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1.
This review summarizes experimental evidence for the freezing of reorienting moments in solids. The moments may be of dipolar or quadrupolar nature, or both; they belong to one of the constituents of a mixed-crystal solid. Extensive results are reported for the following systems: KCl doped with hydroxyl, potassium tantalate doped with Li, Na and Nb, alkali halide cyanides and alkali-alkali cyanides, rubidium ammonium dihydrogen phosphate, solid ortho-para hydrogen and argon-nitrogen mixtures. These have clearly glass-like properties. In other systems, results are limited to one or two methods hinting at glass formation; some of those are also reported. Clustering phenomena and the slowdown of reorientations at the freezing temperature are observed in susceptibility measurements and by local probing on nuclear spins. The modulation of the structure by cluster formation is revealed by diffraction experiments. These phenomena are confronted with model predictions and numerical simulations. 相似文献
2.
M. Dumm M. Dressel M. Nicklas P. Lunkenheimer A. Loidl M. Weiden F. Steglich B. Assmann H. Homborg P. Fulde 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,6(3):317-322
The magnetic susceptibility, using dc and electron spin resonance (ESR) methods, the specific heat, and the infrared properties
of the one-dimensional molecular semiconductors lithium phthalocyanine (LiPc) and the iodinated compound LiPcI have been investigated
for temperatures K. LiPc has a half-filled conduction band and is expected to be an organic metal. However, due to the strong Coulomb repulsion
the system is a one-dimensional Mott-Hubbard insulator with a Hubbard gap of 0.75 eV as inferred from optical measurements.
The localized electrons along the molecular stacks behave like a S = 1/2 antiferromagnetic spin chain. The spin susceptibility, as determined by ESR experiments, and the magnetic contribution
to the heat capacity show a Bonner-Fisher type of behavior with an exchange constant K. LiPcI is an intrinsic narrow-gap semiconductor with an optical gap of 0.43 eV. In ESR experiments it is silent, indicating
that all the unpaired electrons have been removed from the macrocycle via doping with iodine.
Received: 16 June 1998 / Accepted: 14 July 1998 相似文献
3.
Mixed crystals of betaine, phosphite and betaine phosphate have been investigated using broadband di-electric spectroscopy
at frequencies 10−1Hz≤ν≤109Hz and temperatures 1.5 K≤T≤300 K for several betaine phosphate concentrationsx. For 0.2≤x≤0.65 an orientational glass state is found at low temperatures. The broad susceptibility spectra were analyzed using the
concepts of distributions of relaxation times and of distributions of energy barriers. A critical comparison of the different
approaches is given. In the mixed crystals that show antiferroelectric order at low temperatures, charge transport phenomena
are studied. The static permittivity of the proton glass-forming crystals is analyzed, in terms of effectively one- and three-dimensional
Ising models that incorporate random fields and random bonds. 相似文献
4.
A. A. Mukhin V. Yu. Ivanov V. D. Travkin S. P. Lebedev A. Pimenov A. Loidl A. M. Balbashov 《JETP Letters》1998,68(4):356-362
The electrical conductivity, magnetic susceptibility, magnetization, and submillimeter (v=5∓20 cm−1) permittivity and dynamic conductivity of La1−x
Sr
x
MnO3 (0≤x≤ 0.45) single crystals are investigated. The anomalies in the temperature dependences of these quantities are identified
with diverse magnetic and structural phase transformations, including antiferromagnetic and ferromagnetic ordering, structural
transitions between strongly distorted (Jahn-Teller) and weakly distorted (pseudocubic) orthorhombic phases, structural transitions
to a rhombohedral phase and unusual transitions to a polaron-ordering state. As a result, the complete T-x phase diagram of the system La1−2x
Sr
x
MnO3 is constructed in a wide interval of temperatures T=4.2∓1050 K and concentrations x=0−0.45.
Pis’ma Zh. éksp. Teor. Fiz. 68, No. 4, 331–336 (25 August 1998) 相似文献
5.
M. Brando N. Büttgen V. Fritsch J. Hemberger H. Kaps H.-A. Krug von Nidda M. Nicklas K. Pucher W. Trinkl A. Loidl E.W. Scheidt M. Klemm S. Horn 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,25(3):289-298
We present susceptibility, microwave resistivity, NMR and heat-capacity results for Li1-xZnx(V1-yTiy)2O4 with 0 ?
x
? 0.3 and 0 ?
y
? 0.3. For all doping levels the susceptibility curves can be fitted with a Curie-Weiss law. The paramagnetic Curie-Weiss temperatures
remain negative with an average value close to that of the pure compound Θ≈ - 36 K. Spin-glass anomalies are observed in the susceptibility, heat-capacity and NMR measurements for both type of dopants.
From the temperature dependence of the spin-lattice relaxation rate we found critical-dynamic behavior in the Zn doped compounds
at the freezing temperatures. For the Ti-doped samples two successive freezing transitions into disordered low-temperature
states can be detected. The temperature dependence of the heat capacity for Zn-doped compounds does not resemble that of canonical
spin glasses and only a small fraction of the total vanadium entropy is frozen at the spin-glass transitions. For pure LiV2O4 the spin-glass transition is completely suppressed. The temperature dependence of the heat capacity for LiV2O4 can be described using a nuclear Schottky contribution and the non-Fermi liquid model, appropriate for a system close to
a spin-glass quantum critical point. Finally an (
x
/
y
,
T
)-phase diagram for the low-doping regime is presented.
