Synthesis and characterization of polymer linked copper(I) bis(N‐heterocyclic carbene) mechanocatalysts

In this paper, the synthesis and characterization of a series of latent polymeric bis(N‐heterocyclic carbene) (NHC) copper(I) complexes is reported, which can be activated for the copper(I)‐catalyzed azide/alkyne cycloaddition (CuAAC) via ultrasound. To prove the influence of chain length and nature of the polymer towards the activation, poly(isobutylene) (PIB), poly(styrene) (PS) and poly(tetrahydrofuran) (PTHF) are synthesized via living polymerization techniques (LCCP, ATRP, CROP) obtaining different chain lengths (from 2500 to 9000 g/mol), followed by quaternization with N‐methylimidazole, generating the corresponding N‐methylimidazolium‐telechelic polymers. The deprotonation of these macroligands via strong bases like sodium tert‐butoxide (NaO^tBu) or potassium hexamethyldisilazide (KHMDS) yields the free N‐heterocyclic carbenes (NHCs), which are used to coordinate to tetrakis(acetonitrile)copper(I) hexafluorophosphate, forming the final polymer‐based mono‐ and bis(N‐methylimidazole‐2‐ylidene) copper(I)X complexes. The structural proof of these complexes is accomplished via ¹H‐NMR spectroscopy, MALDI‐TOF‐MS and GPC‐techniques. The activation of the copper(I) biscarbene catalysts by ultrasound is studied by GPC, revealing the cleavage of one shielding NHC‐ligand. The initial catalytic latency and the via ultrasound introduced catalytic activation is successfully demonstrated monitoring a CuAAC “click” reaction of benzyl azide and phenylacetylene by in situ ¹H‐NMR spectroscopy introducing thus “click” conversions up to 97%. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 3893–3907     

SOLVENT-FREE CONVERSION OF OXIRANES TO THIIRANES WITH THIOUREA

A simple and efficient method for the conversion of various oxiranes to the corresponding thiiranes using thiourea under solvent free conditions is described.     

Winkelverteilungen elastisch an Edelgas-Atomstrahlen gestreuter Elektronen; Spinpolarisation eines an Argon gestreuten 40 eV-Elektronenstrahls

Various non-leptonic decay modes of baryons are calculated in a simple quark model. Form factors for various matrix elements are taken both from experiment and the quark model. Additionally theK→2π andK→3π decay modes are computed in the same model. The theory has theΔ I=1/2 rule and static SU⁶ built-in. A relation between the∑ ⁺→N ⁺ π ⁺ decay, not calculable in the model, and theK→3π decay is given via an effective six quark interaction. Agreement with experiment is order of magnitude for the baryonic decays and worse for theK decays.     

Superabsorbent hydrogel composites

A new cost‐effective approach to enhance gel strength of superabsorbent hydrogels was invented. Superabsorbent hydrogel composites (SHCs) were prepared through an optimized rapid solution polymerization of concentrated partially neutralized acrylic acid in the presence of a crosslinking agent under normal atmospheric conditions. Kaolin was used as an inorganic component in the polymerization process to strengthen the hydrogel products. FT‐IR spectroscopy was used to confirm grafting of acrylic chains on to the surface of kaolin particles. Morphology of the products was studied by scanning electron microscopy (SEM). Compared with the kaolin‐free hydrogel (control), kaolin caused a reduced equilibrium swelling and swelling rate as low as 17–31% and 19–29%, respectively. Kaolin, however, resulted in enhanced gel strength as high as 21–35% compared to the control. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were used to study thermal properties of the composites. The SHCs exhibited higher thermal stability than the control. Meanwhile, changes in certain thermal transitions reconfirmed the chemical interaction of the acrylic chain with kaolin. These thermostabilized strengthened superabsorbent hydrogels may be considered as good candidates for agricultural application to retain more water under soil pressure. Copyright © 2003 John Wiley & Sons, Ltd.     

