全文获取类型
收费全文 | 2343篇 |
免费 | 96篇 |
国内免费 | 9篇 |
专业分类
化学 | 1245篇 |
晶体学 | 13篇 |
力学 | 137篇 |
数学 | 503篇 |
物理学 | 550篇 |
出版年
2023年 | 16篇 |
2022年 | 22篇 |
2021年 | 54篇 |
2020年 | 59篇 |
2019年 | 83篇 |
2018年 | 77篇 |
2017年 | 49篇 |
2016年 | 90篇 |
2015年 | 95篇 |
2014年 | 90篇 |
2013年 | 132篇 |
2012年 | 145篇 |
2011年 | 172篇 |
2010年 | 119篇 |
2009年 | 113篇 |
2008年 | 153篇 |
2007年 | 122篇 |
2006年 | 126篇 |
2005年 | 107篇 |
2004年 | 83篇 |
2003年 | 63篇 |
2002年 | 66篇 |
2001年 | 26篇 |
2000年 | 25篇 |
1999年 | 24篇 |
1998年 | 30篇 |
1997年 | 19篇 |
1996年 | 17篇 |
1995年 | 23篇 |
1994年 | 19篇 |
1993年 | 11篇 |
1992年 | 15篇 |
1991年 | 11篇 |
1990年 | 14篇 |
1989年 | 13篇 |
1988年 | 7篇 |
1987年 | 7篇 |
1986年 | 8篇 |
1985年 | 9篇 |
1984年 | 7篇 |
1983年 | 14篇 |
1982年 | 11篇 |
1981年 | 12篇 |
1980年 | 10篇 |
1979年 | 10篇 |
1978年 | 5篇 |
1977年 | 12篇 |
1976年 | 10篇 |
1975年 | 5篇 |
1974年 | 6篇 |
排序方式: 共有2448条查询结果,搜索用时 15 毫秒
1.
Dr. Christin Kirst Jonathan Tietze Dr. Peter Mayer Prof. Dr. Hans-Christian Böttcher Prof. Dr. Konstantin Karaghiosoff 《ChemistryOpen》2022,11(3):e202100224
The different coordination behavior of the flexible yet sterically demanding, hemilabile P,N ligand bis(quinoline-2-ylmethyl)phenylphosphine ( bqmpp ) towards selected CuI, AgI and AuI species is described. The resulting X-ray crystal structures reveal interesting coordination geometries. With [Cu(MeCN)4]BF4, compound 1 [Cu2(bqmpp)2](BF4)2 is obtained, wherein the copper(I) atoms display a distorted square planar and square pyramidal geometry. The steric demand and π-stacking of the ligand allow for a short Cu⋅⋅⋅Cu distance (2.588(9) Å). CuI complex 2 [Cu4Cl3(bqmpp)2]BF4 contains a rarely observed Cu4Cl3 cluster, probably enabled by dichloromethane as the chloride source. In the cluster, even shorter Cu⋅⋅⋅Cu distances (2.447(1) Å) are present. The reaction of Ag[SbF6] with the ligand leads to a dinuclear compound ( 3 ) in solution as confirmed by 31P{1H} NMR spectroscopy. During crystallization, instead of the expected phosphine complex 3 , a tris(quinoline-2-ylmethyl)bisphenyl-phosphine ( tqmbp ) compound [Ag2(tqmbp)2](SbF6)2 4 is formed by elimination of quinaldine. The Au(I) compound [Au2(bqmpp)2]PF6 ( 5 ) is prepared as expected and shows a linear arrangement of two phosphine ligands around AuI. 相似文献
2.
Georgia Ivanova Nadezhda Bozova Nikolay Petkov Dr. Cunbin An Dr. Benlin Hu Monika Mutovska Konstantin Konstantinov Dr. Yulian Zagranyarski Dr. Vladimira Videva Adelina Yordanova Prof. Martin Baumgarten Prof. Anela Ivanova 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(16):e202104411
Computational modeling of the optical characteristics of organic molecules with potential for thermally activated delayed fluorescence (TADF) may assist markedly the development of more efficient emitting materials for organic light-emitting diodes. Recent theoretical studies in this area employ mostly methods from density functional theory (DFT). In order to obtain accurate predictions within this approach, the choice of a proper functional is crucial. In the current study, we focus on testing the performance of a set of DFT functionals for estimation of the excitation and emission energy and the excited singlet-triplet energy gap of three newly synthesized compounds with capacity for TADF. The emitters are designed specifically to enable charge transfer by π-electron conjugation, at the same time possessing high-energy excited triplet states. The functionals chosen for testing are from various groups ranging from gradient-corrected through global hybrids to range-separated ones. The results show that the monitored optical properties are especially sensitive to how the long-range part of the exchange energy is treated within the functional. The accurate functional should also be able to provide well balanced distribution of the π-electrons among the molecular fragments. Global hybrids with moderate (less than 0.4) share of exact exchange (B3LYP, PBE0) and the meta-GGA HSE06 are outlined as the best performing methods for the systems under study. They can predict all important optical parameters correctly, both qualitatively and quantitatively. 相似文献
3.
