Journal of Analytical Chemistry - In this article, a new spectrofluorometric method was developed for the determination of methamphetamine based on a turn-on luminescence response of captopril... 相似文献
Research on Chemical Intermediates - A new catalyst has been prepared via immobilization of Cu(proline)2 complex onto the surface of magnetic graphene. The fabricated nanocatalyst was characterized... 相似文献
In this study, a three-component nanocomposite consisted of graphene, manganese ferrite and phosphotungstic acid (PTA) has been prepared. This composite, which is designated as Graphene/MnFe2O4@PTA, was synthesized through anchoring of PTA–imidazolium ionic liquid on magnetic graphene sheets. The structural and magnetic properties of the fabricated nanocomposite were studied by employing FT-IR, SEM, EDX, TEM, ICP, VSM, P-XRD and BET techniques. The synthesized magnetic nanocomposite was examined as an efficient and recyclable acidic catalyst for Mannich reaction under solvent-free conditions. The products of this reaction, which are an important class of potentially bioactive compounds, were obtained with good to excellent yields, and the catalyst could be readily recycled without any significant loss of its activity. 相似文献
Two new complexes of [Mn(2-MPyzCI)2Cl2].H2O (1) and [Mn(2-MPyzCI)2(H2O)2](NO3)2 (2) were synthesized from the reaction of MnX2.4H2O (X=Cl? and NO3?) with 2-cyanopyrazine in methanolic solution. The chelating methyl pyrazine-2-carboximidate (2-MPyzCI) ligand is formed via the methanolysis of 2-cyanopyrazine. Although coordination environment around manganes(II) ions is similar, but these complexes are different in geometrical position of 2-MPyzCI ligands. As both compounds are synthesized under the same reaction conditions, the only difference between these two complexes are counter ions and changing of geometrical position of ligands can be considered as a result of influence of the counter-anions on the molecular structures. 相似文献
We studied sensor application of a graphene oxide and hematite (α‐Fe2O3/GO) composite electrode well‐characterized by the SEM and XRD. Through differential pulse voltammetry (DPV), oxidation of dexamethasone sodium phosphate (DSP) was studied at the surface of a glassy carbon electrode (GCE) modified with graphene oxide nanosheets (GO) and the α‐Fe2O3/GO composite. The values of the transfer coefficient (α) and the diffusion coefficient (D) of DSP were 0.5961 and 4.71×10?5 cm2 s?1 respectively. In the linear range of 0.1–50 μM, the detection limit (DL) was 0.076 μM. In the second step, a GCE was modified with α‐Fe2O3/GO composite and the DSP measurement step was repeated to analyzed and compare the effects of hematite nanoparticles present on graphene oxide surfaces. According to the results, α and D were 0.52 and 2.406×10?4 cm2 s?1 respectively and the DL was 0.046 μM in the linear range of 0.1–10.0 μM. The sensor is simple, inexpensive and uses blood serum. 相似文献
A reusable and cost-effective magnetic graphite oxide (Fe3O4NPs@GO) nanocomposite was fabricated and applied for pre-purification of paclitaxel from leaf-derived crude extract of Taxus baccata. Furthermore, the potential roles of three crucial criteria (i.e., adsorbent dosage, sorption temperature and agitation/shaking power) on the two responses [i.e., efficiency of plant pigments removal (EPPR) and efficiency of taxol purity (ETP)] were examined and simultaneously optimized through response surface methodology. The nanocomposite was accurately characterized using TEM, AFM, BET, FT-IR, Raman and VSM. Moreover, for both proposed second-degree polynomial regression models, highly significant correlations were achieved between the experimental and predicted data (p < 0.0001). Meanwhile, the optimum conditions to simultaneously acquire the maximum EPPR (94.0 %) and ETP (11.4 %) were recorded as adsorbent dosage of 37.7 g L−1, sorption temperature of 30.7 °C and agitation power of 153.1 rpm; and the predictive results were confirmed using experimental rechecking survey. Interestingly, upon five consecutive treatments, the nanocomposite still exhibited substantial potency in eliminating large amounts of plant pigments and impurities (up to 90 %), without significant reduction on sorption capacity and magnetism thereof. Our results demonstrated that the current nanocomposite, as SPE sorbent for MSPE, could be a simple, fast and reusable approach for HPLC-based purification studies of paclitaxel, and probably other plant secondary metabolites.
Degradation of Acid Orange 7 (AO7) as a model azo dye was investigated in a recirculating pilot fluidized-bed reactor by a Fenton-like process using natural magnetite (NM) and potassium persulfate (K2S2O8). Scanning electron microscopy was performed to characterize the magnetite sample. The heterogeneous Fenton-like process (NM/\({\text{S}}_{2} {\text{O}}_{8}^{2 - }\)) is a modified method owing to its enhanced mass transfer. It can be operated reliably and simply by reducing the produced iron oxide sludge in the conventional Fenton process. Degradation efficiency (DE %) of AO7 by NM/ \({\text{S}}_{2} {\text{O}}_{8}^{2 - }\) process was affected by operational parameters. The DE % of 75 % was obtained for the AO7 treatment (15 mg/L) at the desired conditions, such as pH 5, 0.2 mM \({\text{S}}_{2} {\text{O}}_{8}^{2 - }\), and 0.5 g/L NM after 120 min of reaction time. The dye degradation rate in all the experiments followed the pseudo-second-order kinetic with high correlation coefficients (R2 ≥ 0.98). The low released iron concentration, successive reusability at milder pH and the recirculation mode with the proper mixing are the significant advantages of the NM/\({\text{S}}_{2} {\text{O}}_{8}^{2 - }\) process. 相似文献
Journal of Optimization Theory and Applications - By using our own approach, we study the strong convergence of an inexact proximal point algorithm with possible unbounded errors for a maximal... 相似文献
AbstractThis article contains the nonlocal elasticity theory to capture size effects in functionally graded (FG) nano-rod under magnetic field supported by a torsional foundation. Torque effect of an axial magnetic field on an FG nano-rod has been defined using Maxwell’s relation. The material properties were assumed to vary according to the power law in radial direction. The Navier equation and boundary conditions of the size-dependent FG nano-rod were derived by the Hamilton’s principle. These equations were solved by employing the generalized differential quadrature method (GDQM). Presented model has the ability to turn into the classical model if the material length scale parameter is taken to be zero. The effects of some parameters, such as inhomogeneity constant, magnetic field and small-scale parameter, were studied. As an important result of this study can be stated that an FG nano-rod model based on the nonlocal elasticity theory behaves softer and has smaller natural frequency. 相似文献