利用爆磁压缩发生器产生高功率脉冲高电压

 爆磁压缩发生器产生脉冲高电压技术可以用于产生高功率微波及强电磁脉冲的实验研究。给出了利用螺旋型爆磁压缩发生器（HEMG）驱动电爆炸丝功率调节系统产生高功率脉冲高电压的实验方法和主要的结果。在利用HEMG驱动电爆炸丝断路开关（EEOS）产生脉冲高电压实验中，获得了最高电压700~800kV,功率大于20GW的脉冲输出。     

Analysis of concentration patterns in volcanic rocks: Insights into dynamics of highly explosive volcanic eruptions

In this contribution we present new data resulting from the analysis of concentration patterns of mixed juvenile fragments ejected by a highly explosive volcanic eruption that occurred on Salina Island (Aeolian Islands, Italy) and our aim is to identify the fluid-dynamic regime characterizing the magma mixing process. Concentration patterns are studied by calculating the power spectrum of concentration variability along transects crossing the magma mixing structures. Results indicate that the slope of power spectrum has an average value of about −5/3, according to Kolmogorov law of turbulence, and suggest that the magma mixing process, in the studied conditions, can be approximated by considering the passive scalar mixing hypothesis in homogeneous isotropic turbulent flow. These results represent a first step towards a better understanding of magma mixing processes associated to highly explosive volcanic eruptions and this first step is taken by studying concentration patterns in volcanic rocks by coupling petrological and non-linear dynamics methods.     

轴线起爆式螺线管型爆磁压缩发生器理论模型

 对轴线起爆式螺线管型爆磁压缩发生器进行了理论模型研究，建立了爆炸管的一维爆轰驱动模型、螺线管内空间磁场强度分布模型、爆炸管外表面磁压力模型和发生器系统的等效电路模型等，对此类发生器的物理过程进行系统描述。在此基础上，编制了相应的零维数值模拟程序CEMG 1.0，利用该程序分别对四种不同模型参数的发生器进行了理论计算和参数优化，并对其中一模型发生器爆炸管外表面的磁压力及其引起的剩余电感进行了计算，给出了剩余电感与初始输入条件及负载电感的关系，从而得到该模型的输出性能极限。对理论模型的正确性进行了实例验算证明。     

毛细管电泳在火炸药分析中的应用

综述了近年来毛细管电泳在火炸药领域的应用现状，包括各种分离模式、检测器以及毛细管电泳芯片的应用，并对该技术在火炸药分析中的应用前景作了展望，提出了新的发展方向。引用文献45篇。     

Sensitive Voltammetric Sensing of the 2,3‐Dimethyl‐2,3‐dinitrobutane (Dmnb) Explosive Taggant

The highly sensitive voltammetric detection of the 2,3‐dimethyl‐2,3‐dinitrobutane (DMNB), a required additive to commercial plastic explosives, is described. The protocol relies on a fast square‐wave voltammetric measurement of the DMNB explosive taggant at an unmodified carbon fiber electrode using a phosphate buffer (pH 7.0) solution. Different solutions and working electrodes were evaluated. Under the optimal conditions, a linear response is observed over the 300–3000 μg/L DMNB concentration range examined, with a detection limit of 60 μg/L. A highly stable response, with a relative standard deviation (RSD) of 2.6%, is observed for 30 repetitive measurements. Such electrochemical approach offers great promise for a simple, rapid, sensitive and inexpensive field screening of plastic explosives. Preliminary data illustrate the utility of electrochemical detection for electrophoretic microchips for the simultaneous measurements of DMNB, cyclotrimethylenetrinitramine (RDX) and pentaerythritoltetranitrate (PETN).     

