Generic replica symmetric field-theory for short range Ising spin glasses

Symmetry considerations and a direct, Hubbard-Stratonovich type, derivation are used to construct a replica field-theory relevant to the study of the spin glass transition of short range models in a magnetic field. A mean-field treatment reveals that two different types of transitions exist, whenever the replica number n is kept larger than zero. The Sherrington-Kirkpatrick critical point in zero magnetic field between the paramagnet and replica magnet (a replica symmetric phase with a nonzero spin glass order parameter) separates from the de Almeida-Thouless line, along which replica symmetry breaking occurs. We argue that for studying the de Almeida-Thouless transition around the upper critical dimension d = 6, it is necessary to use the generic cubic model with all the three bare masses and eight cubic couplings. The critical role n may play is also emphasized. To make perturbative calculations feasible, a new representation of the cubic interaction is introduced. To illustrate the method, we compute the masses in one-loop order. Some technical details and a list of vertex rules are presented to help future renormalisation-group calculations. Received 9 October 2001     

Electron-phonon interaction in tetrahedral semiconductors

Considerable progress has been made in recent years in the field of ab initio calculations of electronic band structures of semiconductors and insulators. The one-electron states (and the concomitant two-particle excitations) have been obtained without adjustable parameters, with a high degree of reliability. Also, more recently, the electron-hole excitation frequencies responsible for optical spectra have been calculated. These calculations, however, are performed with the constituent atoms fixed in their crystallographic positions and thus neglect the effects of the lattice vibrations (i.e. electron-phonon interaction) which can be rather large, even larger than the error bars assumed for ab initio calculations.Effects of electron-phonon interactions on the band structure can be experimentally investigated in detail by measuring the temperature dependence of energy gaps or critical points (van Hove singularities) of the optical excitation spectra. These studies have been complemented in recent years by observing the dependence of such spectra on isotopic mass whenever different stable isotopes of a given atom are available at affordable prices. In crystals composed of different atoms, the effect of the vibration of each separate atom can thus be investigated by isotopic substitution. Because of the zero-point vibrations, such effects are present even at zero temperature (T=0).In this paper, we discuss state-of-the-art calculations of the dielectric function spectra and compare them with experimental results, with emphasis on the differences introduced by the electron-phonon interaction. The temperature dependence of various optical parameters will be described by means of one or two (in a few cases three) Einstein oscillators, except at the lowest temperatures where the T⁴ law (contrary to the Varshni T² result) will be shown to apply. Increasing an isotopic mass increases the energy gaps, except in the case of monovalent Cu (e.g. CuCl) and possibly Ag (e.g. AgGaS₂). It will be shown that the gaps of tetrahedral materials containing an element of the first row of the periodic table (C,N,O) are strongly affected by the electron-phonon interaction. It will be conjectured that this effect is related to the superconductivity recently observed in heavily boron-doped carbon.     

Localising gravity in composite monopole brane worlds without bulk cosmological constant

We study a 7-dimensional brane world scenario with a Ricci-flat 3-brane residing in the core of a composite monopole defect, i.e., a defect composed of a 't Hooft–Polyakov and a global monopole. Admitting a direct interaction between the two bosonic sectors of the theory, we analyse the structure of the space–time in the limits of small, respectively large direct interaction coupling constant. For large direct interaction, the global monopole disappears from the system and leaves behind a negative cosmological constant in the bulk such that gravity-localising solutions are possible without a priori introduction of a bulk cosmological constant.     

Optical properties of in situ doped and undoped titania nanocatalysts and doped titania sol-gel nanofilms

In this paper we present spectroscopic properties of doped and undoped titanium dioxide (TiO₂) as nanofilms prepared by the sol-gel process with rhodamine 6G doping and studied by photoacoustic absorption, excitation and emission spectroscopy. The absorption spectra of TiO₂ thin films doped with rhodamine 6G at very low concentration during their preparation show two absorption bands, one at 2.3 eV attributed to molecular dimmer formation, which is responsible for the fluorescence quenching of the sample and the other at 3.0 eV attributed to TiO₂ absorption, which subsequently yields a strong emission band at 600 nm. The electronic band structure and optical properties of the rutile phase of TiO₂ are calculated employing a fully relativistic, full-potential, linearized, augmented plane-wave (FPLAPW) method within the local density approximation (LDA). Comparison of this calculation with experimental data for TiO₂ films prepared for undoped sol-gels and by sputtering is performed.     

