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1.
Chao Wang Jing Wang Xiang Xiao Guobin Zhong Shijia Wu Kaiqi Xu Wei Zhao Wei Su Jie Zeng Baojun Wu Weili Zhang Changcheng Wu Zhiqiang Shi 《中国化学快报》2019,30(6):1269-1272
A novel cyclic ammonium salt, N,N-dimethylpyrrolidinium tetrafluoroborate (P11-BF4), was successfully synthesized for the first time. The smallest cyclic structure of P11-BF4 induced high solubility and conductivity in PC, which can easier enter the micropores of activated carbon and occupy more surface area during charge/discharge process. 相似文献
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Xiaofang Lu Qi Zheng Shijia Gu Rui Guo Li Su Jiancheng Wang Zhenxing Zhou Yuchi Fan Wan Jiang Lianjun Wang 《中国化学快报》2020,31(3):880-884
Cu@Ag/Bi2Te3 nanocomposites were prepared for the first time by ultrasonic dispersion-rapid freezedrying method combined with spark plasma sintering(SPS).By changing the content of Cu@Ag nanoparticle,we could modulate the temperature dependent thermoelectric properties.The highest ZT value can be obtained at 450 K for 1 vol%Cu@Ag/Bi2Te3,which is benefited from the decoupling of electrical and thermal properties.With the increase of electrical conductivity,the absolute value of Seebeck coefficient lifts while the thermal conductivity declines.Meanwhile,the average ZT value between 300 K and 475 K was 0.61 for 1 vol%Cu@Ag/Bi2Te3,which is much higher than that of pristine Bi2 Te3.Therefore,the decoupling effect of Cu@Ag nanoparticles incorporation could be a promising method to broaden the application of Bi2Te3 based thermoelectric materials. 相似文献
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Shijia Feng Tuo Wang Bin Liu Congling Hu Lulu Li Zhi‐Jian Zhao Jinlong Gong 《Angewandte Chemie (International ed. in English)》2020,59(5):2044-2048
A facile photoetching approach is described that alleviates the negative effects from bulk defects by confining the oxygen vacancy (Ovac) at the surface of BiVO4 photoanode, by 10‐minute photoetching. This strategy could induce enriched Ovac at the surface of BiVO4, which avoids the formation of excessive bulk defects. A mechanism is proposed to explain the enhanced charge separation at the BiVO4 /electrolyte interface, which is supported by density functional theory (DFT) calculations. The optimized BiVO4 with enriched surface Ovac presents the highest photocurrent among undoped BiVO4 photoanodes. Upon loading FeOOH/NiOOH cocatalysts, photoetched BiVO4 photoanode reaches a considerable water oxidation photocurrent of 3.0 mA cm?2 at 0.6 V vs. reversible hydrogen electrode. An unbiased solar‐to‐hydrogen conversion efficiency of 3.5 % is realized by this BiVO4 photoanode and a Si photocathode under 1 sun illumination. 相似文献
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Xuchu Wang Weiwei Liu Binbin Yin Yiwen Sang Zhenping Liu Yu Dai Xiuzhi Duan Gong Zhang Shijia Ding Zhihua Tao 《Mikrochimica acta》2017,184(6):1603-1610
The authors describe a method for DNA target recognition and signal amplification that is based on the target-induced formation of a three way junction. The subsequent assembly of two DNA probes releases the inhibitory strand and triggers a downstream strand displacement amplification. This causes the formation of a G-rich single sequence that binds to a hemin monomer with its peroxidase-mimicking properties. The resulting peroxidase (POx) activity is quantified by using H2O2 and TMB as the substrate. In the presence of an inhibitor, in contrast, the POx-like activity is strongly reduced. This forms the basis for a highly sensitive DNA assay. It has a 0.8 pM detection limit when operated at a wavelength of 450 nm and was applied to the isothermal determination of target DNA with high selectivity. 相似文献
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Zhouping Wang Nuo Duan Xu Hun Shijia Wu 《Analytical and bioanalytical chemistry》2010,398(5):2125-2132
A highly selective electrochemiluminescent biosensor for the detection of target nephrotoxic toxin, ochratoxin A (OTA), was
developed using a DNA aptamer as the recognition element and N-(4-aminobutyl)-N-ethylisoluminol (ABEI) as the signal-producing compound. The electrochemiluminescent aptamer biosensor was fabricated by
immobilizing aptamer complementary DNA 1 sequence onto the surface of a gold-nanoparticle (AuNP)-modified gold electrode.