Comparison of an antibody and its recombinant derivative for the detection of the small molecule explosive 2,4,6-trinitrotoluene

Antibodies are commonly used as recognition elements in immunoassays because of their high specificity and affinity, and have seen extensive use in competitive assays for the detection of small molecules. However, these complex molecules require production either in animals or by mammalian cell cultures, and are not easily tailored through genetic manipulation. Single chain antibodies (scFv), recombinantly expressed molecules consisting of only the antibody's binding region joined via a linking peptide, can provide an alternative to intact antibodies. We describe the characterization of a new monoclonal antibody (mAb), 2G5B5, able to detect the small molecule explosive 2,4,6-trinitrotoluene (TNT) and the scFv derived from its variable regions. The mAb and scFv were tested by surface plasmon resonance to determine their affinity for an immobilized TNT surrogate; dissociation constants were determined to be 1.5 × 10⁻¹³ M and 4.8 × 10⁻¹⁰ M respectively. Circular dichroism was used to determine their melting temperatures. The mAb is more stable melting at ∼75 °C while the scFv melts at ∼65 °C. The recognition elements were incorporated into a competitive assay format using a bead-based multiplexing platform to examine their sensitivity and specificity. The scFv was able to detect TNT ∼10-fold more sensitively than the mAb in this assay format, allowing detection of TNT concentrations down to at least 1 μg L⁻¹. The 2G5B gave similar detection limits to a commercial anti-TNT mAb, but was less specific, recognizing 1,3,5-trinitrobenzene (TNB) equally well as TNT.     

Nitro Derivatives of Parabanic Acid as Potential Explosives: A Theoretical Study

This work deals with certain parabanic acid (PA) derivatives because they possess great calculated density (>1.8 g · cm^–3) and high content of nitrogen (26 %). Computed ballistic properties of eight different parabanic acid derivatives are presented. The structures were optimized at the B3LYP/6‐31G(d, p) level. The calculated data for PA are found to be compatible with the experimental X‐ray data. The detonation performance analyses were done using empirical Kamlet‐Jacobs equations. Additionally, detonation products were assigned and power index were calculated. All the compounds considered are powerful candidates for high energy materials.     

Large Amplitude Torsions in Nitrotoluene Isomers Studied by Rotational Spectroscopy and Quantum Chemistry Calculations

Rotational spectra of ortho-nitrotoluene (2-NT) and para-nitrotoluene (4-NT) have been recorded at low and room temperatures using a supersonic jet Fourier Transform microwave (MW) spectrometer and a millimeter-wave frequency multiplier chain, respectively. Supported by quantum chemistry calculations, the spectral analysis of pure rotation lines in the vibrational ground state has allowed to characterise the rotational energy, the hyperfine structure due to the ¹⁴N nucleus and the internal rotation splittings arising from the methyl group. For 2-NT, an anisotropic internal rotation of coupled −CH₃ and −NO₂ torsional motions was identified by quantum chemistry calculations and discussed from the results of the MW analysis. The study of the internal rotation splittings in the spectra of three NT isomers allowed to characterise the internal rotation potentials of the methyl group and to compare them with other mono-substituted toluene derivatives in order to study the isomeric influence on the internal rotation barrier.     

同轴型爆磁压缩发生器1维磁扩散模型

 基于１维爆轰驱动模型、爆炸管与金属固壁的１维磁扩散模型及回路等效电路模型，编制了关于轴线起爆大电流同轴型爆磁压缩发生器的数值模拟程序CEMG2.0。应用该程序对洛斯·阿拉莫斯实验室设计试验的43 cm长Ranchero发生器进行了对比模拟，结果证明CEMG2.0程序所采用的模型是合理的，可以应用于今后同类发生器的优化设计。     

Blast wave measurements close to explosive charges

The paper reports the results of experimental measurements of the reflection pressures close to spherical charges of TNT. These measurements were made using a pressure bar technique. Charge weights of up to 3.6 kg were used, with the reflecting plane in the range 25 to 300 mm from the charge surface.A possible wave interaction model is discussed, to account for the observed pressure profiles, and its qualitative correctness checked by means of numerical simulation.This article was processed using Springer-Verlag T_EX Shock Waves macro package 1.0 and the AMS fonts, developed by the American Mathematical Society.