Low-temperature bath/coupled-capillary/sweeping-micellar electrokinetic capillary chromatography for the separation of naphthalene-2,3-dicarboxaldehyde-derivatized dopamine and norepinephrine

The use of a low-temperature (0 degrees C) bath-assisted coupled capillary for the separation of naphthalene-2,3-dicarboxaldehyde (NDA)-derivatized dopamine and norepinephrine using the sweeping-micellar electrokinetic capillary chromatography (MEKC) mode is described. In this technique, a capillary consisting of two portions with different inside diameters is used. Therefore, the field strength inside the capillary is different. Hence, the electrophoretic migration velocities of the analytes and the electro-osmotic flow (EOF) also are different. Furthermore, when a portion of the capillary (wide portion, used for sweeping) is immersed in a low-temperature bath, the viscosity of the buffer and the retention factor of the analytes inside are increased. Thus, not only are the interactions between the SDS micelles and the analytes increased, but the SDS-analytes also move more slowly. As a result, a more complete separation can be achieved, even when the sample injection volume is large, up to approximately 2 microL. In general, when the volume of an injected sample is larger, the effects of sweeping and separation would become insufficient, especially when the retention values (k) of the analytes are quite different. However, this limitation can be improved when the low-temperature bath/coupled capillary/sweeping-MEKC mode is used.     

Application of Equivalent Air Gap Method in Uniaxial Crystal Plate

The equivalent air gap method is a simple way to trace the ray propagation in an isotropic medium, but it cannot be applied to an anisotropic medium. We present the exact general expressions of the equivalent air gap thicknesses and the displacements for the plane-parallel uniaxial crystal plates. They are also suitable for the isotropie medium. This method is useful when one determines whether certain size plane-parallel plates can be fitted into the available air of an optical system, and also in the prism system design.     

地表反照率对短波红外探测大气CO2的影响

在卫星短波红外遥感二氧化碳的过程中, 表征地表特征的地表反照率是影响探测精度的重要参数之一. 针对温室气体二氧化碳高精度探测的需求, 本文研究了地表反照率对正演模拟光谱和反演近地面二氧化碳平均柱浓度XCO₂的影响. 模拟计算结果显示, 地表反照率数值增大时, 观察的光谱强度也相应增大, 并且在O₂-A波段造成的光谱差异比1.6 μm波段高出一个数量级, 即地表反照率在O₂-A波段的影响比较大. 选取了两个不同地表类型的实际观测光谱, 仅改变O₂-A波段和1.6 μm波段地表反照率数值, 得出草地点在O₂-A波段地表反照率达到0.25的误差时, 会给XCO₂的反演结果造成大于1%的相对误差, 而1.6 μm波段的地表反照率变化对XCO₂的反演结果造成的误差可以忽略不计, 说明了地表反照率在反演XCO₂过程中的重要性主要来自对O₂-A波段的影响. 此研究表明了地表反照率在卫星遥感温室气体过程中的重要性, 为提高遥感探测二氧化碳的精度提供了重要的理论依据和指导.     

静态偏振风成像干涉仪中光在四面角锥棱镜中的传播规律研究

简述了自行设计的新型静态偏振风成像干涉仪的原理和四面角锥棱镜的分光机理;应用光线追迹法,推导出了主截面内任意光线在棱镜中的传播方向及出射点坐标,建立了平行光束经角锥棱镜后的偏向角和透过率的理论表达式;采用计算机模拟给出了偏向角和透过率随入射角的变化关系曲线;根据静态偏振风成像干涉仪的具体参数确定了四面角锥棱镜的侧面和底面夹角以及底边长度.该研究为静态偏振风成像干涉仪的研制提供了理论依据.     

