全文获取类型
收费全文 | 390篇 |
免费 | 24篇 |
国内免费 | 19篇 |
专业分类
化学 | 333篇 |
力学 | 9篇 |
综合类 | 24篇 |
数学 | 10篇 |
物理学 | 57篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 9篇 |
2021年 | 20篇 |
2020年 | 12篇 |
2019年 | 12篇 |
2018年 | 10篇 |
2017年 | 16篇 |
2016年 | 18篇 |
2015年 | 7篇 |
2014年 | 14篇 |
2013年 | 32篇 |
2012年 | 16篇 |
2011年 | 19篇 |
2010年 | 31篇 |
2009年 | 28篇 |
2008年 | 24篇 |
2007年 | 26篇 |
2006年 | 20篇 |
2005年 | 21篇 |
2004年 | 14篇 |
2003年 | 20篇 |
2002年 | 4篇 |
2001年 | 11篇 |
2000年 | 10篇 |
1999年 | 6篇 |
1998年 | 7篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
排序方式: 共有433条查询结果,搜索用时 687 毫秒
1.
活性污泥法处理城市污水中鼓风和纯氧两种曝气方法的比较 总被引:1,自引:0,他引:1
对活性污泥法处理城市污水中鼓风曝气和纯氧(或富氧)曝气这两种方法,从曝气设备结构、特点、工艺技术指标、运行管理及经济性等方面进行了分析和比较。 相似文献
2.
3.
1前言流化床焚烧污犯是近年来发达国家广泛采用的方法,它能很好地实现污泥的稳定化、无害化、减容化和资源化处理。燃煤流化床锅炉污染物排放方面已做了大量的研究工作,由于污泥与煤在结构和性质方面的差异较大,因此有必要对流化床焚烧污泥时污染物排放特性进行研究。本文详细研究了造纸、废水污泥在流化床中焚烧时污泥水份、运行床温及过量空气对NO。和SO。的排放特性及污泥N-+NO。、S-SO。的转化率的影响,并对这两种性质差异较大的污泥焚烧时的NO。和502的生成特性进行了对比分析,取得了许多有价值的结果,为污泥流化床焚烧… 相似文献
4.
建立了离子色谱-质谱联用技术测定活性污泥样品中高氯酸盐的分析方法。以高容量、强亲水性的IonPacAS20(2mm)阴离子交换柱为分析柱,EGC在线产生等浓度KOH为淋洗液,淋洗液经抑制成水后将样品带入质谱检测。ESI-MS-MS以多元反应监测模式监控100.8/84.9、98.8/66.9、100.8/68.9和98.8/82.9离子对,以98.8/82.9离子对的峰面积进行定量。该方法对高氯酸盐的检出限(S/N=3)为0.01μg/L,高氯酸盐在0.05~100μg/L浓度范围内具有良好的线性,线性相关系数r=0.9988。0.2μg/L的标准溶液重复进样9次,高氯酸盐峰面积的相对标准偏差(RSD)为2.3%。运用该方法测定采自不同地区的活性污泥样品中的高氯酸盐,并对样品加标回收,得回收率在88.5%~102.2%之间。 相似文献
5.
Rivard C. J. Himmel M. E. Vinzant T. B. Adney W. S. Wyman C. E. Grohmann K. 《Applied biochemistry and biotechnology》1989,(1):461-478
Economic evaluations of the capital costs for anaerobic digestion systems for gas production show that the reactor is a significant
cost component. The successful application of high solids digestion of processed MSW (e.g., greater than 10% solids within
the digester) would allow a decrease in reactor volume with maintenance of relatively high gas production rates. However,
high solids slurries do not mix well in conventional stirred tank reactors. A horizontal shaft, hydraulically driven reactor
was designed and fabricated to test the anaerobic digestion of high solids concentrations. Digester performance was evaluated
as a function of experimental parameters such as nutrient requirements, feeding rates, pH control, and agitator design/ rotation
speed; horsepower of mixing was also evaluated for the reactor. Several startup protocols were examined to obtain a biologically
stable anaerobic fermentation at high solids levels. 相似文献
6.
Uncoupled metabolism stimulated by chemical uncoupler and oxic-settling-anaerobic combined process to reduce excess sludge production 总被引:1,自引:0,他引:1
The effects of three uncoupled metabolic systems (conventional activated sludge process with the addition of 3,3′,4′,5-tetrachlorosalicylanilide
[TCS], oxic-settling-anaerobic [OSA] process modified by insertion of a sludge-holding tank in the sludge return line, and
TCS and OSA combined process) on reducing excess sludge production were studied. Compared with the control conventional activated
sludge process, the most effective system was the combined process, which could reduce excess sludge production by 46.90%.
