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1.
Hydrodynamic cavitation experiments in microfluidic systems have been performed with an aqueous solution of luminol as the working fluid. In order to identify where and how much reactive radical species are formed by the violent bubble collapse, the resulting chemiluminescent oxidation reaction of luminol was scrutinized downstream of a constriction in the microchannel. An original method was developed in order to map the intensity of chemiluminescence emitted from the micro-flow, allowing us to localize the region where radicals are produced. Time averaged void fraction measurements performed by laser induced fluorescence experiments were also used to determine the cavitation cloud position. The combination void fraction and chemiluminescence two-dimensional mapping demonstrated that the maximum chemiluminescent intensity area was found just downstream of the cavitation clouds. Furthermore, the radical yield can be obtained with our single photon counting technique. The maximum radical production rates of 1.2*107 OH/s and radical production per processed liquid volume of 2.15*1010 HO/l were observed. The proposed technique allows for two-dimensional characterisation of radical production in the microfluidic flow and could be a quick, non-intrusive way to optimise hydrodynamic cavitation reactor design and operating parameters, leading to enhancements in wastewater treatments and other process intensifications. 相似文献
2.
《Current Applied Physics》2020,20(1):82-88
A detailed investigation about the effect of Sc2O3: 1 mol%Ho3+/5 mol%Yb3+ co-doped with Ce4+ ions prepared by sol-gel methods was performed systematically. Under the excitation of 980 nm laser diode, both green emission (553 nm, 5F4/5S2→5I8) and red emission (672 nm, 5F5→5I8) were both observed in the emission spectra of the samples, which were found to be two-photon process and sensitized by Yb3+ ions. With the increasing of Ce4+ ions, the up-conversion green emission intensity are increased by 6.52, 8.69, 10.85, 13.92 and 16.66 fold, corresponding to the Ce4+ ions concentrations from 5 mol% to 13 mol%, respectively. The number of photons are necessary to populate the upper emitting state decreases to 2 and the infrared absorption coefficient is reduced, when the Ce4+ ions concentration increase to 13 mol%. Ce4+ ions play an important role in tailoring the local crystal field around Ho3+ ions, lowering the highest phonon cut-off energy of matrix and reducing the infrared absorption coefficient, thus hindering the non-radiative processes, which contribute to the increased emission intensity. The excellent enhancement makes it a promising multifunctional optical luminescence material. 相似文献
3.
4.
Self‐Assembly and Gelation of Poly(aryl ether) Dendrons Containing Hydrazide Units: Factors Controlling the Formation of Helical Structures 下载免费PDF全文
Partha Malakar Prof. Dr. Edamana Prasad 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(13):5093-5100
Self‐assembly of AB2 and AB3 type low molecular weight poly(aryl ether) dendrons that contain hydrazide units were used to investigate mechanistic aspects of helical structure formation during self‐assembly. The results suggest that there are three important aspects that control helical structure formation in such systems with acyl hydrazide/hydrazone linkage: i) J‐type aggregation, ii) the hydrogen‐bond donor/acceptor ability of the solvent, and iii) the dielectric constant of the solvent. The monomer units self‐assemble to form dimer structures through hydrogen‐bonding and further assembly of the hydrogen‐bonded dimers leads to macroscopic chirality in the present case. Dimer formation was confirmed by NMR spectroscopy and by mass spectrometry. The self‐assembly in the system was driven by hydrogen‐bonding and π–π stacking interactions. The morphology of the aggregates formed was examined by scanning electron microscopy, and the analysis suggests that aprotic solvent systems facilitate helical fibre formation, whereas introduction of protic solvents results in the formation of flat ribbons. This detailed mechanistic study suggests that the self‐assembly follows a nucleation–elongation model to form helical structures, rather than the isodesmic model. 相似文献
5.
6.
Lu Chuanrong 《数学年刊B辑(英文版)》1997,18(1):71-78
Let $\{\xi_{\bold t}, {\bold t}
\in {\bold Z}^d\}$ be a nonuniform $\varphi$-mixing strictly stationary
real random field with
$E\xi_{\bold 0}=0, E|\xi_{\bold 0}|^{2+\delta}<\infty$ for some
$0<\delta<1$. A sufficient
condition is given for the sequence of partial sum set-indexed process
$\{Z_n(A),\ A\in \Cal A\}$ to converge to Brownian motion. By a direct
calculation, the author shows
that the result holds for a more general class of set index ${\Cal A}$, where
${\Cal A}$ is assumed only to have the metric entropy exponent $r, 0相似文献
7.
The large deviation principle (LDP) which has been effectively used in queueing analysis is the sample path LDP, the LDP in a function space endowed with the uniform topology. Chang [5] has shown that in the discrete-time G/D/1 queueing system under the FIFO discipline, the departure process satisfies the sample path LDP if so does the arrival process. In this paper, we consider arrival processes satisfying the LDP in a space of measures endowed with the weak* topology (Lynch and Sethuraman [12]) which holds under a weaker condition. It is shown that in the queueing system mentioned above, the departure processes still satisfies the sample path LDP. Our result thus covers arrival processes which can be ruled out in the work of Chang [5]. The result is then applied to obtain the exponential decay rate of the queue length probability in an intree network as was obtained by Chang [5], who considered the arrival process satisfying the sample path LDP. 相似文献
8.
Y. Wardi 《Journal of Optimization Theory and Applications》1989,61(3):473-485
A stochastic algorithm for finding stationary points of real-valued functions defined on a Euclidean space is analyzed. It is based on the Robbins-Monro stochastic approximation procedure. Gradient evaluations are done by means of Monte Carlo simulations. At each iteratex
i
, one sample point is drawn from an underlying probability space, based on which the gradient is approximated. The descent direction is against the approximation of the gradient, and the stepsize is 1/i. It is shown that, under broad conditions, w.p.1 if the sequence of iteratesx
1,x
2,...generated by the algorithm is bounded, then all of its accumulation points are stationary. 相似文献
9.
José E. Valdés 《Operations Research Letters》2006,34(1):49-52
Components C1 and C2 form a series system. Suppose we can allocate the spare R1 in parallel with C1 and the spare R2 in parallel with C2, or otherwise, allocate R1 with C2 and R2 with C1. In this paper, we compare these two options using hazard rate ordering. 相似文献
10.
Fabio Schoen 《Journal of Global Optimization》1991,1(3):207-228
In this paper stochastic algorithms for global optimization are reviewed. After a brief introduction on random-search techniques, a more detailed analysis is carried out on the application of simulated annealing to continuous global optimization. The aim of such an analysis is mainly that of presenting recent papers on the subject, which have received only scarce attention in the most recent published surveys. Finally a very brief presentation of clustering techniques is given. 相似文献