新型静态偏振风成像干涉仪理论探测误差的分析与计算

简述了新型静态偏振风成像干涉仪的原理,推导出一般情况下系统的Jones矩阵.在此基础上计算了系统中各偏振器件重要参数在非理想情况下对风速和温度探测结果的影响.利用计算机模拟对探测误差进行了分析,并按照系统精度要求从理论上提出了各重要参数的误差容限.该研究为新型静态偏振风成像干涉仪的研制、定标及后期数据处理提供了理论依据. 关键词： 静态偏振风成像干涉仪 Jones矩阵 方位角误差 相位延迟量误差     

高层大气风场四强度测量法误差分析与计算

利用干涉成像光谱技术和电磁波的多普勒效应,通过测量高层大气(80—300km)中的气辉(极光)辐射线的四个干涉强度值而获知高层大气的速度和温度信息.采用四强度干涉测量法,分别对基于Michelson干涉仪的动镜扫描和基于无动镜四分区镀膜的干涉图获取模式所引起的测量误差进行了深入的理论分析与研究.给出了由于此测量误差所导致的相位误差所引起的高层大气风场速度、温度的误差数值;采用计算机模拟得出了在不同相位误差条件下,两种模式计算得到的风场速度和温度的误差分布图;给出了风速误差、温度误差与相位步进误差的关系曲线 关键词： 高层大气风场测量 四强度测量法 模拟计算     

利用一个三粒子W态隐形传送N粒子GHZ态

杨洪钦等提出一个用两个三粒子W态作为量子信道将N粒子GHZ态从发送者传送给两个接收者中任意一个的量子隐形传送方案. 给出其理论分析,并提出了一个仅用一个三粒子W态作为量子信道将N粒子GHZ态传送给两个接收者之一的量子隐形传送的方案. 关键词： 隐形传态 GHZ态 W态量子信道     

Separation of crystal violet dyes and its application to pen ink analysis using CZE and MEKC methods

A crystal violet (CV) standard was irradiated under a Hg-Cd lamp for different exposure times to obtain various N-demethylation products. CZE effectively separated the photodegradation products based on molecular weight differences. In contrast, micellar EKC (MEKC), using SDS as the surfactant, was ineffective because the binding constants of the demethylation products and SDS were too close for separation. Nevertheless, MEKC analysis of ink has applications in forensic science because MEKC separated neutral components in the inks. Thus, MEKC can be used to obtain an ink "fingerprint" since each ink is unique depending on the location and time it was made. In contrast, CZE is useful for dating inks because CV is the primary ink dye and it photodegrades slowly.     

基于组合Wollaston棱镜成像光谱仪的视场扩大原理分析

论述了视场扩大型成像光谱仪的核心部件——组合Wollaston棱镜的结构和分光机理;应用波法线追迹法分析了光在任意方位入射面内,以任意角入射时组合Wollaston棱镜中的波矢传播规律;推导出了光在棱镜中的传播方向及出射点坐标;给出了传播过程中e光和o光之间光程差的理论表达式;采用计算机模拟,给出了光程差随入射角和入射面方位角的变化曲线;在此基础上对组合Wollaston棱镜扩大光谱仪视场的原理进行了深入分析和讨论.上述研究对偏振干涉成像光谱技术的理论研究与技术创新,对自行设计的稳态大视场偏振干涉成像光谱 关键词： Wollaston棱镜 偏振干涉成像光谱仪 波法线追迹法 视场扩大原理     

基于三角谐振环的新型六边形谐振环金属线复合周期结构左手材料性质研究

通过实验及仿真研究了三角谐振环组合新型六边形谐振环金属线复合周期结构左手材料.仿真研究了以金属铜三角开口谐振环（SRRs）为基本单元的周期结构负磁导率材料,与闭口环（CSRRs）结果对比发现三角开口谐振环能产生很好的谐振效果即能产生负磁导率,并且多层单元仿真发现多个谐振环耦合能提高谐振频率并加宽谐振频段;设计、制作并实验和仿真研究了三角开口环为基本单元的六边形谐振环金属线复合周期结构左手材料,仿真结果在98GHz附近出现良好负折射效应,实验验证在93—108 GHz出现良好负折射效应,与仿真结果具有良好的一致性.该研究对新型周期结构左手材料的研究、设计和研制具有重要的科学意义和应用前景. 关键词： 左手材料 三角环组成的六边形谐振环 负折射