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1.
Numerical Algorithms - We develop a formal construction of a pointwise divergence-free basis in the nonconforming virtual element method of arbitrary order for the Stokes problem introduced in Zhao... 相似文献
2.
Nonlinear Dynamics - In this paper, we address the issue of $$\mathcal {H}_{\infty }$$ synchronization for two identical chaotic systems with time-varying delays and uncertainties under... 相似文献
3.
Dr. Zhoulong Fan Katherine L. Bay Dr. Xiangyang Chen Zhe Zhuang Han Seul Park Dr. Kap-Sun Yeung Prof. Dr. K. N. Houk Prof. Dr. Jin-Quan Yu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(12):4800-4807
A simple and efficient nitrile-directed meta-C−H olefination, acetoxylation, and iodination of biaryl compounds is reported. Compared to the previous approach of installing a complex U-shaped template to achieve a molecular U-turn and assemble the large-sized cyclophane transition state for the remote C−H activation, a synthetically useful phenyl nitrile functional group could also direct remote meta-C−H activation. This reaction provides a useful method for the modification of biaryl compounds because the nitrile group can be readily converted to amines, acids, amides, or other heterocycles. Notably, the remote meta-selectivity of biphenylnitriles could not be expected from previous results with a macrocyclophane nitrile template. DFT computational studies show that a ligand-containing Pd–Ag heterodimeric transition state (TS) favors the desired remote meta-selectivity. Control experiments demonstrate the directing effect of the nitrile group and exclude the possibility of non-directed meta-C−H activation. Substituted 2-pyridone ligands were found to be key in assisting the cleavage of the meta-C−H bond in the concerted metalation–deprotonation (CMD) process. 相似文献
4.
Gangyong Lee Jae Keol Park S. Tariq Rizvi Cosmin S. Roman 《Journal of Pure and Applied Algebra》2018,222(9):2427-2455
Let V be a module with . V is called a quasi-Baer module if for each ideal J of S, for some . On the other hand, V is called a Rickart module if for each , for some . For a module N, the quasi-Baer module hull (resp., the Rickart module hull ) of N, if it exists, is the smallest quasi-Baer (resp., Rickart) overmodule, in a fixed injective hull of N. In this paper, we initiate the study of quasi-Baer and Rickart module hulls. When a ring R is semiprime and ideal intrinsic over its center, it is shown that every finitely generated projective R-module has a quasi-Baer hull. Let R be a Dedekind domain with F its field of fractions and let be any set of R-submodules of . For an R-module with , we show that has a quasi-Baer module hull if and only if is semisimple. This quasi-Baer hull is explicitly described. An example such that has no Rickart module hull is constructed. If N is a module over a Dedekind domain for which is projective and , where is the torsion submodule of N, we show that the quasi-Baer hull of N exists if and only if is semisimple. We prove that the Rickart module hull also exists for such modules N. Furthermore, we provide explicit constructions of and and show that in this situation these two hulls coincide. Among applications, it is shown that if N is a finitely generated module over a Dedekind domain, then N is quasi-Baer if and only if N is Rickart if and only if N is Baer if and only if N is semisimple or torsion-free. For a direct sum of finitely generated modules, where R is a Dedekind domain, we show that N is quasi-Baer if and only if N is Rickart if and only if N is semisimple or torsion-free. Examples exhibiting differences between the notions of a Baer hull, a quasi-Baer hull, and a Rickart hull of a module are presented. Various explicit examples illustrating our results are constructed. 相似文献
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6.
We demonstrate a reversible shape‐morphing with concurrent fluorescence switching in the nanomaterials which are complexed with cucurbit[7]uril (CB[7]) in water. The cyanostilbene derivative alone forms ribbon‐like two‐dimensional (2D) nanocrystals with bright yellow excimeric emission in water (λem=540 nm, ΦF=42 %). Upon CB[7] addition, however, the ribbon‐like 2D nanocrystals immediately transform to spherical nanoparticles with significant fluorescence quenching and blue‐shifting (λem=490 nm, ΦF=1 %) through the supramolecular complexation of the cyanostilbene and CB[7]. Based on this reversible fluorescence switching and shape morphing, we could demonstrate a novel strategy of turn‐on fluorescence sensing of spermine and also monitoring of lysine decarboxylase activity. 相似文献
7.
