Seismic base isolation by nonlinear mode localization

Summary In this paper, the performance of a nonlinear base-isolation system, comprised of a nonlinearly sprung subfoundation tuned in a 1∶1 internal resonance to a flexible mode of the linear primary structure to be isolated, is examined. The application of nonlinear localization to seismic isolation distinguishes this study from other base-isolation studies in the literature. Under the condition of third-order smooth stiffness nonlinearity, it is shown that a localized nonlinear normal mode (NNM) is induced in the system, which confines energy to the subfoundation and away from the primary or main structure. This is followed by a numerical analysis wherein the smooth nonlinearity is replaced by clearance nonlinearity, and the system is excited by ground motions representing near-field seismic events. The performance of the nonlinear system is compared with that of the corresponding linear system through simulation, and the sensitivity of the isolation system to several design parameters is analyzed. These simulations confirm the existence of the localized NNM, and show that the introduction of simple clearance nonlinearity significantly reduces the seismic energy transmitted to the main structure, resulting in significant attenuation in the response. This work was supported in part by the National Science Foundation Grant CMS 00-00060. The authors are grateful for this support.     

Targeted energy transfers in vibro-impact oscillators for seismic mitigation

In the field of seismic protection of structures, it is crucial to be able to diminish ‘as much as possible’ and dissipate ‘as fast as possible’ the load induced by seismic (vibration-shock) energy imparted to a structure by an earthquake. In this context, the concept of passive nonlinear energy pumping appears to be natural for application to seismic mitigation. Hence, the overall problem discussed in this paper can be formulated as follows: Design a set of nonlinear energy sinks (NESs) that are locally attached to a main structure, with the purpose of passively absorbing a significant part of the applied seismic energy, locally confining it and then dissipating it in the smallest possible time. Alternatively, the overall goal will be to demonstrate that it is feasible to passively divert the applied seismic energy from the main structure (to be protected) to a set of preferential nonlinear substructures (the set of NESs), where this energy is locally dissipated at a time scale fast enough to be of practical use for seismic mitigation. It is the aim of this work to show that the concept of nonlinear energy pumping is feasible for seismic mitigation. We consider a two degree-of-freedom (DOF) primary linear system (the structure to be protected) and study seismic-induced vibration control through the use of Vibro-Impact NESs (VI NESs). Also, we account for the possibility of attaching to the primary structure additional alternative NES configurations possessing essential but smooth nonlinearities (e.g., with no discontinuities). We study the performance of the NESs through a set of evaluation criteria. The damped nonlinear transitions that occur during the operation of the VI NESs are then studied by superimposing wavelet spectra of the nonlinear responses to appropriately defined frequency – energy plots (FEPs) of branches of periodic orbits of underlying Conservative systems.     

Experimental study of non-linear energy pumping occurring at a single fast frequency

Experimental verification of passive non-linear energy pumping in a two-degree-of-freedom system comprising a damped linear oscillator coupled to an essentially non-linear attachment is carried out. In the experiments presented the non-linear attachment interacts with a single linear mode and, hence, energy pumping occurs at a single ‘fast’ frequency in the neighborhood of the eigenfrequency of the linear mode. Good agreement between simulated and experimental results was observed, in spite of the strongly (essentially) non-linear and transient nature of the dynamics of the system considered. The experiments bear out earlier predictions that a significant fraction of the energy introduced directly to a linear structure by an external impulsive (broadband) load can be transferred (pumped) to an essentially non-linear attachment, and dissipated there locally without spreading back to the system. In addition, the reported experimental results confirm that (a) non-linear energy pumping in systems of coupled oscillators can occur only above a certain threshold of the input energy, and (b) there is an optimal value of the energy input at which a maximum portion of the energy is absorbed and dissipated at the NES.     