Algebraic structure of association schemes of prime order

Finite groups of prime order must be cyclic. It is natural to ask what about association schemes of prime order. In this paper, we will give an answer to this question. An association scheme of prime order is commutative, and its valencies of nontrivial relations and multiplicities of nontrivial irreducible characters are constant. Moreover, if we suppose that the minimal splitting field is an abelian extension of the field of rational numbers, then the character table is the same as that of a Schurian scheme.     

Quantum HeisenbergS=1/2 spin glass with ferromagnetic coupling and random Dzyaloshinskii-Moriya interactions

By means of the generalized static replica symmetric spin glass theory, a quantum HeisenbergS=1/2 spin glass model with the infinite-ranged random Dzyaloshinskii-Moriya (DM) interaction and ferromagnetic coupling is investigated. The dependence of entropy, specific heat, susceptibility and the corresponding order parameters on temperature is studied numerically for different ferromagnetic interactions and fixed anisotropy. Two spin glass phases has been found including transverse and mixed spin glass phases. It has been shown that the local susceptibility exhibits double-cusp features for different ferromagnetic coupling (J ₀). Phase transition poins are found in the specific heat-temperature plane at various ferromagnetic coupling values. Additionally, the dependence of the spontaneous moment on temperature is calculated.     

Effect of isotopic mass on the photoluminescence spectra of zinc oxide

ZnO is a wurtzite-type semiconductor at ambient conditions whose natural composition consists of almost pure ¹⁶O and a mixture of 48.6% ⁶⁴Zn, 27.9% ⁶⁶Zn, 4.1% ⁶⁷Zn, 18.8% ⁶⁸Zn, and 0.6% ⁷⁰Zn. In this work, we report a photoluminescence study of different samples of isotopically pure and natural zinc oxide between 15 and 300 K. The isotopic coefficients of the bound exciton energy have been obtained and compared with previous values for the shift of the free A exciton energy. The isotopic coefficients of the bound exciton energy have allowed us to estimate the contribution of the zinc and the oxygen vibrations to the bandgap renormalization by electron-phonon interaction. A two-oscillator model based on the zinc and oxygen renormalization energies has been used to account for the temperature dependence of the bandgap in ZnO.     

Resonance Raman spectroscopy of Ga1−xAlxAs mediated via compositional variation

A specially prepared Ga_1−xAl_xAs sample with a laterally graded alloy composition has allowed a novel investigation of resonance Raman scattering from the optical phonons. Instead of varying the exciting light energy, the resonance is probed by changing the alloy composition at fixed incident energy. Both incoming and outgoing resonances are observed at the direct gap of the alloy, free of the usual overwhelming photoluminescence background.     

A flower-like Ising model. Thermodynamic properties

We consider a flower-like Ising model, in which there are some additional bonds (in the “flower-core”) compared to a pure Ising chain. To understand the behaviour of this system and particularly the competition between ferromagnetic (usual) bonds along the chain and antiferromagnetic (additional) bonds across the chain, we study analytically and iteratively the main thermodynamic quantities. Very interesting is, in the zero-field and zero-temperature limit, the behaviour of the magnetization and the susceptibility, closely related to the ground state configurations and their degeneracies. This degeneracy explains the existence of non-zero entropy at zero temperature, in our results. Also, this model could be useful for the experimental investigations in studying the saturation curves for the enzyme kinetics or the melting curves for DNA-denaturation in some flower-like configurations.     

A model of adsorption at liquid-solid interface involving association in the bulk phase

A model of monolayer adsorption of binary liquid mixtures on homogeneous and heterogeneous solid surfaces involving association of one component in the bulk phase is discussed. Suitable model calculations, illustrating association and heterogeneity effects, have been performed according to an equation derived for adsorption excess. This equation has been examined by using the experimental data of adsorption of alcohols from benzene andn-heptane on silica gel.

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Adsorptionsmodell für die Grenzfläche Feststoff-Flüssigkeit unter Berücksichtigung der Assoziation in der Flüssigkeitsphase

Zusammenfassung Es wird ein Adsorptionsmodell binärer, flüssiger Mischungen an homogenen und heterogenen Oberflächen von Feststoffen unter Beachtung der Assoziation eines der Bestandteile in der Flüssigkeitsphase diskutiert. Mit der aus dem Oberflächenüberschuß abgeleiteten Gleichung wurden entsprechende Modellberechnungen durchgeführt, die die mit Assoziation und Heterogenität verbundenen Effekte illustrieren. Die Gleichung wurde für die experimentellen Daten der Alkoholadsorption aus Benzol undn-Heptan an Kieselgel überprüft.