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1.
M. V. Moskalev A. A. Skatova V. A. Chudakova N. M. Khvoinova N. L. Bazyakina A. G. Morozov O. V. Kazarina A. V. Cherkasov G. A. Abakumov I. L. Fedushkin 《Russian Chemical Bulletin》2015,64(12):2830-2840
Digallane (dpp-bian)Ga—Ga(dpp-bian) (1) (dpp-bian is the 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) catalyzes the addition of 4-chloroaniline to some terminal alkynes RC≡CH (R = Bun, Ph, 4-MeC6H4). The reaction orders in each of the substrates were found for the reaction of phenylacetylene with 4-chloroaniline catalyzed by compound 1. The reaction of compound 1 with phenylacetylene in a molar ratio of 1: 10 led to 1-[N-(2,6-diisopropylphenyl)imino]-2-(1-phenylethylidene)acenaphthene (5) and the compound [C12H6(NC6H3Pr2 i)(PhC=CH2)(PhC=CH)]Ga(C≡CPh)2 (6). The reaction of digallane 1 with phenylacetylene and aniline in a stoichiometric ratio of 1: 2: 2 gave bis-anilide (dpp-bian)-Ga[N(H)Ph]2 (7) in 40% yield. The compound (PhC≡C)3Ga·THF (9) was obtained by the reaction of three equivalents of sodium phenylacetylide (prepared in situ from phenylacetylene and sodium) with one equivalent of GaCl3 in tetrahydrofuran. Compounds 5—7 and 9 were characterized by IR spectroscopy, 1H NMR spectroscopy was used to characterize products 5, 6, and 9, whereas EPR spectroscopy was used for amide 7. The structures of compounds 5—7 and 9 were determined by single crystal X-ray diffraction analysis. 相似文献
2.
A. M. Moskalev 《Fluid Dynamics》1984,19(6):1005-1006
A study is made of the motion of fine spherical particles in a given steady vortex flow of an incompressible fluid. The results are given of an investigation into the Lyapunov stability of a particle trajectory coincident with the vortex axis, and of trajectories from which the distance to the vortex axis is determined by the condition of equality of the radial components of the force of the phase interaction and of the centrifugal force which acts on the particle.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 167–169, November–December, 1984. 相似文献
3.
A. M. Yakub M. V. Moskalev N. L. Bazyakina I. L. Fedushkin 《Russian Chemical Bulletin》2018,67(3):473-478
A mixture of allylbromide and diphenylacetonitrile is reduced to afford 2,2-diphenylpentene-4-nitrile as a major product in the presence of catalytic amounts of the magnesium complex (dpp-bian)Mg(thf)3 (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene dianion). The overall conversion of nitrile is 71% within 3 h at 85 °С. 4,4-Diphenylbutene-1 and diphenylmethane are by-products in this process. Complexes (dpp-bian)Mg(thf)3 and (dpp-bian)Ca(thf)4 (in an amount of 0.5—5 mol.%) catalyze the intramolecular hydroamination of some aminopentenes and aminohexenes with the conversion from 67 to 99%. 相似文献
4.
We presume that extending lifespan and particularly its healthy period is absolutely beneficial for human being. However,
the existing views and approaches did not result in a significant extension of human lifespan. 相似文献
5.
A. M. Yakub M. V. Moskalev N. L. Bazyakina A. V. Cherkasov A. S. Shavyrin I. L. Fedushkin 《Russian Chemical Bulletin》2016,65(12):2887-2894
The complexes (dpp-bian)Mg(thf)3, (dpp-bian)Ca(thf)4 and (dpp-bian)Mg(pyr)3 (dpp-bian is the 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene dianion; pyr is the pyrrolidine) catalyze the addition of pyrrolidine to 2-vinylpyridine at room temperature. The compound (dppbian)Mg[N(SiMe3)2] containing a dpp-bian radical anion catalyzes the addition of pyrrolidine to styrene at 60 °C. The dpp-bian radical anion lithium-sodium salt [(dpp-bian)Li{N-(SiMe3)2}][Na(C7H8)] is an active catalyst of the addition of pyrrolidine to styrene and isoprene at 60 °C. In all the case, the content of the catalyst was from 1 to 2 mol.%. For styrene and 2-vinylpyridine, the reactions proceeded with the formation of anti-Markovnikov addition product, while 1,4-addition product was obtained in the case of isoprene. 相似文献
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P. V. Moskalev 《Technical Physics》2009,54(6):763-769
An implementation of algorithms for constructing and analyzing the cluster structure for a square quadruply connected lattice
in the uncorrelated percolation problem is considered. Subsets of the complete superior hull and the skeleton of a percolation
cluster are singled out using a modification of the Hoshen—Kopelman relabeling algorithm and the Bellman principle of optimality.
The critical nature of the percolation process is demonstrated using the method for statistical tests, and the behavior of
mass dimension is analyzed for various subsets of a percolation cluster. 相似文献