排序方式: 共有44条查询结果,搜索用时 15 毫秒
1.
" 应用浸渍法在不同的焙烧条件(90~500 ℃)制备了一系列Al2O3担载钴基催化剂(质量含量为15%);采用XRD、XPS、程序升温还原对其进行了结构表征和分析,考察其在一氧化碳选择加氢制备清洁燃料用长链烷烃的反应中的催化性能.XPS结果表明,对于在90~200 ℃焙烧的催化剂,仍可观察到未完全分解的硝酸钴的存在;对于在200~500 ℃焙烧的几个催化剂可观察到Co3O4的物相.对于经过几种热处理制备的氧化铝担载的四个纳米钴基催化剂(200~500 ℃热处理),XRD和XPS结果表明四个样品中主要是9 相似文献
2.
We consider the superposition of infinitely many instantons on a circle in . The construction yields a self-dual solution of the Yang-Mills equations with action density concentrated on the ring. We show that this configuration is reducible in which case magnetic charge can be defined in a gauge invariant way. Indeed, we find a unit charge monopole (worldline) on the ring. This is an analytic example of the correlation between monopoles and action/topological density, however with infinite action. We show that both the Maximal Abelian Gauge and the Laplacian Abelian Gauge detect the monopole, while the Polyakov gauge does not. We discuss the implications of this configuration. 相似文献
3.
4.
Cobalt was incorporated into the zirconia support by different methods. The reducibility and activity of the catalysts was
directly related to the preparation methods. Impregnated Co/ZrO2 catalyst showed the highest reduction degree and the highest CO hydrogenation activity. 相似文献
5.
6.
P、As为中心原子的杂多钼酸盐的合成、热稳定性及还原性研究 总被引:2,自引:0,他引:2
在合成(NH4)3PMo12O40和K3PMo12O40的基础上,用改进的方法合成了(NH4)3AsMo12O40和K3AsMo12O40,以FTIR、XRD、TG-DTA、ESR和TPR等手段对其结构、热稳定性和还原性进行了考查,当中心原子由P换成As后,杂多钼酸盐热稳定性下降,还原性提高. 相似文献
7.
CeO2对CuO/Al2O3分散状态及催化性能的影响 总被引:24,自引:0,他引:24
用色谱-液反流动法技术,考察了CuO催化剂对CO的性及添加CeO2对催化活性的影响,并运用XRD,TPR和XPS技术,研究了催化剂的物相结构和还原牧场 生。实验结果表明,CeO2的添加增加了CuO的分散性,使CuO的特征衍射峰消失,从而改善了催化剂的氧化活性。 相似文献
8.
E?ect of Thermal Treatment on Structure and Catalytic Activity of Supported Fischer-Tropsch Nano-Cobalt Catalysts for Clean Fuels 下载免费PDF全文
"A series of 15%Co/Al2O3 catalysts were prepared by incipient wetness impregnation under various calcination conditions (90-500 oC), and were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy experiments (XPS), temperature programmed reduction, and catalytic measurements of hydrogenation of carbon monoxide to long-chained hydrocarbons leading to clean fuels (Fischer-Tropsch synthesis). The results of XPS show the presence of incompletely decomposed cobalt nitrate for catalysts calcined at 90-200 oC, and the presence of Co3O4 for catalysts calcined at 200-500 oC. For the four alumina-supported nano cobalt catalysts with different thermal treatment (200-500 oC), XRD and XPS results illustrated that there were mainly nano Co3O4 crystalite phases of 9-10 nm and the size of cobalt nano-particles did almost not change with the different temperature of thermal treatment. This was different from that of silica-supported cobalt catalysts. The supported cobalt catalyst (CoAp340 sample) calcinated at 340 oC presented a better activity for Fischer Tropsch synthesis to clean fuels, at mild conditions like atmospheric pressure (100 kPa), 1800 mL/g/h and 190 oC; rather than high pressure (2 MPa or more)." 相似文献
9.
Jing LI 《数学年刊B辑(英文版)》2020,41(3):419-440
In this paper, the author establishes a reduction theorem for linear Schr¨odinger equation with finite smooth and time-quasi-periodic potential subject to Dirichlet boundary condition by means of KAM(Kolmogorov-Arnold-Moser) technique. Moreover, it is proved that the corresponding Schr¨odinger operator possesses the property of pure point spectra and zero Lyapunov exponent. 相似文献
10.
Mitja Mastnak 《Linear algebra and its applications》2009,430(7):1838-1848
Motivated by problems concerning simultaneous triangularization, we study the structure of finite, minimal nonabelian groups. Using the structure result of Miller and Moreno we explicitly describe all irreducible representations of such groups. We illustrate the usefulness of results of this type on several examples. 相似文献