首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   7562篇
  免费   1216篇
  国内免费   650篇
化学   5233篇
晶体学   77篇
力学   467篇
综合类   68篇
数学   765篇
物理学   2818篇
  2023年   173篇
  2022年   162篇
  2021年   224篇
  2020年   372篇
  2019年   343篇
  2018年   283篇
  2017年   238篇
  2016年   380篇
  2015年   366篇
  2014年   486篇
  2013年   571篇
  2012年   639篇
  2011年   685篇
  2010年   450篇
  2009年   363篇
  2008年   485篇
  2007年   419篇
  2006年   374篇
  2005年   312篇
  2004年   211篇
  2003年   204篇
  2002年   149篇
  2001年   111篇
  2000年   131篇
  1999年   140篇
  1998年   121篇
  1997年   129篇
  1996年   144篇
  1995年   105篇
  1994年   102篇
  1993年   83篇
  1992年   71篇
  1991年   62篇
  1990年   66篇
  1989年   43篇
  1988年   39篇
  1987年   20篇
  1986年   27篇
  1985年   18篇
  1984年   17篇
  1983年   12篇
  1982年   14篇
  1981年   13篇
  1980年   9篇
  1979年   7篇
  1975年   5篇
  1974年   5篇
  1970年   12篇
  1966年   3篇
  1937年   5篇
排序方式: 共有9428条查询结果,搜索用时 16 毫秒
1.

We investigate the nature of the relationship between corporate social responsibility (CSR) and corporate financial performance (CFP) by examining how it changes across a third dimension that accounts for firm-specific factors. We propose a semi-latent specification of an endogenous control variable, which can, for the first time, explicitly identify, for each individual firm, the threshold level where the marginal impact of CSR on CFP turns positive. We provide empirical evidence that this threshold depends on the additional dimension and consequently, the previously reported U-shape seems to be an aggregation of relationships of differential magnitude and direction. This disaggregation fits the data better and therefore, we maintain that the addition of a higher dimension, along with the identification of the threshold level, can explain the conflicting results in the literature.

  相似文献   
2.
We experimentally analyze the heat capacity and thermal expansion of reference solids in a wide temperature range from several Kelvin to melting temperature,and establish a universal double-linear relation between the experimental heat capacity Cp and thermal expansion β,which is different from the previous models.The universal behavior between heat capacity and thermal expansion is important to predict the thermodynamic parameters at constant pressure,and is helpful for understanding the nature of thermal properties in solids.  相似文献   
3.
Pan  Nana  Fan  Jishan  Zhou  Yong 《Applications of Mathematics》2021,66(3):373-382
Applications of Mathematics - We prove a regularity criterion for a nonhomogeneous incompressible Ginzburg-Landau-Navier-Stokes system with the Coulomb gauge in ?3. It is proved that if the...  相似文献   
4.
对热等静压(HIP)扩散焊制备的W/Fe/RAFM钢接头进行了正火和回火处理,以恢复其中RAFM钢的 组织和性能。采用电子探针微分析器(EPMA)和掠入射X射线衍射(GIXRD)对W/Fe界面组织的演化进行了分析,采 用剪切测试和扫描电镜(SEM)对接头连接性能的演化进行了测试和分析。结果表明,正火处理后,RAFM钢中的C 元素扩散到了W/Fe界面,Fe2W相中W和C元素含量增加,这导致了接头剪切强度增加,而纯铁中间层强度的增加 则导致了接头剪切位移下降。回火处理后,W/Fe界面形成了W/Fe2W/Fe3W3C/Fe的界面结构,回火态接头Fe2W相 的成分和纯铁中间层强度与HIP态接头基本相同,因此回火态接头室温剪切性能基本与HIP态接头一致。  相似文献   
5.
Wang  Litao  Cheng  Jianfeng  Bao  Chenyang  Wang  Yanhui  Jiang  Qiao  Pan  Yuelong  Liu  Yu  Hong  Tao  Tuo  Xianguo  Leng  Yangchun 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(5):2159-2167
Journal of Radioanalytical and Nuclear Chemistry - Groundwater is the most important factor contributing to the diffusion and migration of radionuclides in the repository. In this paper, the...  相似文献   
6.
采用网络调查法,由浙江科技大脑、巨潮资讯网、浙江省大型科研仪器开放共享平台分别获取了浙江省国产仪器研制项目立项情况、全国仪器仪表行业A股上市企业情况及浙江省国产科研仪器应用现状,并对获取的数据进行了分析,进而梳理了浙江省国产科研仪器发展现状,指出了目前存在的问题,提出了相应的对策建议.  相似文献   
7.
Semens of Astragali Complanati own anti-erectile dysfunction effect; however, the components which contribute to the anti-erectile dysfunction effect remain unclear. This work raised a strategy that integrates liquid chromatography coupled mass spectrometry-based quantitative analysis, anti-erectile dysfunction assessment on impotent rats, and their relationship analysis for pinpointing anti-erectile dysfunction components from semens of Astragali Complanati. For simultaneous quantification of seven major components in raw and salt-processed semens of Astragali Complanati, an accurate and reliable liquid chromatography–mass spectrometry method was developed under multiple reaction monitoring mode. Of note, chloramphenicol was employed as the internal standard. The method showed good linearity and repeatability, where the recovery rates of each component ranged from 98.1 to 104.7%, and the precisions of intra- and interday were all within 3.4%. The method has been used for quantification of the seven major components in 10 batches of raw and salt-processed semens of Astragali Complanati. Then, the anti-erectile dysfunction effects of raw and salt-processed semens of Astragali Complanati were evaluated on impotent rats. Gray relationship analysis and partial least squares regression were combined for elucidating the relationship. As a result, complanatuside, astragalin, complanatoside B, and kaempferol were found to be responsible for anti-erectile dysfunction effect of Astragali Complanati.  相似文献   
8.
Xiang  Wang-Kai  Xie  Qing  Xu  Shan-Shan  Sun  Chen-Xuan  Yu  Cheng-Tao  Zheng  Ying  Pan  Peng-Ju 《高分子科学》2022,40(6):567-575

