全文获取类型
收费全文 | 165篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
化学 | 79篇 |
晶体学 | 2篇 |
力学 | 13篇 |
数学 | 13篇 |
物理学 | 61篇 |
出版年
2021年 | 2篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2016年 | 4篇 |
2015年 | 1篇 |
2014年 | 3篇 |
2013年 | 4篇 |
2012年 | 6篇 |
2011年 | 3篇 |
2010年 | 8篇 |
2009年 | 4篇 |
2008年 | 5篇 |
2007年 | 9篇 |
2006年 | 10篇 |
2005年 | 15篇 |
2004年 | 7篇 |
2003年 | 6篇 |
2002年 | 5篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1991年 | 3篇 |
1990年 | 7篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1981年 | 5篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1971年 | 1篇 |
1970年 | 3篇 |
1969年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有168条查询结果,搜索用时 15 毫秒
1.
R. R. Reznik K. P. Kotlyar I. V. Il’kiv I. P. Soshnikov S. A. Kukushkin A. V. Osipov E. V. Nikitina G. E. Cirlin 《Physics of the Solid State》2016,58(10):1952-1955
The potential to grow filamentary GaN nanocrystals by molecular beam epitaxy on a silicon substrate with a nanosized buffer layer of silicon carbide has been demonstrated. Morphological and optical properties of the obtained system have been studied. It has been shown that the intensity of the photoluminescence spectrum peak of such structures is higher than that of the best filamentary GaN nanocrystals without the buffer silicon carbide layer by a factor of more than two. 相似文献
2.
Ortal Haik Francis Susai Amalraj Daniel Hirshberg Luba Burlaka Michael Talianker Boris Markovsky Ella Zinigrad Doron Aurbach Jordan K. Lampert Ji-Yong Shin Martin Schulz-Dobrick Arnd Garsuch 《Journal of Solid State Electrochemistry》2014,18(8):2333-2342
Thermodynamic instability of positive electrodes (cathodes) in Li-ion batteries in humid air and battery solutions results in capacity fading and batteries degradation, especially at elevated temperatures. In this work, we studied thermal interactions between cathode materials Li2MnO3, xLi2MnO3 .(1???x)Li(MnNiCo)O2,LiNi0.33Mn0.33Co0.33O2, LiNi0.4Mn0.4Co0.2O2, LiNi0.8Co0.15Al0.05O2 LiMn1.5Ni0.5O4, LiMn(or Fe)PO4, and battery solutions containing ethylene carbonate (EC) or propylene carbonate (PC), dimethyl carbonate (DMC) or ethylmethyl carbonate (EMC) and LiPF6 salt in the temperature range of 40–400 °C. It was found that these materials are stable chemically and well performing in LiPF6-based solutions up to 60 °C. The thermal decomposition of the electrolyte solutions starts >180 °C. The macro-structural transformations of cathode materials upon exothermic reactions were studied by transmission electron microscopy (TEM), X-ray difraction (XRD) and Raman spectroscopy. Differential scanning calorimetry (DSC) studies have shown that the exothermic reactions in the temperature range of 60–140 °C lead to partial decomposition of both the cathode material and electrolyte solution. The systems thus formed consisted of partially decomposed solutions and partially chemically delithiated cathode materials covered by reactions products. Thermal reactions terminate and this system reaches equilibrium at about 120 °C. It remains stable up to the beginning of the solution decomposition at about 180 °C. The increased content of surface Li2CO3 is found to significantly affect the thermal processes at high temperature range due to extensive exothermic decomposition at low temperatures. 相似文献
3.
Synthesis and Cytotoxic Activity of 1‐{3‐[1‐(5‐Organylsilylfuran‐2‐yl)silinan‐1‐yl]propyl}amines and Some Trimethylgermyl Analogues 下载免费PDF全文
Dr. Luba Ignatovich Dr. Vitalijs Romanovs Velta Muravenko Ilze Sleiksha Dr. Jury Popelis Dr. Irina Shestakova 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(40):12786-12788
New highly cytotoxic 1‐{3‐[1‐(5‐organylsilyl‐furan‐2‐yl)silinan‐1‐yl]propyl}amines and some trimethylgermyl analogues (IC50 1–7 μg mL?1) have been synthesized by a hydrosilylation reaction of aliphatic and heterocyclic N‐allylamines in the presence of Speier’s catalyst. The effects of the silacycle, the element‐organic substituent in position 5 of the furan ring, and the structure of the amine on the cytotoxicity of the new compounds have been studied. 相似文献
4.
