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1.
We have recently found that the reaction of α-keto acids (1) with phosphorus (III) compounds (3) yielded cyclic acyloxyphosphoranes(C-AOPs, 4), a new class of pentacovalent phosphorus species having a P-OC(O) group.1, 2) The present paper deals with a new reaction of glyoxylic acid (2) with 3 to give C-AOPs (5) having no substituent at the C-3 position. 1 is an α-keto acid whereas 2 can be taken as an α-formyl acid. Although it is well known in the field of organic chemistry that the formyl group often behaves differently from a keto group, the reaction of 2 with 3 provides an example in which both groups behave in a similar manner. 相似文献
2.
Abstract We used absorption spectroscopy to observe decomposition of benzene (C6H6) subjected to the passage of strong shock waves generated by projectile impact. These measurements were made using a recently developed double-beam, double-pass, fiber-optic-coupled apparatus. Near 13 GPa, we observe absorption throughout most of the visible region, with strong absorption occurring for wavelengths below 400 nm. The absorption is most likely due to a combination of molecular absorption and Mie scattering from carbon particles formed as a result of shock decomposition. 相似文献
3.
The asymmetric Michael addition of 2-alkoxyphenyl α-substituted nitroacetates to non-prochiral α,β-unsaturated carbonyl compounds catalyzed by 10 mol % of sodium 2′-[2-(2-methoxyethoxy)ethoxy]-1,1′-binaphthalen-2-oxide gave the desired adducts in high yields with up to 95% ee. 相似文献
4.
Genki Odahara Shigeki Otani Chuhei Oshima Masahiko Suzuki Tsuneo Yasue Takanori Koshikawa 《Surface and interface analysis : SIA》2011,43(12):1491-1493
We observed in situ growth of a single graphene sheet on Ni(111) by low‐energy electron microscopy. The sheet was grown epitaxially beyond the steps on the substrate. The crystalline shapes of graphene islands were clearly seen; the straight edges of the island are crossed at either 60 or 120°, and the linear edges shifted perpendicular to the edge keeping the equilibrium shape. Graphene islands were united to form a single sheet without any grain boundaries and any wrinkles. The Ni substrate of several centimeters in size was covered with a single‐domain graphene sheet. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
5.
J.-B. Laloë T. Yang T. Kimura Y. Otani 《Journal of magnetism and magnetic materials》2009,321(22):3829-3832
We investigate the injection of a pure spin current into a non-magnetic Cu wire in a lateral spin valve. We detect the spin accumulation occurring at the interfaces between the magnetic nanopillars and the non-magnetic wire in the non-local geometry. We confirm that the accumulated spins diffuse equally in the Cu wire irrespective of the presence of a charge current. The inversion of the injector and detector magnetic nanopillars does not affect the spin signal, in agreement with analytical predictions for this system. 相似文献
6.
This paper presents an FMM (Fast Multipole Method) for periodic boundary value problems for Maxwell’s equations in 3D. The effect of periodicity is taken into account with the help of the periodised moment to local expansion (M2L) transformation formula, which includes lattice sums. We verify the proposed method by comparing the obtained numerical results with analytic solutions for models of the multi-layered dielectric slab. We then apply the proposed method to scattering problems for periodic two-dimensional arrays of dielectric spheres and compare the obtained energy transmittances with those from the previous studies. We also consider scattering problems for woodpile crystals, where we find a passband related to a localised mode. Through these numerical tests we conclude that the proposed method is efficient and accurate. 相似文献
7.
Takashi Otani 《Tetrahedron letters》2009,50(27):3853-727
A variety of 4-arylquinoline-2-thiones and 3-arylthieno[2,3-b]indoles were synthesized in high yields via TfOH-promoted tandem Friedel-Crafts alkenylation-cyclization reactions of 2-alkynylphenyl isothiocyanates. 相似文献
8.
We have successfully grown a uniform BC3 honeycomb sheet with high crystalline quality over the entire macroscopic area of the NbB2 (0001) surface by carbon-substituted technique in a boron honeycomb. This is the first macroscopic uniform sheet of single-crystal BC3 with a monolayer thickness. So far, only BC3 micro-crystals with radii of a few nanometres were produced. The properties of the sheet have been investigated by using XPS, AES, LEED, STM, ARUPS and HREELS. All the experimental data and the theoretical calculations, which are concerning with atomic structure, chemical concentration, and phonon structure, indicated that the uniform BC3 honeycomb sheet was grown in an epitaxial manner to the substrate lattice. 相似文献
9.
Optically driven actuators have a feature of a non-contact method supplied by light energy. A new method is proposed with
three poly(vinylidene difluoride) (PVDF) cantilevers as the legs and a polymer film as the body. The PVDF cantilevers are
coated with silver on one surface. When one side of the cantilever is irradiated by a laser beam, an electric field is produced
along a cross-section of the cantilever by the pyroelectric effect and a mechanical displacement occurs by the piezoelectric
effect. Its response time and its generated force are measured experimentally. Two types of optically driven actuators using
PVDF film are proposed to move using different characteristics. 相似文献
10.
T. Otani L. Herbst M. Heglin S.V. Govorkov A.O. Wiessner 《Applied Physics A: Materials Science & Processing》2004,79(4-6):1335-1339
The trend of the ever-continuing miniaturization requires fast and flexible processing tools. Lasers are flexible tools which have proven their reliability in manufacturing of macrofeatures for many years already. However, to process small features the requirements of the laser source, e.g. in regard to the beam profile, are very high. Innovative laser sources which meet these requirements, such as diode-pumped solid-state lasers, and the progress in processing technology, have made microfeature processing commercially viable during recent years. Examples of industrial applications are laser-drilled micro-injection nozzles for highly efficient automobile engines or manufacturing of complex spinnerets for production of synthetic fibers. The unique advantages of laser-based techniques stem from their ability to produce high-aspect-ratio holes, while yielding small heat-affected zones with exceptional surface quality, roundness and taper tolerances. Additionally, the ability to drill blind holes and slots in very hard materials such as diamond, silicon, sapphire, ceramics and steel is of great interest for many applications in the microelectronics, semiconductor and automotive industries. This kind of high-quality, high-aspect-ratio micromachining requires high peak powers and short pulse durations. PACS 42.55.Xi; 42.62.Cf; 81.40.-z 相似文献