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S. E. Boganov M. P. Egorov V. I. Faustov I. V. Krylov O. M. Nefedov R. Becerra R. Walsh 《Russian Chemical Bulletin》2005,54(3):483-511
The results of time resolved gas phase studies of labile germylenes (GeH2 and GeMe2) and dimethylstannylene (SnMe2) reactions reported to date are considered together with data of quantum-chemical investigations of the potential energy surfaces of these systems. Reaction mechanisms are discussed. A comparison of reactivity in the series of carbene analogs, ER2 (E = Si, Ge, Sn, R = H, Me), is made.__________Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 477–505, March, 2005. 相似文献
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