全文获取类型
收费全文 | 415篇 |
免费 | 8篇 |
国内免费 | 2篇 |
专业分类
化学 | 279篇 |
晶体学 | 3篇 |
力学 | 1篇 |
数学 | 22篇 |
物理学 | 120篇 |
出版年
2022年 | 3篇 |
2021年 | 2篇 |
2019年 | 6篇 |
2016年 | 7篇 |
2015年 | 7篇 |
2014年 | 7篇 |
2013年 | 14篇 |
2012年 | 19篇 |
2011年 | 19篇 |
2010年 | 9篇 |
2009年 | 10篇 |
2008年 | 34篇 |
2007年 | 22篇 |
2006年 | 21篇 |
2005年 | 40篇 |
2004年 | 26篇 |
2003年 | 27篇 |
2002年 | 15篇 |
2001年 | 7篇 |
2000年 | 7篇 |
1999年 | 5篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1994年 | 5篇 |
1993年 | 6篇 |
1992年 | 6篇 |
1991年 | 5篇 |
1990年 | 2篇 |
1989年 | 4篇 |
1988年 | 5篇 |
1987年 | 4篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 4篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1976年 | 3篇 |
1974年 | 4篇 |
1973年 | 14篇 |
1972年 | 2篇 |
1968年 | 7篇 |
1967年 | 2篇 |
1961年 | 3篇 |
1960年 | 2篇 |
1957年 | 1篇 |
1956年 | 1篇 |
排序方式: 共有425条查询结果,搜索用时 562 毫秒
1.
To prepare cross‐linked silicone (silicone rubber) particles in an aqueous medium, we investigated two synthesis methods involving a miniemulsion system. The first method was based on cationic ring‐opening polymerization of cyclic siloxane, which is a common synthetic route for linear silicone oil and uses octamethylcyclotetrasiloxane (D4) as the monomer and dimeric D4 (bis‐D4) as the cross‐linker. Although this method produces silicone particles, the particles do not remain in the particulate state after drying because of low cross‐linking density. The polymerization mechanism of this method was also investigated, which proceeds under the ring‐opening reaction of D4 in monomer droplets and upon polycondensation of hydrolyzed D4, which occurs in the water phase (ie, outside the monomer droplets). This mechanism implied that introducing the cross‐linking structure into particles is difficult because of the low solubility of bis‐D4 in water. To overcome these difficulties, we demonstrated a second method of preparing silicone particles based on the thiol‐Michael addition reaction between thiol‐terminated silicone oil and triacrylate in miniemulsion systems. Transmission electron microscopy images indicated that the silicone particles obtained in the particulate state upon drying and the aggregates of these particles showed elasticity. 相似文献
2.
3.
4.
Synthesis and Self‐Assembly of Cyclic 2,7‐Anthrylene Ethynylene 1,3‐Phenylene Ethynylene Trimer with a Planar Conformation 下载免费PDF全文
Yuta Takaki Ryota Ozawa Dr. Takashi Kajitani Prof. Takanori Fukushima Prof. Masaaki Mitsui Prof. Kenji Kobayashi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(47):16760-16764
Cyclic arylene ethynylene hexamer 1 , composed of alternating 2,7‐anthrylene ethynylene units and meta‐phenylene ethynylene units, was synthesized. It shows C3 symmetry and possesses a flat and rigid conformation with a large equilateral triangle‐like cavity. Macrocycle 1 self‐associates through π–π stacking interactions between the anthracene‐containing macrocyclic aromatic cores with indefinite‐association constant KE=6980 m ?1 in CDCl3 at 303 K. Macrocycle 1 also self‐assembles into π‐stacked nanofibers in the drop‐cast film. 相似文献
5.
1.IntroductionInthispaper,wewillinvestigatethenumericalsolutionsofthefollowinginitialvalueproblemsforDDEswithmanyvariabledelayswherea,bl,b2,...,bmandcoEC,0相似文献
6.
Daisuke Saeki Takeshi Yamada Yasuko In Tetsuya Kajimoto Reiko Tanaka Yota Iizuka Takahisa Nakane Akihito Takano Kazuo Masuda 《Tetrahedron》2013,69(5):1583-1589
Novel 5 lupane-type of triterpenois, i.e., 3β-acetoxy-18α,19α-epoxylupan-21β-ol (1), 18α,19α-epoxy-21β-hydroxylupan-3-one (2), lup-18-ene-3,21-dione (3), lupa-18,21-dien-3β-yl acetate (4), and (17S)-17,18-seco-lup-19(21)-ene-3,18,22-trione (5), named officinatrione, as well as 16 known compounds from the roots of Taraxacum officinale collected in Takatsuki city, Osaka, Japan. Of the above compounds, 5 was the first lupane-type triterpene, of which the D-ring was open to form a nine-membered ring. Compounds 2 and 5 exhibited moderate cytotoxic activities against L1210 cell line (IC50 10.5 and 10.1 μM). 相似文献
7.
Takahisa Miyata 《Topology and its Applications》2010,157(14):2194-2224
The notions of pro-fibration and approximate pro-fibration for morphisms in the pro-category pro-Top of topological spaces were introduced by S. Mardeši? and T.B. Rushing. In this paper we introduce the notion of strong pro-fibration, which is a pro-fibration with some additional property, and the notion of ANR object in pro-Top, which is approximately an ANR-system, and we consider the full subcategory ANR of pro-Top whose objects are ANR objects. We prove that the category ANR satisfies most of the axioms for fibration category in the sense of H.J. Baues if fibrations are strong pro-fibrations and weak equivalences are morphisms inducing isomorphisms in the pro-homotopy category pro-H(Top) of topological spaces. We give various applications. First of all, we prove that every shape morphism is represented by a strong pro-fibration. Secondly, the fibre of a strong pro-fibration is well defined in the category ANR, and we obtain an isomorphism between the pro-homotopy groups of the base and total systems of a strong pro-fibration, and hence obtain the pro-homotopy sequence of a strong pro-fibration. Finally, we also show that there is a homotopy decomposition in the category ANR. 相似文献
8.