Dong Gun Oh Prof. Hristiyan A. Aleksandrov Haneul Kim Dr. Iskra Z. Koleva Dr. Konstantin Khivantsev Prof. Georgi N. Vayssilov Prof. Ja Hun Kwak 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(49):e202200684
Pd-based catalysts are the most widely used for CO oxidation because of their outstanding catalytic activity and thermal stability. However, fundamental understanding of the detailed catalytic processes occurring on Pd-based catalysts under realistic conditions is still lacking. In this study, we investigated CO oxidation on metallic Pd clusters supported on Al2O3 and SiO2. High-angle annular dark-field scanning transmission electron microscopy revealed the formation of similar-sized Pd clusters on Al2O3 and SiO2. In contrast, CO chemisorption analysis indicated a gradual change in the dispersion of Pd (from 0.79 to 0.2) on Pd/Al2O3 and a marginal change in the dispersion (from 0.4 to 0.24) on Pd/SiO2 as the Pd loading increased from 0.27 to 5.5 wt %; these changes were attributed to differences in the metal-support interactions. Diffuse reflectance infrared Fourier-transform spectroscopy revealed that fewer a-top CO species were present in Pd supported on Al2O3 than those in Pd supported on SiO2, which is related to the morphological differences in the metallic Pd clusters on these two supports. Despite the different dispersion profiles and surface characteristics of Pd, O2 titration demonstrated that linearly bound CO (with an infrared signal at 2090 cm−1) reacted first with oxygen in the case of CO-saturated Pd on Al2O3 and SiO2, which suggests that a-top CO on the terrace site plays an important role in CO oxidation. The experimental observations were corroborated by periodic density functional calculations, which confirmed that CO oxidation on the (111) terrace sites is most plausible, both kinetically and thermodynamically, compared to that on the edge or corner sites. This study will deepen the fundamental understanding of the effect of Pd clusters on CO oxidation under reaction conditions. 相似文献
4.
Azhibekov A. K. Penionzhkevich Yu. E. Lukyanov S. M. Issatayev T. Maslov V. A. Mendibayev K. Naumenko M. A. Skobelev N. K. Kuterbekov K. A. Mukhambetzhan A. M. 《Physics of Atomic Nuclei》2021,84(5):635-642
Physics of Atomic Nuclei - The results of an experiment carried out on the MAVR high-resolution magnetic spectrometer and devoted to studying neutron transfer in the $${}^{18}\textrm{O}+^{181}$$ Ta... 相似文献
5.
Dr. Alexey S. Kiryutin Mikhail S. Panov Dr. Alexandra V. Yurkovskaya Prof. Dr. Konstantin L. Ivanov Prof. Dr. Geoffrey Bodenhausen 《Chemphyschem》2019,20(5):766-772
A study of long-lived spin order in chlorothiophene carboxylates at both high and low magnetic fields is presented. Careful sample preparation (removal of dissolved oxygen in solution, chelating of paramagnetic impurities, reduction of convection) allows one to obtain very long-lived singlet order of the two coupled protons in chlorothiophene derivatives, having lifetimes of about 130 s in D2O and 240 s in deuterated methanol, which are much longer than the T1-relaxation times (18 and 30 s, respectively, at a field =9.4 T). In protonated solvents the relaxation times become shorter, but the lifetime is still substantially longer than . In addition, long-lived coherences are shown to have lifetimes as long as 30 s. Thiophene derivatives can be used as molecular tags to study slow transport, slow dynamics and slow chemical processes, as has been shown in recent years. 相似文献
6.
7.
Marco Reichel Konstantin Karaghiosoff 《Angewandte Chemie (International ed. in English)》2020,59(30):12268-12281
The introduction of a monofluoromethyl moiety has undoubtedly become a very important area of research in recent years. Owing to the beneficial properties of organofluorine compounds, such as their metabolic stability, the incorporation of the CH2F group as a bioisosteric substitute for various functional groups is an attractive strategy for the discovery of new pharmaceuticals. Furthermore, the monofluoromethyl unit is also widely used in agrochemistry, in pharmaceutical chemistry, and in fine chemicals. The problems associated with climate change and the growing need for environmentally friendly industrial processes mean that alternatives to the frequently used CFC and HFBC fluoromethylating agents (CH2FCl and CH2FBr) are urgently needed and also required by the Montreal Protocol. This has recently prompted many researchers to develop alternative fluoromethylation agents. This Minireview summarizes both the classical and new generation of fluoromethylating agents. Reagents that act via electrophilic, nucleophilic, and radical pathways are discussed, in addition to their precursors. 相似文献
8.
Mathematical Notes - 相似文献
9.
Han Bing-yuan Khoroshilov Andrey V. Tyurin Alexander V. Baranchikov Alexander E. Razumov Mikhail I. Ivanova Olga S. Gavrichev Konstantin S. Ivanov Vladimir K. 《Journal of Thermal Analysis and Calorimetry》2020,142(4):1533-1543
Journal of Thermal Analysis and Calorimetry - Thermodynamic properties (heat capacity Cp, entropy S°, enthalpy change ΔH° and reduced Gibbs energy ΔΦ°) of crystalline... 相似文献
10.
Optics and Spectroscopy - We propose an approach to the analysis and interpretation of spectra of photoinduced circular dichroism (PICD) of semiconductor nanocrystals, in particular, quantum dots,... 相似文献