首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   4847篇
  免费   559篇
  国内免费   826篇
化学   2724篇
晶体学   34篇
力学   417篇
综合类   32篇
数学   567篇
物理学   2458篇
  2024年   20篇
  2023年   171篇
  2022年   163篇
  2021年   202篇
  2020年   262篇
  2019年   184篇
  2018年   187篇
  2017年   195篇
  2016年   226篇
  2015年   211篇
  2014年   275篇
  2013年   336篇
  2012年   268篇
  2011年   368篇
  2010年   276篇
  2009年   350篇
  2008年   336篇
  2007年   303篇
  2006年   300篇
  2005年   217篇
  2004年   211篇
  2003年   170篇
  2002年   156篇
  2001年   133篇
  2000年   96篇
  1999年   76篇
  1998年   83篇
  1997年   70篇
  1996年   43篇
  1995年   55篇
  1994年   36篇
  1993年   30篇
  1992年   29篇
  1991年   30篇
  1990年   21篇
  1989年   14篇
  1988年   14篇
  1987年   18篇
  1986年   15篇
  1985年   13篇
  1984年   13篇
  1982年   12篇
  1981年   7篇
  1980年   8篇
  1979年   3篇
  1978年   4篇
  1976年   3篇
  1973年   6篇
  1971年   3篇
  1970年   2篇
排序方式: 共有6232条查询结果,搜索用时 187 毫秒
1.
Lithium-sulfur batteries (LSBs) with high energy density and low cost have been recognized as one of the most promising next-generation energy storage systems. Although it has taken decades of development, the practical application of LSBs has been hindered by several inherent obstacles, particularly the severe shuttle effect and sluggish reaction kinetics in the sulfur cathode. Various strategies have been proposed to address these problems via rational design of electrode materials and configurations. Freestanding sulfur cathode could be a promising strategy to improve the sulfur mass loading at the cathode level and energy density of LSBs. This minireview will briefly summary the recent advances in freestanding cathodes for LSBs. The advantages and disadvantages of various freestanding cathodes are discussed and the prospects for the development of flexible cathodes are envisioned.  相似文献   
2.
3.
Quinones are electroactive species that have shown great promise for redox flow batteries due to the ability to tune their properties and to act as both negative and positive electrolytes. The following review outlines highlights of work in the last couple of years working to provide materials with higher stability, solubility, and performance. Developments toward stable negolytes have provided opportunities for potential commercial opportunities when paired with alternate chemistries. However, the stability of quinones in high potential electrolytes is still not sufficient and the number of potential quinones limited.  相似文献   
4.
5.
一类非线性Schr(o)dinger方程的守恒差分法与Fourier谱方法   总被引:1,自引:0,他引:1  
龚玉飞  许传炬 《数学研究》2006,39(4):360-369
考察了一类带导数项的非线性Schrodinger方程的周期边值问题,提出了一种守恒的差分格式,在空间方向上采用Fourier谱方法,证明了格式的稳定性和收敛性.数值试验得到了与理论分析一致的结果.  相似文献   
6.
张赫  王琳  何多慧 《中国物理 C》2006,30(Z1):138-140
介绍了一组合肥光源新高亮度模式的Lattice. 新的设计维持了储存环上所有元件和光束线位置不变,也没有加入新的元件. 取得了较低发射度. 所有直线节处的垂直方向β函数值都很小,适合插入件的运行. 跟踪计算表明新Lattice具有足够大的动力学孔径用于注入和储存粒子.  相似文献   
7.
给出2005年全国部分高校研究生数学建模竞赛D题的研究背景,对参赛论文作了简要评注,并提供了一种参考解答.  相似文献   
8.
高温水蓄冷空调的原理和理论分析   总被引:1,自引:1,他引:0  
介绍了一种新型高温水蓄冷空调方案的原理井进行了理论分析。它可利用高至38℃水的显热或其它材料的相变潜热来蓄冷空调.分析了完全不掺混系统的性能与过冷水流率的关系;给出了完全掺混系统非稳态循环的性能变化;数值计算并讨论了蓄冷水部分掺混系统的温度分层和动态特性、为高温水蓄冷空调系统的设计和运行提供了理论指导.  相似文献   
9.
The present work is concerned with the thermally induced vibration in a homogeneous and isotropic unbounded body with a spherical cavity. The Green and Nagdhi model of thermoelasticity without energy dissipation is employed. The closed form solutions for distributions of displacement, temperature and stresses are obtained. The solutions valid in the case of small frequency are deduced and the results are compared with the corresponding results obtained in other generalized thermoelasticity theories. Numerical results applicable to a copper-like material are also presented graphically and the nature of variations of the physical quantities with radial coordinate and with frequency of vibration is analyzed.  相似文献   
10.
The formation and characterization of some interpolyelectrolyte complex (IPEC) nanoparticles based on poly(sodium 2‐acrylamido‐2‐methylpropanesulfonate) (NaPAMPS), as a function of the polycation structure, polyanion molar mass, and polyion concentration, were followed in this work. Poly(diallyldimethylammonium chloride) and two polycations (PCs) containing (N,N‐dimethyl‐2‐hydroxypropyleneammonium chloride) units in the backbone (PCA5 and PCA5D1) were used as starting polyions. The complex stoichiometry, (n?/n+)iso, was pointed out by optical density at 500 nm (OD500), polyelectrolyte titration, and dynamic light scattering. IPEC nanoparticle sizes were influenced by the polycation structure and polyanion molar mass only before the complex stoichiometry, which was higher for the more hydrophilic polycations (PCA5 and PCA5D1) and for a higher NaPAMPS molar mass, and were almost independent of these factors after that, at a flow rate of the added polyion of about 0.28 mL × (mL PC)?1 × h?1. The IPEC nanoparticle sizes remained almost constant for more than 2 weeks, both before and after the complex stoichiometry, at low concentrations of polyions. NIPECs as stable colloidal dispersions with positive charges in excess were prepared at a ratio between charges (n?/n+) of 0.7, and their storage colloidal stability, as a function of the polycation structure and polyion concentration (from 0.8 to ca. 7.8 mmol/L), was demonstrated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2495–2505, 2004  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号