ABEI-labeled aptamer DNA 2 sequence hybridized to DNA 1 and was utilized as an electrochemiluminescent probe. A decreased
electrochemiluminescence (ECL) signal was generated upon aptamer recognition of the target OTA, which induced the dissociation
of DNA 2 (ABEI-labeled aptamer electrochemiluminescent probe) from DNA 1 and moved it far away from the electrode surface.
Under the optimal conditions, the decreased ECL intensity was proportional to an OTA concentration ranging from 0.02 to 3.0 ng mL-1, with a detection limit of 0.007 ng mL-1. The relative standard deviation was 3.8% at 0.2 ng mL-1 (n = 7). The proposed method has been applied to measure OTA in naturally contaminated wheat samples and validated by an official
method. This work demonstrates the combination of a highly binding aptamer with a highly sensitive ECL technique to design
an electrochemiluminescent biosensor, which is a very promising approach for the determination of small-molecule toxins. 相似文献
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A novel linked‐half‐sandwich lutetium–bis(allyl) complex [(C5Me4? C5H4N)Lu(η3‐C3H5)2] ( 1 ) attached by a pyridyl‐functionalized cyclopentadienyl ligand was synthesized and fully characterized. Complex 1 in combination with [Ph3C][B(C6F5)4] exhibited unprecedented dual catalysis with outstanding activities in highly syndiotactic (rrrr>99 %) styrene polymerization and distinguished cis‐1,4‐selective (99 %) butadiene polymerization, respectively. Strikingly, this catalyst system exhibited remarkable activity (396 kg copolymer (molLu h)?1) for the copolymerization of butadiene and styrene. Irrespective of whether the monomers were fed in concurrent mode or sequential addition of butadiene followed by styrene, diblock copolymers were obtained exclusively, which was confirmed by a kinetics investigation of monomer conversion of copolymerization with time. In the copolymers, the styrene incorporation rate varied from 4.7 to 85.4 mol %, whereas the polybutadiene (PBD) block was highly cis‐1,4‐regulated (95 %) and the polystyrene segment remained purely syndiotactic (rrrr>99 %). Correspondingly, the copolymers exhibited glass transition temperatures (Tg) around ?107 °C and melting points (Tm) around 268 °C; typical values for diblock microstructures. Such copolymers cannot be accessed by any other methods known to date. X‐ray powder diffraction analysis of these diblock copolymers showed that the crystallizable syndiotactic polystyrene (syn‐PS) block was in the toluene δ clathrate form. The AFM micrographs of diblock copolymer showed a remarkable phase‐separation morphology of the cis‐1,4‐PBD block and syn‐PS block. This represents the first example of a lutetium‐based catalyst showing both high activity and selectivity for the (co)polymerization of styrene and butadiene. 相似文献
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Three models for the aggregated stochastic processes based on an underlying continuous-time Markov repairable system are developed in which two-part partition of states is used. Several availability measures such as interval availability, instantaneous availability and steady-state availability are presented. Some of these availabilities are derived by using Laplace transforms, which are more compact and concise. Other reliability-distributions for these three models are given as well. 相似文献
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Nuo Duan Shijia Wu Shaoliang Dai Tingting Miao Jie Chen Zhouping Wang 《Mikrochimica acta》2015,182(5-6):917-923