Efficient synthesis of furoquinolinones using Hendrickson reagent-initiated cascade annulation

A new synthesis of furo[3,4-b]quinolin-3(1H)-one derivatives has been established in straightforward fashion in high overall yields. An efficient Hendrickson reagent-initiated cascade annulation, which is composed of mild conversion of the stable amide precursor to the reactive imido-carbonium intermediate and subsequent intramolecular aza Diels-Alder reaction, successfully serves as the key reaction in the synthesis. Final oxidative cleavage of the carbon-carbon double bond of representative tricyclic precursor 8g led to completion of the synthesis of quinoline-lactone 2g in a high yield.     

一种直接求解的动态载荷识别方法

基于直接求解系统方程的位移响应,提出了一种时域内动态载荷的识别方法.该方法从中心差分格式的有限元离散形式出发,进行分块矩阵变换,将载荷识别问题转化为一个虚构系统方程的响应求解问题.通过数值算例,用两种不同形式的载荷检验了该方法的识别能力,分析了有无零相位滤波器对识别结果的影响.结果表明:所提出的载荷识别方法在位移响应数据含有噪声的情况下,能有效稳定地实现载荷识别;且计算简单快捷,抗噪能力强,不需进行模态分解,不存在模态截取等问题.     

混凝土材料动态本构参数的分阶段计算反求技术

基于不同应变率下的分离式Hopkinson压杆实验,提出了一种混凝土材料动态本构参数的分阶段反求方法。该分阶段反求方法中,结合不同的实验模型对未知参数进行敏感性分析,并依据敏感程度对参数进行分类,每类参数对应于1组实验,再利用反求方法分阶段确定各类参数,在每一类参数反求时均将上一次反求结果作为已知条件。结果表明,该分阶段反求方法充分利用所有实验的测量响应信息,能快速获取混凝土本构中较难确定的关键参数,为参数的确定提供了一种有效的途径。     

Chemical recycling of carbon fibre reinforced epoxy resin composites in subcritical water: Synergistic effect of phenol and KOH on the decomposition efficiency

The combination of phenol and potassium hydroxide (KOH) was used to chemically recycle carbon fibre reinforced epoxy resin cured with 4,4′-diaminodiphenylmethane in subcritical water. This combination had a synergistic effect on decomposing this kind of epoxy resin. The main decomposition products from the epoxy resin were identified by means of GC-MS, and a possible free-radical reaction mechanism for the decomposition of epoxy resin is proposed. The recovered carbon fibres were characterized using single fibre tensile tests, scanning electron microscopy and X-ray photoelectron spectroscopy. Compared to virgin carbon fibres after sizing removal, the surface compositions of the recovered carbon fibres had little change and the tensile strength of the recovered carbon fibres was well retained.