9.
A simple and highly sensitive method for the determination of free and total (free + conjugated) catecholamines (norepinephrine, epinephrine and dopamine) in human urine is described which employs HPLC with fluorescence detection. Conjugated catecholamines (sulfate form) are hydrolyzed by a sulfatase-mediated reaction to the corresponding free amines. After cation exchange chromatography on a Toyopak IC-SP S cartridge, catecholamines and isoproterenol (internal standard) in urine samples were converted into the corresponding fluorescent compounds by reaction with 1,2-diphenylethylenediamine. These compounds were separated within 8 min on a reversed phase column with isocratic elution using a mixture of water, methanol and acetonitrile containing a Tris-hydrochloric acid buffer (pH 7.0). The detection limit for each catecholamine is ca 2 fmol per 100 microL injection volume. 相似文献
10.
Summary The energy spectrum of cosmic-ray neutrinos in the atmosphere has been calculated for the neutrino energy from 0.2 GeV to
108 GeV by taking into account the results of p-p collision, p-nucleus collision, nucleus-nucleus collision, the energy spectrum
of primary cosmic rays, momentum spectrum and charge ratio of cosmic-ray muons measured by MUTRON, and the production of prompt
neutrinos in the decay of charmed particles. Our result on neutrino intensity is in good agreement with the result of Osborneet al. for the horizontal direction if their muon spectrum has been corrected, and also with the result of Volkova for the vertical
direction except for the lower energies. For the horizontal direction the intensity of prompt muon-neutrinos exceeds that
of muonneutrinos from the conventional processes at the neutrino energy of 106 GeV and also the intensity of prompt electron-neutrinos exceeds that of electron-neutrinos from the conventional processes
at the energy of 105 GeV. The corresponding values for the vertical direction are 105 GeV and 104 GeV, respectively. In the energy region from 0.3 GeV to 3 GeV, the expected value for the ratio of intensity of electron-neutrino
to that of muon-neutrino is obtained as 0.42±0.08 and this is excellent agreement with the experimental value 0.36±0.13 of
NUSEX group.
Riassunto è stato calcolato lo spettro d’energia dei neutrini dei raggi cosmici nell’atmosfera per un’energia neutrinica da 0.2 a 108 GeV tenendo conto dei risultati delle collisioni p-p, p-nucleo, nucleo-nucleo, dello spettro d’energia dei raggi cosmici primari, dello spettro dell’impulso e del rapporto di carica dei muoni dei raggi cosmici misurato da MUTRON e dalla produzione di neutrini pronti nel decadimento di particelle con charm. Il nostro risultato sull’intensità dei neutrini è in buon accordo con il risultato di Osborneet al. per la direzione orizzontale se il loro spettro muonico viene corretto, ed anche con il risultato di Volkova per la direzione verticale tranne che per le energie piú basse. Per la direzione orizzontale l’intensità dei neutrini muonici pronti è maggiore di quella dei neutrini muonici che derivano dai processi convenzionali ad energia neutrinica di 106 GeV ed anche l’intensità dei neutrini elettronici pronti è maggiore di quella dei neutrini elettronici che derivano dai processi convenzionali all’energia di 105 GeV. I valori corrispondenti per la direzione verticale sono rispettivamente 105 e 104 GeV. Nella regione d’energia tra 0.3 e 3 GeV, il valore atteso ottenuto per il rapporto tra l’intensità dei neutrini elettronici e quella dei neutrini muonici è 0.42±0.08 e questo è in accordo eccellente con il valore sperimentale 0.36±0.13 del gruppo NUSEX.
Ёнергетический спектр нейтрино космических лучей в атмосфере
Резюме Вычисляется Энергетический спектр нейтрино космических лучей в атмосфере для Энергий нейтрино от 0.2 ГЭВ до 108 ГЭВ, учитывая р-р соударения, р-ядерные соударения, ядерно-ядерные соударения, Энергетический спектр первичных космических лучей, импульсный спектр и зарядовое отнощение мюонов космических лучей, измеренных с помошью МUTRON, и образование нейтрино в распадах очарованных частиц. Нащ результат для интенсивности нейтрино хорощо согласуется с результатом Осборна и др. для горизонтального направления, если их мюонный спектр является правильным, а также с результатом Волковой для вертикального направления, за исключением низких Энергий. Для горизонтального направления интенсивность мгновенных мюонных нейтрино превыщает интенсивность мюон-ных нейтрино из обычных процессов при Энергиях нейтрино 106 ГЭВ. Йнтенсивность мгновенных Электронных нейтрино превыщает интенсивность Электронных нейтрино из обычных процессов при Энергии 105 ГЭВ. Соответствуюшие величины для вертикального направления соответственно равны 105 ГЭВ и ДО4 ГЭВ. В области Энергий от 0.3 ГЭВ до 3 ГЭВ ожидаемая величина отнощения интенсивностей Электронных нейтрино к интенсивности мюонных нейтрино составляет 0.42±0.08. Ёта величина прекрасно согласуется с Экспериментальным результатом 0.36±0.13, полученным группой相似文献