Can a Procedure for the Growth of Single-layer Graphene on Copper be used in Different Chemical Vapor Deposition Reactors?

In the last decade, catalytic chemical vapor deposition (CVD) has been intensively explored for the growth of single-layer graphene (SLG). Despite the scattering of guidelines and procedures, variables such as the surface texture/chemistry of catalyst metal foils, carbon feedstock, and growth process parameters have been well-scrutinized. Still, questions remain on how best to standardize the growth procedure. The possible correlation of procedures between different CVD setups is an example. Here, two thermal CVD reactors were explored to grow graphene on Cu foil. The design of these setups was entirely distinct, one being a “showerhead” cold-wall type, whereas the other represented the popular “tubular” hot-wall type. Upon standardizing the Cu foil surface, it was possible to develop a procedure for cm²-scale SLG growth that differed only by the carrier gas flow rate used in the two reactors.     

平面火花隙三电极开关研制及性能测试

 研制了一种适用于平行板传输连接的平面火花隙三电极开关，开关正负电极为半圆形状，触发电极为细条状。将之替代立体式（半球形电极）火花隙三电极开关并应用于爆炸箔起爆装置中，装置回路参数将得以优化。实验测试了空气间隙为4.12， 3.14和2.2 mm的平面火花隙三电极开关的性能。结果表明，在开关间隙间距一定的情况下，随着电压的升高，开关间隙的放电时延和分散时间呈指数降低，开关电感小于15 nH；对于不同范围内的应用电压，使用不同间隙间距的开关，其分散时间不大于10 ns。该开关应用于较低充电电压（小于10 kV）的脉冲功率装置中，与立体式火花隙三电极开关相比，回路电感降低了约50 nH，放电周期缩短近1/3，峰值电流增加约1/3。     

软X光辐射烧蚀实验方法研究

 用强激光辐照金箔靶，以金箔背侧软X光辐射为基础，提出了软X光辐射烧蚀研究的新靶型、新方法，做了C₈H₈样品辐射烧蚀初步实验。     

A Tin(IV) Porphyrin with Two Axial Organometallic NCN‐Pincer Platinum Units

A tin(IV) porphyrin was combined with two axial NCN‐pincer platinum(II) fragments by utilizing the oxophilicity of the apical positions on the tin atom and the acidic nature of the NCN‐pincer platinum derived benzoic acid. The solid‐state structure determined by X‐ray crystallography revealed some close contacts between the pincer complexes and the meso‐p‐tolyl subsitutents of the porphyrin. It was shown by ¹H NMR spectroscopy that these close contacts were not present in solution and that this compound can potentially act as a novel building block for supramolecular architectures.     

塞曼石墨炉原子吸收光谱法直接测定垃圾焚烧废气中锡

采用钯加抗坏血酸溶液作为基体改进荆，用塞曼效应扣除背景，对消化后的垃圾焚烧废气滤筒直接进行测定。方法的检出限为100pg，线性范围为0．2～4ng，回收率为96．8％～102．0％。     

球形SnO2 纳米微粒的合成及形成机理分析

以SnCl4·5H2 O为主要原料 ,用溶剂热技术在油酸体系中成功地合成了球形SnO2 纳米微粒 ,在无水乙醇体系中合成了菱形的SnO2 纳米微粒 .通过X射线粉末衍射 (XRD) ,选区电子衍射 (SAED)和透射电镜 (TEM )对两种产物进行了表征 ,并对两种产物的形成机理进行了分析 .透射电镜 (TEM)结果表明 :在油酸体系中得到了平均尺寸约为 3.5nm的球形SnO2 纳米微粒 ,此微粒趋向于特殊高的比表面积 ,适合于作气敏探测器材料方面的应用     

Two-dimensional autocorrelation function analysis of smoked foil patterns

Digital image processing techniques have been applied to the analysis of cellular smoked foil patterns from gaseous detonations. In particular, the two-dimensional autocorrelation function is applied to digital cell pattern images and an orientational correlation parameter is calculated. Taking line profiles along the directions of highest correlation provides an unbiased method of determining the mean cell size in each of the two principal directions. By analyzing the width, amplitude and angular position of the orientational correlation plots, information can be extracted concerning the cellular pattern regularity, the relative angular correlation between two sets of transverse waves in two directions, and the mean shape or elongation of the cells within the pattern. The technique is applied to smoked foils from oxyacetylene mixtures with argon dilutions ranging from 0 to 75% to quantify the increase in regularity with argon dilution. This method provides a simple and useful way of analyzing cellular patterns and constitutes a promising technique for improving smoked foil diagnostics.     

腔靶等离子体辐射温度空间分布测量

本文描述了用膜吸收法测量激光等离子体辐射温度空间分布的原理和方法给出了柱形缝靶轴向辐射温度随空间位置变化的特征,对测量结果进行了分析讨论。     

塞曼石墨炉原子吸收光谱法测定粉尘降尘中痕量锡

以KOH熔样,又以KOH作基体改进剂,研究了测定锡的灰化温度、原子化行为和消除干扰及试样前处理的方法,以KOH熔解的粉尘及降尘样液,特别适用于塞曼石墨炉的测定,背景可完全扣除。方法简便、快速、准确,灵敏度和精度高。相对标准偏差为4.0%,回收牢在96.4～110%范围内。     

Topochemically Controlled Redox Reactions in the System In/Sn/Cl

The difference in reactivity of the two modifications of InCl in solid state reactions with SnCl₂ is discussed. It is explained on the basis of semi‐empirical and ab initio calculations giving the density of states diagrams of InCl and the energies of possible disproportionation reactions. Their general features are discussed on the basis of a simple bonding picture for open‐packed structures involving inert pair elements. A detailed analysis of the DOS distribution allows to pinpoint the observed redox instability to a specific structural feature of α‐InCl.