Effects of structural factors on filtering operation of photonic band gap air bridges with circular and square shape holes

Applying the finite element analysis on the photonic band-gap materials with a cavity at the center for two types of structures, circular and square shape holes with the same cross section, filtering operation of these structures is simulated and compared. Any variations in the structure parameters, such as cavity length, period and hole dimensions, change the transmission peak and frequency bandwidth of these structures. The effects of rotation of square holes and ellipticity of circular holes on filtering operation are studied. Other new structures such as tapered, shortened and non-uniform rotated structures are proposed and filtering characteristics of them are discussed. It is found that, by rotating the square holes around their axis, it is possible to have a blue-shift in the transmission peak wavelength without notable variations in the filter peak and bandwidth. It is concluded that the increase of elliptical holes diameters length causes the decrease of transmission peak and increase of bandwidth with blueshift of the peak wavelength. This shift is larger for one of the elliptical diameter values considered that is along the waveguide length.     

Separation and determination of closely related lantibiotics by micellar electrokinetic chromatography

A sensitive micellar electrokinetic chromatography (MEKC) method was developed for the separation and determination of four closely related lantibiotics: gallidermin, cinnamycin, duramycin and nisin. Factors affecting the separation of the lantibiotics such as pH, phosphate buffer concentration, SDS concentration and wavelength for UV detection were investigated. By optimizing these experimental conditions, successful separation was achieved between class 1A lantibiotics (nisin and gallidermin) and class 1B lantibiotics (duramycin and cinnamycin). The four lantibiotics were separated within 12 min in 50 mM phosphate buffer at pH 3.95 ± 0.1 containing 80 mM SDS with UV detection of 214 nm. The LOD (S/N = 3) were 61 ng/mL for gallidermin, 57 ng/mL for cinnamycin, 55 ng/mL for duramycin and 58 ng/mL for nisin. The method was successfully applied to real samples such as fermentation broth, bovine colostrum and predrop beer. This method yielded satisfactory results, with quantitative recoveries of spiked lantibiotics in the three samples ranging from 86.1 to 99.6%.     

Synthesis of bio‐based internal and external cross‐linkers based on tannic acid for preparation of antibacterial superabsorbents

Recent researches focus on the synthesis of new cross‐linkers from natural resources. In the current work, functionalized tannic acid was employed as a replacement of petroleum‐based cross‐linkers because of its outstanding biochemical properties. Alkene‐ and epoxy‐functionalized tannic acids were synthesized as internal and external cross‐linkers, respectively. Cross‐linker structures were characterized with Ft‐IR and ¹HNMR analysis. Different amounts, as well as different numbers of alkene functional group, were incorporated during the superabsorbent synthesis. Moreover, the internal cross‐linked superabsorbent was surface cross‐linked with different amounts of epoxy‐functionalized tannic acid and increased the absorbency under load about 10 g g^?1. Free absorption properties in water and saline solution, absorbency under load, and rheological properties of superabsorbents were investigated. In addition, the antibacterial activity of the internal and external cross‐linked superabsorbent was studied against Escherichia coli and Staphylococcus aureus bacteria via different methods and compared with that of conventional superabsorbent.     

Investigation of the different discharge mechanisms in pseudosparkdischarges

The intention of this paper is to give an overview of recent experiments explaining the development and transition of the discharge phases in a pseudospark. The reported experiments include single gap pseudospark discharges in ultra-high-vacuum systems with hydrogen as working gas, as well as multigap pseudospark discharges in argon. Temporally and spatially resolved framing photography, spectrometry, raster electron microscopy and time resolved electrical measurements are presented. The experiments comprise a current range of some hundreds of amps to 60 kA. The results are used to specify the four characteristic phases of the pseudospark: Townsend-, hollow cathode-, high current- and metal vapor arc phase     

Color screening and deconfinement for bound states of heavy quarks

We study the binding and deconfinement of heavy quarks in a thermal environment, using a non-relativistic confinement potential model with color screening. As a result, we obtain the dependence of the dissociation energies, the binding radii and the masses of heavy quark resonances (charmonium and bottonium states) on the color screening lengthr _D of the medium, and we determine for the different resonances those values ofr _D below which no more binding is possible. Finally, we consider the implication of our results on resonance suppression as signal for deconfinement.