全文获取类型
收费全文 | 113篇 |
免费 | 0篇 |
专业分类
化学 | 54篇 |
力学 | 5篇 |
数学 | 4篇 |
物理学 | 50篇 |
出版年
2020年 | 1篇 |
2015年 | 2篇 |
2013年 | 3篇 |
2012年 | 1篇 |
2010年 | 1篇 |
2009年 | 2篇 |
2008年 | 3篇 |
2006年 | 2篇 |
2005年 | 2篇 |
2004年 | 2篇 |
2003年 | 5篇 |
2002年 | 6篇 |
2001年 | 4篇 |
2000年 | 5篇 |
1999年 | 8篇 |
1998年 | 3篇 |
1996年 | 3篇 |
1995年 | 8篇 |
1994年 | 9篇 |
1993年 | 1篇 |
1992年 | 6篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1973年 | 2篇 |
1968年 | 1篇 |
1937年 | 1篇 |
1933年 | 1篇 |
1922年 | 1篇 |
排序方式: 共有113条查询结果,搜索用时 15 毫秒
1.
2.
Henri-Edouard Audier Marcel Fetizon Yannik Henry Thierry Prange 《Journal of mass spectrometry : JMS》1976,11(10):1047-1055
The fragmentation mechanisms of oxazole have been studied in detail on using various experimental techniques (refocusing of metastable ions, deuteration, AP measurements) and by theoretical calculations. 相似文献
3.
4.
5.
6.
7.
8.
The determination of sulfur in biologically relevant samples such as metalloproteins is described. The analytical methodology used is based on robust on-line coupling between capillary electrophoresis (CE) and octopole reaction cell inductively-coupled plasma mass spectrometry (ORC–ICP–MS). Polyatomic ions that form in the plasma and interfere with the determination of S at mass 32 are minimised by addition of xenon to the collision cell. The method has been applied to the separation and simultaneous element-specific detection of sulfur, cadmium, copper, and zinc in commercially available metallothionein preparations (MT) and metallothionein-like proteins (MLP) extracted from liver samples of bream (Abramis brama L.) caught in the river Elbe, Germany. Instrumental detection limits have been calculated according to the German standard procedure DIN 32645 for the determination of sulfur and some simultaneously measured trace elements in aqueous solution. For sulfur detection limits down to 1.3 g L–1 (34S) and 3.2 g L–1 (32S) were derived. For the other trace elements determined simultaneously detection limits ranging from 300 ng L–1 (58Ni) to 500 ng L–1 (66Zn, 55Mn) were achieved. For quantification of sulfur and cadmium in a commercially available MT preparation under hyphenated conditions the use of external calibration is suggested. Finally, the need for proper sample-preparation technique will be discussed. 相似文献
9.
The intermolecular [2+2] photocycloaddition of dimedone 6 and 1-acetoxy-2-methyl-5-dioxolan-1-hexene 7 followed by alkaline treatment, gave the 1,5,5,11-tetramethyl-7-dioxolan bicyclo [4,3,2]-4-decen-2,3-dione 12, and the 1,5,5-trimethyl-3-hydroxy-7-dioxolan bicyclo [5,4,1] dodecan-2,11-dione 13. 相似文献
10.
Schaumlöffel D Prange A Marx G Heumann KG Brätter P 《Analytical and bioanalytical chemistry》2002,372(1):155-163
In a new approach to the characterization and quantification of metallothionein isoforms an on-line isotope-dilution method in combination with the coupling of capillary electrophoresis (CE) to an inductively coupled plasma-sector field mass spectrometer (ICP-SFMS) is reported. Metallothionein (MT) isoforms are separated by CE and the elements Cu, Zn, Cd, and S are detected simultaneously by use of ICP-SFMS in the medium resolution mode. On-line isotope dilution is performed by continuous introduction of an isotopically enriched, species-unspecific spike solution after the separation step. MT from rabbit liver and a further purified MT-1 isoform were quantified by determination of sulfur, and the stoichiometric compositions of the metalloprotein complexes are characterized by determination of their sulfur-to-metal ratios. 相似文献