Received 16 March 2001 and Received in final form 30 October 2001 相似文献
6.
Brieler FJ Grundmann P Fröba M Chen L Klar PJ Heimbrodt W Krug von Nidda HA Kurz T Loidl A 《Journal of the American Chemical Society》2004,126(3):797-807
Arrays of highly ordered Zn(1-x)MnxS quantum wires with x ranging from 0.01 to 0.3 and with lateral dimensions of 3, 6, and 9 nm were synthesized within mesoporous SiO2 host structures of the MCM-41 and SBA-15 type. The hexagonal symmetry of these arrays (space group p6m) and the high degree of order was confirmed by X-ray diffraction and transmission electron microscopy (TEM) studies. Physisorption measurements show the progressive filling of the pores of the SiO2 host structures, while TEM and Raman studies reveal the wire-like character of the incorporated Zn(1-x)MnxS nanostructures. X-ray absorption near-edge structure, extended X-ray absorption fine structure, photoluminescence excitation (PLE), and electron paramagnetic resonance studies confirm the good crystalline quality of the incorporated Zn(1-x)MnxS guest species and, in particular, that the Mn2+ ions are randomly distributed and are situated on tetrahedrally coordinated cation sites of the Zn(1-x)MnxS wires for all x up to 0.3. The amount of Mn2+ ions loosely bound to the surface of the Zn(1-x)MnxS nanowires is less than 4% of the total Mn content even for the 3 nm nanostructures up to the highest Mn content of x = 0.3. The effects of the reduction of the lateral dimensions on electronic properties of the diluted magnetic semiconductor were studied by PLE spectroscopy. Due to the quantum confinement of the excitons in the wires an increase of the direct band gap with decreasing particle size is observed. 相似文献
7.
Timoshenko's theory of vibrating beams requires a shear correction factor to correctly take into account the effects of shear deformation for different beam cross-sections. This correction is crucial for a precise determination of the shear modulus from the resonant frequencies. Hutchinson's beam theory is used to derive a new shear correction coefficient for anisotropic materials. A comparison is made with other shear coefficients for anisotropic materials published in the literature. Computer-simulated spectra are used to validate the new anisotropic shear correction coefficient. 相似文献
8.
A. Loidl A. Krimmel K. Knorr G. Sparn M. Lang C. Geibel S. Horn A. Grauel F. Steglich B. Welslau N. Grewe H. Nakotte F. R. de Boer A. P. Murani 《Annalen der Physik》1992,504(2):78-91
Elastic and inelastic neutron-scattering studies on the system Ce(Cu1?xNix)2Ge2 are reported. These measurements are complemented by measurements of the magnetic susceptibility, high-field magnetization, heat capacity, thermal expansion, electrical resistivity and thermopower. The results reveal an interesting T-x phase diagram consisting of two different antiferromagnetic phases for x < 0.2 and 0.2 < x < 0.75, respectively, and a heavy-Fermi-liquid regime at higher Ni concentrations. The experimental results are interpreted in terms of an alloying-induced transition from local-moment to itinerant heavy-fermion magnetism. Fingerprints of this latter phase are a strongly reduced ordered moment and a short incommensurate ordering wave vector, in accord with theoretical predictions. A surprisingly good agreement between theory and experiment is found for x > 0.5. Further experimental evidence for different types of antiferromagnetic ordering derives from a line-shape analysis of the quasielastic neutron-scattering intensity, from magnetization and thermopower experiments. 相似文献
9.
The complex conductivity in polycrystalline C60 and C70 has been investigated for frequencies 20 Hz≤ν≤106 Hz and temperatures 10 K≤T≤750 K. The high-frequency dielectric constants εα= 2.6±0.1(C60) and ε∞= 4.6±0.1 (C70) were deduced from these experiments. The observed low temperature relaxation process in C60 fits well into the relaxation dynamics of the C60 molecules as determined by many other experimental techniques operating on very different time scales. In addition to the study of the dipolar relaxation process, the dc and ac conductivities were determined. From the temperature dependence of the dc conductivities energy barriers of EG=1.75±0.1 eV (C60) and EG=1.7±0.1 eV (C70) were estimated. In C70 we found indications for small polaron tunneling. 相似文献
10.
M. Paasch M. Winterlich R. Böhmer R. Sonntag G. J. McIntyre A. Loidl 《Zeitschrift für Physik B Condensed Matter》1995,99(1):333-338
The χ,T phase diagram of (NH4I)x(KI)1−x has been determined using neutron diffraction experiments and dielectric spectroscopy. At low temperatures and with decreasing
χ, the sequence γ, β, ε and glass phase has been detected. The critical concentration χc≈0.55 separates the glassy phase with frozen-in orientational disorder from the ε phase which reveals long-range orientational
order. Close to χc our experiments reveal evidence for two subsequent glass transitions. 相似文献