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1.
To improve our understanding of the combustion characteristics of propyne, new experimental data for ignition delay times (IDTs), pyrolysis speciation profiles and flame speed measurements are presented in this study. IDTs for propyne ignition were obtained at equivalence ratios of 0.5, 1.0, and 2.0 in ‘air’ at pressures of 10 and 30 bar, over a wide range of temperatures (690–1460 K) using a rapid compression machine and a high-pressure shock tube. Moreover, experiments were performed in a single-pulse shock tube to study propyne pyrolysis at 2 bar pressure and in the temperature range 1000–1600 K. In addition, laminar flame speeds of propyne were studied at an unburned gas temperature of 373 K and at 1 and 2 bar for a range of equivalence ratios. A detailed chemical kinetic model is provided to describe the pyrolytic and combustion characteristics of propyne across this wide-ranging set of experimental data. This new mechanism shows significant improvements in the predictions for the IDTs, fuel pyrolysis and flame speeds for propyne compared to AramcoMech3.0. The improvement in fuel reactivity predictions in the new mechanism is due to the inclusion of the propyne + H?2 reaction system along with ?H radical addition to the triple bonds of propyne and subsequent reactions.  相似文献   
2.
Annals of Global Analysis and Geometry - In this paper, we show that any convex affine domain with a nonempty limit set on the boundary under the action of the identity component of the...  相似文献   
3.
Ukrainian Mathematical Journal - Two determinants of Wronskian matrices are evaluated for the case where the matrix rows are partitioned into n blocks. Similar formulae are derived for the matrices...  相似文献   
4.
Journal of Applied Spectroscopy - With the COVID-19 outbreak, many challenges are posed before the scientific world to curb this pandemic. The diagnostic testing, treatment, and vaccine development...  相似文献   
5.
Jiang  H.  Lei  Z.  Bai  R.  Liu  J.  Guo  Z.  Dong  H.  Feng  W. 《Experimental Mechanics》2021,61(5):867-883
Experimental Mechanics - Ratcheting is an important mechanical behavior of metals and alloys, which is caused by the repeated accumulations of tensile and compressive strain in circle load....  相似文献   
6.
Waterproof light-emitting perovskite–polymer composite microparticles are synthesized by a continuous one-step microfluidic reactor, which enables in situ production of metal halide perovskite nanoparticles (MHP-NPs) by the ligand-assisted reprecipitation process (LARP) and the encapsulation of MHP-NPs by UV cross-linking polymerization in the microfluidic channel. Successful encapsulation of MHP-NPs in polymer microparticles is attributed to the co-dispersion of an LARP solution and UV polymerizable solution in an aqueous continuous phase within the microfluidic channel, in which N,N-dimethylformamide, in co-dispersion droplets, is continuously extracted to the aqueous medium upon UV polymerization. MHP-NPs–polymer composite microparticles show enhanced stability against air and moisture.  相似文献   
7.
The energy spectra of three types of two-dimensional potentials(we will call them‘Davidson-like potentials’(DLPs)),characterized by four minima separated by barriers,are investigated.The predictions for spectra and wave functions are obtained by using the nine-point finite-difference method.For these potentials,with the existence of a single configuration,a transition of spectra,as a function of barrier height,is covered from tunneling splitting modes to fluctuations phenomena,with equal peaks wave functions,crossing to the spectra of purely anharmonic oscillator potentials(AOPs).A different type of phase transition occurs when two(or more)configurations coexist.With the change of the parameters,a transition of spectra is covered from coexistence phenomena of two distinct quantum tunneling modes to fluctuations phenomena,with unequal peaks wave functions,crossing to the spectra of purely AOPs.Using DLPs,a particular application of the coherent quadropole-octupole model to describe energy bands with alternating parity of the nuclei100Mo,146,148Nd,148,150Sm,220Ra,220,222Rn,and220,222Th is presented.The global parametrization of the model for the selected nuclei is achieved.  相似文献   
8.
Recent theoretical studies have shown that termolecular chemistry can be facilitated through reactions of flame radicals (H, O, and OH) or O2 with highly-energized collision complexes (either radical or stable species) formed in exothermic reactions. In this work, radical-radical recombination reaction induced termolecular chemistry and its impact on combustion modeling was studied. Two recombination reactions, H + CH3 + M → CH4 + M and H + OH + M → H2O + M, were analyzed using ab-initio master equation analyses guided by quasiclassical trajectory results. The dynamics results and the master equation calculations indicate that CH4? and H2O? (formed in the two radical-radical reactions outlined above) react rapidly with flame radicals and O2 at rates that are competitive with collisional cooling. The addition of these processes into conventional combustion modeling requires two modifications: the inclusion of the new nonthermal termolecular reaction rates and the simultaneous reduction of the competing recombination reaction rates. The former is described with newly derived Arrhenius expressions based on quasiclassical trajectories, and the latter is achieved by perturbing the recombination reaction rate during the simulation. Kinetic modeling was used to gauge the impact of including this nonthermal chemistry for H2/CH4-air laminar flames speeds. Inclusion of this nonthermal chemistry has a noticeable impact on simulated flame speeds. The procedure developed here can be utilized to properly quantify the effects of such nonthermal reactions in macroscopic kinetic models.  相似文献   
9.
10.
Chen  C. Y.  Kao  C. L.  Huang  S. T.  Kuo  C. E.  Song  P. L.  Li  W. J.  Hsu  L. T.  Li  H. T. 《Chemistry of Natural Compounds》2022,58(1):107-109
Chemistry of Natural Compounds -  相似文献   
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