The 180-d operation results confirmed that TCS is an effective chemical uncoupler in reducing the sludge yield but that it
had an adverse effect on substrate removal capability, effluent nitrogen concentration, and sludge settleability. The OSA
process decreased excess sludge production by only 26% but had less adverse effect on effluent quality and could improve sludge
settleability. The effluent total phosphorous concentration of the three systems was slightly lower than of the control unit.
Microbial populations were monitored by both microscopic and molecular biologic analysis method (polymerase chain reaction
[PCR]-denaturing gradient gel electrophoresis [DGGE]). The presence of TCS caused metazoans to disappear and decreased the
number and activity of protozoa. PCR amplification of 16S rRNA and sequent DGGE analysis found a shift in the diversity of
the predominant species. The results imply that OSA combined with the chemical uncoupler process may effectively reduce excess
sludge yield and not affect process performance significantly. 相似文献
7.
D. Choudhury R. C. Borah R. L. Goswamee H. P. Sharmah P. G. Rao 《Journal of Thermal Analysis and Calorimetry》2007,89(3):965-970
Pyrolysis of petroleum refinery sludge has received global acclamation as a clean conversion technique for providing solution
of sludge disposal as well as efficient resource utilization. This communication reports the kinetics study of pyrolysis of
petroleum refinery sludge. Experiments were carried out by means of thermogravimetric analysis at different heating rates
of 5, 10 and 20°C min−1. The pyrolytic reaction is significant in the temperature range of 200–350°C and analysis and evaluation of kinetic parameters
is done in the 100–500°C region of non-isothermal TG curves obtained in nitrogen atmosphere.
The activation energy is calculated by iso-conversional method, then other kinetic parameters are determined by considering
single reaction and two reaction global kinetic model. Two-reaction model is found to fit satisfactorily the experimental
results. 相似文献
8.
Ma Tsz-Chun P. L. Chan H. Lawford H. Chua W. H. Lo Peter Hoifu Yu 《Applied biochemistry and biotechnology》2005,122(1-3):731-739
The first objective of this study was the measurement of physical properties of P(3HB-co-3HV) copolymers with different (hydroxybutyrate)
HB to (hydroxyvalerate) HV ratios produced by Bacillus cereus (TRY2) isolated from activated sludge. The 3HV PHBV copolymers were 0.05, 22.6, 39.2, 54.1, and 69.1 mol%, respectively.
The second objective was to study possible wastewater treatment and production of PHAs at the same time by B. cereus (TRY2) and Pseudomonas spp. (TOB17) (both were isolated from activated sludge), recombinant Bacillus DH5α, and a combination of the above three bacteria. The results were satisfactory; the maximum COD and TOC of the sewage sludge
reduced were 53.5% and 67.5%, respectively. 相似文献
9.
J. Rodriguez-Añón J. Prouupin M. González-Añón L. Núñez-Regueira 《Journal of Thermal Analysis and Calorimetry》1998,52(3):1005-1012
The heating values of municipal solid waste generated in three towns with a population of less than 50 000, situated in Galicia
(Spain), were measured with a static bomb calorimeter. Samples of raw refuse were burnt either as received or after sorting
of the different combustible components. A study was made of samples from controlled and uncontrolled landfills.
The calorific values were compared with those corresponding to a commercial residual derived fuel in order to study the possibility
of using municipal solid waste as a source of recovered energy.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
10.
Development and validation of methods for the trace determination of phthalates in sludge and vegetables 总被引:1,自引:0,他引:1
Sablayrolles C Montréjaud-Vignoles M Benanou D Patria L Treilhou M 《Journal of chromatography. A》2005,1072(2):233-242
A routine method which is simple, quick and precise has been set up and validated for phthalate analysis in environmental samples (tomato plants and sewage sludges). Six phthalates have been studied simultaneously: dimethylphthalate, diethylphthalate, di-n-butylphthalate, n-butylbenzylphthalate, di-2-ethyl-hexyl phthalate (DEHP) and di-n-octylphthalate. Optimization of sample, solvent extraction uses a Soxtec apparatus and extract purification with an a solid-phase extraction cartridge allows between 90 and 110% recovery of phthalates. Precise, sensitive and selective identification and quantifying of analytes is by GC-MS in the single ion monitoring mode. This protocol allows analytes with concentrations as low as 10 microg/kg dry matter (DM) to be determined from small (1-2 g DM) samples. This analytical method has been applied to the phthalate transfer study for agricultural recycling of sludges, where phthalate bioavailability has been studied in aquiculture using two types of experiments. Tomatoes have been grown in containers where the trace organics have been directly introduced as pure substances, and in a second experiment under the same growth conditions, sewage sludge has replaced the pure substances. Transfer of these trace organics has been followed into the various parts of the tomato plant and in general only the DEHP is worthy of note although its percentage transfer remains very low even in an experiment designed to maximize this. 相似文献