Luba Ignatovich Olga Starkova Vitalijs Romanovs Ilze Sleiksha Irina Shestakova Jury Popelis Edmunds Lukevics 《Comptes Rendus Chimie》2013,16(6):621-627
The reaction of 1,2-phenylenediamine with a variety of silicon- or germanium-containing 2-furaldehydes or 2-thienylcarbaldehydes in DMFA gave the corresponding benzimidazole derivatives in moderate yields (36–49%) in the presence of sodium hydrogen sulfite. As a result, a new series of silyl, germyl substituted hetarylbenzimidazoles were synthesized and their in vitro cytotoxicity was studied. The quaternisation of N-substituted benzimidazoles by heating with various alkyl, allyl and propargyl chlorides and bromides leads to the formation of benzimidazolinium salts. Potential cytotoxic activity of synthesized new benzimidazoles and benzimidazolinium salts was tested in vitro on two monolayer tumour cell lines: MG-22A (mouse hepatoma), HT-1080 (human fibrosarcoma) and normal mouse fibroblasts (NIH 3T3) and compared with corresponding benzimidazoles. 相似文献
5.
We describe a general scheme for solving nonconvex optimization problems, where in each iteration the nonconvex feasible set
is approximated by an inner convex approximation. The latter is defined using an upper bound on the nonconvex constraint functions.
Under appropriate conditions, a monotone convergence to a KKT point is established. The scheme is applied to truss topology
design (TTD) problems, where the nonconvex constraints are associated with bounds on displacements and stresses. It is shown
that the approximate convex problem solved at each inner iteration can be cast as a conic quadratic programming problem, hence
large scale TTD problems can be efficiently solved by the proposed method. 相似文献
6.
The two-dimensional problem of the electrochemical dimensional machining of a metal is investigated within the framework of
the model of an ideal stationary process, which makes it possible to use the analogy with the problems of fluid flows with
free surfaces. In the problem considered the cathode (machining tool) takes the form of two parallel semi-infinite rectangular
electrodes. The blank (anode) is a half-plane whose boundary is perpendicular to the cathodes. Depending on the relationship
between the physical and geometrical parameters of the problem, on the machined part (anode) a projection symmetrical about
the center line between the cathodes may be formed. Additional mechanical machining of the part is then required. In order
to exclude such solutions, a condition is obtained for the mathematical parameters which determine the solution of the problem
in the auxiliary complex plane. General and particular limiting cases are considered. For the cases considered the calculation
results are presented in the form of plots of the shape of the part machined. 相似文献
7.
B. D. Kotlyar 《Journal of Mathematical Sciences》1990,51(5):2534-2536
An inequality is obtained connecting the characteristics of a figureG with the characteristics of similar images of a convex figureg contained inG and containingG. In the case wheng is a disk the well-known inequality of Bonnesen is obtained.Translated from Ukrainskií Geometricheskií Sbornik, No. 30, 1987, pp. 49–52. 相似文献
8.
A.A. Saranin A.V. Zotov V.G. Kotlyar O.A. Utas M. Katayama K. Oura 《Surface science》2005,574(1):99-109
Formation of the beryllium (Be) submonolayers on the Si(1 1 1)7 × 7 surface has been studied using scanning tunneling microscopy. It has been found that Be interaction with Si(1 1 1) at 500-700 °C results in a self-assembly formation of the four various types of the highly-ordered nanostructure arrays. The nanostructure arrays develop on top of the “soft” silicide layer, which period and orientation alter with the nanostructure growth: the shorter the nanostructure period, the larger the rotation angle. The main structural parameters of the silicide layer and nanostructure arrays have been established. 相似文献
9.
We study the uncertain dichotomous choice model. In this model a group of decision makers is required to select one of two alternatives. The applications of this model are relevant to a wide variety of areas, such as medicine, management and banking. The decision rule may be the simple majority rule; however, it is also possible to assign more weight to the opinion of members known to be more qualified. The extreme example of such a rule is the expert decision rule. We are concerned with the probability of the expert rule to be optimal. Our purpose is to investigate the behaviour of this probability as a function of the group size for several rather general types of distributions. One such family of distributions is that where the density function of the correctness probability is a polynomial (on the interval [1/2,1]). Our main result is an explicit formula for the probability in question. This contains formerly known results as very special cases. 相似文献
10.
J. Łojewska A. Lubańska P. Miśkowiec T. Łojewski L.M. Proniewicz 《Applied Physics A: Materials Science & Processing》2006,83(4):597-603
This study deals with the quantitative and qualitative interpretation of transmission FTIR spectra of aged model paper samples to prepare the basis for a kinetic model of cellulose degradation involving mixed hydrolytic and oxidative mechanism. The ageing experiments were performed in situ under various conditions (pure water vapour, dried air, 100, 150 °C) to discriminate between hydrolytic and oxidative paths. Our focus was on the spectra between 1500–1900 cm-1, where the products of paper ageing appear in the form of various carbonyl groups. A procedure of spectra standardization was used to interpret the bands area in terms of the conversion of carbon atoms in cellulose. From the time evolution of the bands the overall kinetic curves were generated. The positions of the carbonyl bands were verified by independent experiments and theoretical calculations (DFT method). A simple model involving a hydrolytic reaction route and first order kinetics was positively tested on the available experimental basis. PACS 81.05.-t; 82.20.Wt; 87.15.Rn 相似文献