Synthesis and characterization of eumelanin‐inspired poly(indoylenearylenevinylene)s and poly(indoylenearyleneethynylene)s

Four novel conjugated polymers containing the eumelanin‐inspired indole core have been successfully synthesized using common cross coupling reactions. These polymers differed by the arylene and the carbon–carbon bond linkage. Optoelectronic experiments of these polymers suggest that the ethynylene linkage contributed to the red‐shifted absorption spectra and blue‐shifted emission spectra when compared to the vinylene linkage polymers. Furthermore, the optical bandgaps of the poly(indoylenearyleneethynylene)s (PIAEs) were smaller compared to the poly(indoylenearylenevinylene)s (PIAVs). Surprisingly, the HOMOs of these polymers were less affected by the nature of the carbon–carbon linkage. However, the LUMOs of the PIAEs were lower in comparison to the PIAVs. These eumelanin‐inspired PIAEs and PIAVs are good fluorophores with fluorescence quantum yields ranging from 0.12 to 0.67 and have good thermal stability for applications such as in organic light‐emitting diodes. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 457–463     

A time-domain nonlinear system identification method based on multiscale dynamic partitions

Based on a theoretical foundation for empirical mode decomposition, which dictates the correspondence between the analytical and empirical slow-flow analyses, we develop a time-domain nonlinear system identification (NSI) technique. This NSI method is based on multiscale dynamic partitions and direct analysis of measured time series, and makes no presumptions regarding the type and strength of the system nonlinearity. Hence, the method is expected to be applicable to broad classes of applications involving time-variant/time-invariant, linear/nonlinear, and smooth/non-smooth dynamical systems. The method leads to nonparametric reduced order models of simple form; i.e., in the form of coupled or uncoupled oscillators with time-varying or time-invariant coefficients forced by nonhomogeneous terms representing nonlinear modal interactions. Key to our method is a slow/fast partition of transient dynamics which leads to the identification of the basic fast frequencies of the dynamics, and the subsequent development of slow-flow models governing the essential dynamics of the system. We provide examples of application of the NSI method by analyzing strongly nonlinear modal interactions in two dynamical systems with essentially nonlinear attachments.     

Novel Osmium‐based Coordination Complexes as Photosensitizers for Panchromatic Photodynamic Therapy

Cancer remains a major global malaise requiring the advent of new, efficient and low‐cost treatments. Photodynamic therapy, which combines a photosensitizer and photons to produce cytotoxic reactive oxygen species, has been established as an effective cancer treatment but has yet to become mainstream. One of the main limitations has been the paucity of photosensitizers that are effective over a wide range of wavelengths, can exert their cytotoxic effects in hypoxia, are easily synthesized and produce few if any side effects. To address these shortfalls, three new osmium‐based photosensitizers (TLD1822, TLD1824 and TLD1829) were synthesized and their photophysical and photobiological attributes determined. These photosensitizers are panchromatic (i.e. black absorbers), activatable from 200 to 900 nm and have strong resistance to photobleaching. In vitro studies show photodynamic therapy efficacy with both red and near‐infrared light in normoxic and hypoxic conditions, which translated to good in vivo efficacy of TLD1829 in a subcutaneous murine colon cancer model.     

A ToF-SIMS and XPS study of protein adsorption and cell attachment across PEG-like plasma polymer films with lateral compositional gradients

In this work we report a detailed X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS) study of poly(ethylene glycol) PEG-like chemical gradients deposited via plasma enhanced chemical vapour deposition (PECVD) at two different load powers using diethylene glycol dimethyl ether (DG) as a monomer. Principal component analysis (PCA) was applied to the ToF-SIMS data both before and after protein adsorption on the plasma polymer thin films. Results of the PCA loadings indicated a higher content of hydrocarbon fragments across the higher load power gradient, which adsorbed higher amounts of proteins. Gradients deposited at a lower load power retained a higher degree of monomer like functionality as did the central region directly underneath the knife edge electrode. Analysis of the adsorption of serum proteins (human serum albumin and fetal bovine serum) was monitored across the gradient films and increased with decreasing ether (PEG-like) film chemistries. The effect of protein incubation time on the levels adsorbed fetal bovine serum on the plasma polymer films was critical, with significantly more protein adsorbing after 24 hour incubation times on both gradient films. The attachment of HeLa cells on the gradients appeared to be dictated not only by the surface chemistry, but also by the adsorption of serum proteins. XPS analysis revealed that at surface ether concentrations of less than 70% in the gradient films, significant increases in protein and cell attachment were observed.     

Theory of sheath in a collisional multi-component plasma

The aim of this brief report is to study the behaviour of sheath structure in a multi-component plasma with dust-neutral collisions. The plasma consists of electrons, ions, micron size negatively charged dust particles and neutrals. The sheath-edge potential and sheath width are calculated for collisionally dominated sheath. Comparison of collisionless and collisionally dominated sheath are made.