Nishihara Y Okamoto D Ushijima Y Nishie A Yamaguchi K Taketomi A Honda H 《Magnetic resonance imaging》2012,30(6):854-859