Jae Sang Lee Byung Ho Shin Byoung Yong Yoo Sun‐Young Nam Miji Lee Juhwan Choi Hansoo Park Young Bin Choy Chan Yeong Heo Won‐Gun Koh 《Macromolecular bioscience》2019,19(12)
The surface of poly(dimethylsiloxane) (PDMS) is grafted with poly(acrylic acid) (PAA) layers via surface‐initiated photopolymerization to suppress the capsular contracture resulting from a foreign body reaction. Owing to the nature of photo‐induced polymerization, various PAA micropatterns can be fabricated using photolithography. Hole and stripe micropatterns ≈100‐µm wide and 3‐µm thick are grafted onto the PDMS surface without delamination. The incorporation of PAA micropatterns provides not only chemical cues by hydrophilic PAA microdomains but also topographical cues by hole or stripe micropatterns. In vitro studies reveal that a PAA‐grafted PDMS surface has a lower proliferation of both macrophages (Raw 264.7) and fibroblasts (NIH 3T3) regardless of the pattern presence. However, PDMS with PAA micropatterns, especially stripe micropatterns, minimizes the aggregation of fibroblasts and their subsequent differentiation into myofibroblasts. An in vivo study also shows that PDMS samples with stripe micropatterns polarized macrophages into anti‐inflammatory M2 macrophages and most effectively inhibits capsular contracture, which is demonstrated by investigation of inflammation score, transforming‐growth‐factor‐β expression, number of macrophages, and myofibroblasts as well as the collagen density and capsule thickness. 相似文献
8.
Santosh Kumar Sejy Lee Reju George Thomas Seung‐Jea Lee Hong‐Joon Lee In‐Kyu Park Yong Yeon Jeong Tae‐Ho Yoon Dong‐Chan Shin Jae‐Suk Lee 《Journal of polymer science. Part A, Polymer chemistry》2019,57(11):1165-1172
Self‐emulsion polymerization (SEP), a green route developed by us for the polymerization of amphiphilic monomers, does not require any emulsifier or an organic solvent except that the water‐soluble initiators such as 2,2′‐azobis[2‐(2‐imidazolin‐2‐yl)propane]dihydrochloride (VA‐044) and potassium persulfate (KPS) are only used. We report here the polymer nanoscaffolds from a number of amphiphilic monomers, which can be used for in situ encapsulation of a variety of nanoparticles. As a demonstration of the efficacy of these nanoscaffolds, the synthesis of a biocompatible hybrid nanoparticle (nanohybrid), prepared by encapsulating Fe3O4 magnetic nanoparticle (Fe3O4 MNPs) in poly(2‐hydroxyethyl methacrylate) in water, for MRI application is presented. The nanohybrid prepared following the SEP in the form of an emulsion does not involve the use of any stabilizing agent, crosslinker, polymeric emulsifier, or surfactant. This water‐soluble, spherical, and stable nanohybrid containing Fe3O4 MNPs of average size 10 ± 2 nm has a zeta potential value of ?41.89 mV under physiological conditions. Magnetic measurement confirmed that the nanohybrid shows typical magnetic behavior having a saturation magnetization (Ms) value of 32.3 emu/g and a transverse relaxivity (r2) value of 29.97 mM?1 s?1, which signifies that it can be used as a T2 contrast agent in MRI. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 相似文献
9.
In recent years, the interaction between the local positivity of divisors and Okounkov bodies has attracted considerable attention, and there have been attempts to find a satisfactory theory of positivity of divisors in terms of convex geometry of Okounkov bodies. Many interesting results in this direction have been established by Choi–Hyun–Park–Won [4] and Küronya–Lozovanu [17], [18], [19] separately. The first aim of this paper is to give uniform proofs of these results. Our approach provides not only a simple new outlook on the theory but also proofs for positive characteristic in the most important cases. Furthermore, we extend the theorems on Seshadri constants to graded linear series setting. Finally, we introduce the integrated volume function to investigate the relation between Seshadri constants and filtered Okounkov bodies introduced by Boucksom–Chen [3]. 相似文献
10.
Afif Ahmed Radenahmad Nikdalila Rahman Seikh Mohammad Habibur Torino Nico Saqib Muhammad Hossain Shahzad Park Jun-Young Azad Abul Kalam 《Journal of Solid State Electrochemistry》2022,26(1):111-120
Journal of Solid State Electrochemistry - Protonic ceramic fuel cells have become extremely interesting due to their high power output at the intermediate temperature range... 相似文献