Linearization of column responses by correlation chromatography. Separation improvement and reduction of undesired adsorption effects

Summary Experiments and simulations prove that correlation chromatography can greatly reduce the disadvantage of a non-linear response of the chromatographic column. A factor that has been accepted as being an important source of error in correlation or multiplex chromatography, has been shown not to be. Separations affected, improve dramatically when correlation chromatography is used, and a substantial amount of correlation noise only arises when there is a large difference in separation between a conventional chromatogram and a correlogram.A model has been developed for simulating these nonlinearities. It is shown that, especially for correlation chromatography, the simulation results match the practical measurements very well.     

Generic Transport Aft-body Drag Reduction using Active Flow Control

Active flow-separation control is an effective and efficient mean for drag reduction and unsteady load alleviation resulting from locally or massively separated flow. Such a situation occurs in configurations where the aerodynamic performance is of secondary importance to functionality. The performance of heavy transport helicopters and aeroplanes, having a large, and almost flat, aft loading ramp suffer from the poor aerodynamics of the aft body. Hence, a combined experimental and numerical investigation was undertaken on a generic transport aeroplane/helicopter configuration. The experimental study provided surface pressures, direct drag measurements, surface and smoke flow visualization. The baseline flow was numerically analyzed, using finite volume solutions of the RANS equations. The baseline flow around the model was insensitive to the Reynolds number in the range it was tested. The flow separating from the aft body was characterized by two main sources of drag and unsteadiness. The first is a separation bubble residing at the lower ramp corner and the second is a pair of vortex systems developing and separating from the sides of the ramp. As the model incidence is decreased, the pair of vortex systems also penetrates deeper towards the centerline of the ramp, decreasing the pressure and increasing the drag. As expected, the ramp lower corner bubble was highly receptive to periodic excitation introduced from four addressable piezo-fluidic actuators situated at the ramp lower corner. Total drag was reduced by 3–11%, depending on the model incidence. There are indications that the flow in the wake of the model is also significantly steadier when the bubble at the lower ramp corner is eliminated. The vortex system is tighter and steadier when the ramp-corner bubble is eliminated.     

Pre—Separation Axioms in Fuzzifying Topology

1　 IntroductionYing[5,6 ] introduced and elementally developed so called fuzzifying topology with the semanticmethod of continuous valued L ogic.Shen[7] introduced and studied T0 -,T1-,T2 (Hausdorff) -,T3(regularity) -,T4 (normality) -separation axioms in fuzzifying topology.In [3 ]the concepts of thefamily of fuzzifying pre-open sets,fuzzifying pre-neighbourhood structure of a point and fuzzifyingpre-closure are introduced and studied.It is worth to mention that pre-separation axioms are …     

数字全息中再现像分离问题的研究

详细分析了数字全息的再现像分离条件,指出数字全息和普通全息的再现像分离条件之间的区别,同时也讨论了再现条件对数字全息记录光路的要求,同时给出一种能部分避免再现像重叠的处理方法,并做出相应的实验验证.     

拓扑系统的紧性和分离性

考察拓扑系统的两种紧性——空间式紧和locale式紧,给出紧性的若干刻画,讨论了两种紧性的相互关系,证明了拓扑系统的两种紧性都是拓扑空间紧性的良好推广,说明了紧拓扑系统的闭子拓扑系统、有限和系统以及积系统仍是紧拓扑系统。最后在拓扑系统中考察了紧性加强分离性的问题,得到了紧,(强)T2拓扑系统为(强)T3,(强)T4拓扑系统等结论,并用理想收敛刻画了拓扑系统的强T2分离性。     

Microelectromagnet for magnetic manipulation in lab-on-a-chip systems

We demonstrate a simple scheme for fabrication of microelectromagnets consisting of planar spiral coils semi-encapsulated in soft magnetic yokes using conventional microfabrication techniques. The microelectromagnets are suitable for applications operating at frequencies below 250 kHz. Conventional fabrication schemes for planar microelectromagnets typically rely on five mask steps. We allow the current to flow in the soft magnetic yoke and thereby two mask steps are eliminated. We have characterized the electromagnets electrically, the results agree well with theory, and the implications arising from current flowing in the magnetic yoke are discussed. We have integrated the microelectromagnets with microfluidic channels, and demonstrated separation of commercially available magnetic beads from a fluid in a microfluidic system, i.e. a lab-on-a-chip system.     

Synthesis and simple separation of β-pyrrole sulfonated porphycenes

New water-soluble porphycenes having sulfonic acid groups at the β-pyrrolic positions were synthesized and characterized by UV-vis, NMR, IR, and mass spectroscopy as well as elemental analyses. The series of mono- to tri-sulfonato derivatives were simply separated by the extraction method.     

流通池介质交换差示脉冲阳极溶出伏安法用于多元素重叠峰的分离及其同时测定

本文用流通池介质交换差示脉冲阳极溶出伏安法在盐酸介质中富集,而以碳酸钠-碳酸氢钠缓冲溶液为溶出介质,有效地分离了酸性介质中Cu(Ⅱ)、Sb(Ⅲ)、Pb(Ⅱ)、Tl(Ⅰ)、Cd(Ⅱ)、In(Ⅲ)的重叠溶出峰,实现了多离子的同时测定。