Stereocomplex (SC) crystallization has been an effective way to improve the physical performances of stereoregular polymers. However, the competition between homo and SC crystallizations can lead to more complicated crystallization kinetics and polymorphic crystalline structure in stereocomplexable polymers, which influences the physical properties of obtained materials. Herein, we select the medium-molecular-weight (MMW) poly(L-lactic acid)/poly(D-lactic acid) (PLLA/PDLA) asymmetric blends with different PDLA fractions (fD=0.01–0.5) as the model system and investigate the effects of fD and crystallization temperature (Tc) on the crystallization kinetics and polymorphic crystalline structure. We observe the fractionated (i.e., multistep) crystallization kinetics and the formation of peculiar β-form homocrystals (HCs) in the asymmetric blends under quiescent conditions, which are strongly influenced by both fD and Tc. Precisely, crystallization of β-form HCs is favorable in the MMW PLLA/PDLA blends with high fD (≥0.2) at a low Tc (80–100 °C). It is proposed that the formation of metastable β-form HCs is attributed to the conformational matching between β-form HCs and SCs, and the stronger constrain effects of precedingly-formed SCs in the early stage of crystallization. Such effects can also cause the multistep crystallization kinetics of MMW PLLA/PDLA asymmetric blends in the heating process.

  相似文献   
9.
Shang  Ao  Luo  Siwei  Zhang  Jianquan  Zhao  Heng  Xia  Xinxin  Pan  Mingao  Li  Chao  Chen  Yuzhong  Yi  Jicheng  Lu  Xinhui  Ma  Wei  Yan  He  Hu  Huawei 《中国科学:化学(英文版)》2022,65(9):1758-1766

Side-chain engineering has been demonstrated as an effective method for fine-tuning the optical, electrical, and morphological properties of organic semiconductors toward efficient organic solar cells (OSCs). In this work, three isomeric non-fullerene small molecule acceptors (SMAs), named BTP-4F-T2C8, BTP-4F-T2EH and BTP-4F-T3EH, with linear and branched alkyl chains substituted on the α or β positions of thiophene as the side chains, were synthesized and systematically investigated. The results demonstrate that the size and substitution position of alkyl side chains can greatly affect the electronic properties, molecular packing as well as crystallinity of the SMAs. After blending with donor polymer D18-Cl, the prominent device performance of 18.25% was achieved by the BTP-4F-T3EH-based solar cells, which is higher than those of the BTP-4F-T2EH-based (17.41%) and BTP-4F-T2C8-based (15.92%) ones. The enhanced performance of the BTP-4F-T3EH-based devices is attributed to its stronger crystallinity, higher electron mobility, suppressed biomolecular recombination, and the appropriate intermolecular interaction with the donor polymer. This work reveals that the side chain isomerization strategy can be a practical way in tuning the molecular packing and blend morphology for improving the performance of organic solar cells.

  相似文献   
10.
Li  Jiashen  Pan  Yun 《Russian Physics Journal》2022,64(9):1715-1723
Russian Physics Journal - The improvement of chip integration leads to the increase of power density of system chips, which leads to the overheating of system chips. When dispatching the power...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号