全文获取类型
收费全文 | 41篇 |
免费 | 1篇 |
国内免费 | 9篇 |
专业分类
化学 | 31篇 |
力学 | 3篇 |
数学 | 2篇 |
物理学 | 15篇 |
出版年
2022年 | 2篇 |
2019年 | 2篇 |
2018年 | 1篇 |
2017年 | 1篇 |
2016年 | 1篇 |
2015年 | 1篇 |
2014年 | 3篇 |
2013年 | 3篇 |
2012年 | 3篇 |
2011年 | 1篇 |
2010年 | 1篇 |
2009年 | 2篇 |
2008年 | 2篇 |
2006年 | 2篇 |
2005年 | 2篇 |
2004年 | 2篇 |
2002年 | 1篇 |
2001年 | 3篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1998年 | 5篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 3篇 |
排序方式: 共有51条查询结果,搜索用时 15 毫秒
1.
聚变等离子体中的快离子压强 总被引:2,自引:2,他引:0
本文运用Fokker-Planck方程的慢化近似,考虑存在多种离子成份(包括杂质),假定它们具有共同的温度,我们得到了聚变产生的快离子压强的简单封闭形式表示式。表明在典型的工作温度下(~60keV),D-~3He等离子体中聚变产生的快离子压强约为本底热压强的20%,这与D-T等离子体工作在20keV时的比值几乎相同。因此,D-~3He和D-T在它们相应的预期工作温度下,它们各自的快离子压强对总压强的影响是类似的,然而在更高的温度下,这个比值将变得更大。 相似文献
2.
D—^3He聚变动力可行性研究 总被引:9,自引:3,他引:6
本文首先简要地讨论D-3He聚变的物理要求并与D-T聚变作相应的比较,然后运用目前的约束定律和第一稳定区β极限,对计划的近期ETR规模装置(如CIT,TIBER,FER,NET)进行D-3He得失相当和点火实验的可行性研究,并对高径比第二稳定区D-3He托卡马克堆进行参数学研究,最后指出潜在的缩短商用化进程可能性。 相似文献
3.
Zhang Yongqiang Wang Baiquan Xu Shansheng Zhou Xiuzhong Sun Jie 《Transition Metal Chemistry》1999,24(6):722-725
Reactions of diiron complexes (E)[5-t-BuC5H3)Fe(CO)]2(-CO)2 [E = Me2Si (1), Me2SiSiMe2 (2), and Me2SiOSiMe2 (3)] with iodine in CHCl3 yielded diiodide complexes (E)[5-t-BuC5H3)Fe(CO)2I]2 [E=Me2Si (5), Me2SiSiMe2 (6), and Me2SiOSiMe2 (7)]. Like (1–3), complexes (5–7) also exists as mixtures of cis and trans isomers even though the Fe–Fe bond in (1–3) has been cleaved. When the pure isomers (1–3) reacted with iodine respectively in CHCl3, the cis isomers (1c–3c) yielded only the cis products (5c–7c), whereas the trans isomers (1t–3t) yielded only the trans isomers (5t–7t). This indicates that iodination of bridged diiron complexes is stereospecific. Similar treatment of trans-(Me2Si)[{5-t-(heptyl)C5H3}Fe(CO)]2(-CO)2 (4t) with iodine gave only the trans product (Me2Si)[{5-t-(heptyl)C5H3}Fe(CO)2I]2 (8t). The molecular structure of (5t) was determined by X-ray diffraction. 相似文献
4.
Nuancheng Wang Prof. Dr. Bin Li Prof. Dr. Haibin Song Prof. Shansheng Xu Prof. Dr. Baiquan Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(1):358-364
The mechanism of the [(Cp*MCl2)2] (M=Rh, Ir)‐catalyzed oxidative annulation reaction of isoquinolones with alkynes was investigated in detail. In the first acetate‐assisted C? H‐activation process (cyclometalated step) and the subsequent mono‐alkyne insertion into the M? C bonds of the cyclometalated compounds, both Rh and Ir complexes participated well. However, the desired final products, dibenzo[a,g]quinolizin‐8‐one derivatives, were only formed in high yield when the Rh species participated in the final oxidative coupling of the C? N bond. Moreover, a RhI sandwich intermediate was isolated during this transformation. The iridium complexes were found to be inactive in the oxidative coupling processes. All of the relevant intermediates were fully characterized and determined by single‐crystal X‐ray diffraction analysis. Based on this mechanistic study, a RhIII→RhI→RhIII catalytic cycle was proposed for this reaction. 相似文献
5.
瓦斯爆炸过程中激波的诱导条件及其分析 总被引:18,自引:2,他引:18
在实验的基础上,研究了瓦斯爆炸过程中激波的产生条件.研究结果表明,障碍物和薄膜的存在对瓦斯爆炸过程中激波的产生具有重要影响.当有障碍物存在时,瓦斯爆炸过程中火焰的传播速度将迅速提高,并可诱导激波的产生;同样,在瓦斯爆炸破膜过程中也将产生激波现象.因此,为了减轻瓦斯爆炸的破坏作用,应尽量减少矿井巷道中的障碍物并加固好风门与密闭墙,以防发生破膜现象,导致激波的产生.研究结果对指导现场如何防治瓦斯爆炸,减轻瓦斯爆炸的威力具有重要作用. 相似文献
6.
7.
Doping‐free white organic light‐emitting diodes (WOLEDs) have great potential to the next‐generation solid‐state lighting and displays due to the excellent properties, such as high efficiency, bright luminance, low power consumption, simplified structure and low cost. In this account, our recent developments on doping‐free WOLEDs have been summarized. Firstly, fundamental concepts of doping‐free WOLEDs have been described. Then, the effective strategies to develop doping‐free WOLEDs have been presented. Particularly, the manipulation of charges and excitons distribution in different kinds of doping‐free WOLEDs have been highlighted, including doping‐free fluorescent/phosphorescent hybrid WOLEDs, doping‐free thermally activated delayed fluorescent WOLEDs and doping‐free phosphorescent WOLEDs. In the end, an outlook for the future development of doping‐free WOLEDs have been clarified. 相似文献
8.
为了研究瓦斯爆炸冲击波的动压演化规律,利用数值模拟软件模拟开口型管道内的爆炸。结果表明:动压与流速在时间上存在较好的对应关系,基本同时出现正向和反向的峰值;动压在3个方向上不仅伴随传播距离的增大而不断增大,也伴随传播时间的延长而增大;沿管道方向(火焰传播方向)上的最大动压值是其他2个方向(管道径向)上的数千倍;相比爆炸超压而言,管道径向上的动压对爆炸破坏效应的影响较小,而沿管道方向上的动压造成的破坏效应不能忽视;验证了动压与流速的平方呈正比关系,同时通过分析给出了动压基于管道几何尺寸和流速的经验公式。 相似文献
9.
We have recently reported a novel rearrangement reaction involving an intramolecular metathesis between M-M and Fe-Fe bonds in the dinuclear iron complexes (Me2MMMe2)[η5-C5R4)Fe(CO)]2(μ-CO)2 (M=Si, Ge; R=H, Me):[1-5].In order to extend the applied range of the rearrangement reaction we tried to synthesize the digermyl briged diruthenium analogues. The results showed a great difference between them. 相似文献
10.
An efficient Ru3(CO)12-catalyzed dehydrogenative SiN coupling reaction of indoles, pyrrole, and carbazole with hydrosilanes is reported. The reaction does not need any external additive. This catalytic reaction has a wide substrate range, excellent functional group tolerance, and high to excellent reaction efficiency. Gram-scale synthesis demonstrates the practicability of this synthetic method. 相似文献