全文获取类型
收费全文 | 5139篇 |
免费 | 149篇 |
国内免费 | 18篇 |
专业分类
化学 | 3739篇 |
晶体学 | 16篇 |
力学 | 61篇 |
数学 | 934篇 |
物理学 | 556篇 |
出版年
2020年 | 49篇 |
2019年 | 50篇 |
2018年 | 36篇 |
2016年 | 92篇 |
2015年 | 92篇 |
2014年 | 100篇 |
2013年 | 163篇 |
2012年 | 160篇 |
2011年 | 224篇 |
2010年 | 113篇 |
2009年 | 105篇 |
2008年 | 213篇 |
2007年 | 201篇 |
2006年 | 203篇 |
2005年 | 227篇 |
2004年 | 177篇 |
2003年 | 147篇 |
2002年 | 104篇 |
2001年 | 42篇 |
2000年 | 49篇 |
1997年 | 64篇 |
1996年 | 60篇 |
1995年 | 67篇 |
1994年 | 48篇 |
1993年 | 50篇 |
1992年 | 65篇 |
1991年 | 44篇 |
1990年 | 67篇 |
1989年 | 37篇 |
1988年 | 61篇 |
1987年 | 64篇 |
1986年 | 40篇 |
1985年 | 93篇 |
1984年 | 55篇 |
1983年 | 59篇 |
1982年 | 67篇 |
1981年 | 62篇 |
1980年 | 48篇 |
1979年 | 64篇 |
1978年 | 68篇 |
1977年 | 51篇 |
1976年 | 73篇 |
1975年 | 72篇 |
1974年 | 52篇 |
1973年 | 46篇 |
1972年 | 39篇 |
1971年 | 32篇 |
1970年 | 45篇 |
1967年 | 36篇 |
1966年 | 41篇 |
排序方式: 共有5306条查询结果,搜索用时 46 毫秒
1.
Tim Granath Karl Mandel Peer Löbmann 《Particle & Particle Systems Characterization》2021,38(8):2100098
This study demonstrates how the method of thermally assisted oxidative precipitation in water can be opened for—the so far neglected—metal organic iron(II) complexes (herein: citrate) in order to obtain, in one step, ferromagnetic magnetite nanoparticles, possessing essential ligand properties. Based on a dedicated analysis of the specific precursor in combination with the consideration of known properties of the ligand, it is possible to identify existing inhibition-attributes of the iron organyl such that these can be overcome. Moreover, they can be exploited in a targeted manner; thus, simply by changing concentrations, a variety of magnetite nanoparticle morphologies with distinct properties can be obtained. In the case of the herein investigated ferrous citrate, three major inhibition effects are identified. While two of them efficiently prevent the formation of magnetite and need to be addressed to be overcome, the third can be exploited to selectively synthesize, for example, relatively stable carboxyl group-bearing nuclei clusters, exhibiting the properties of magnetically responsive photonic crystals, or relatively large mesocrystals, whose intraparticular magnetic interactions are apparently disturbed. 相似文献
2.
3.
4.
Metabolic profiling of new synthetic cannabinoids AMB and 5F‐AMB by human hepatocyte and liver microsome incubations and high‐resolution mass spectrometry 下载免费PDF全文
5.
Mathematische Semesterberichte - 相似文献
6.
7.
QiuHong Wang Abdusalam Abdukerim Wei Chen Xun Chen YunHua Chen XiangYi Cui YingJie Fan DeQing Fang ChangBo Fu LiSheng Geng Karl Giboni Franco Giuliani LinHui Gu XuYuan Guo Ke Han ChangDa He Di Huang Yan Huang YanLin Huang Zhou Huang Peng Ji XiangDong Ji YongLin Ju YiHui Lai Kun Liang HuaXuan Liu JiangLai Liu WenBo Ma YuGang Ma YaJun Mao Yue Meng Parinya Namwongsa KaiXiang Ni JinHua Ning XuYang Ning XiangXiang Ren ChangSong Shang Lin Si AnDi Tan AnQing Wang HongWei Wang Meng Wang SiGuang Wang XiuLi Wang Zhou Wang MengMeng Wu ShiYong Wu JingKai Xia MengJiao Xiao PengWei Xie BinBin Yan JiJun Yang Yong Yang ChunXu Yu Jumin Yuan Dan Zhang HongGuang Zhang Tao Zhang Li Zhao QiBin Zheng JiFang Zhou Ning Zhou XiaoPeng Zhou 《中国科学:物理学 力学 天文学(英文版)》2020,(3):54-63
In dark matter direct detection experiments,neutron is a serious source of background,which can mimic the dark matter-nucleus scattering signals.In this paper,we present an improved evaluation of the neutron background in the PandaX-II dark matter experiment by a novel approach.Instead of fully relying on the Monte Carlo simulation,the overall neutron background is determined from the neutron-induced high energy signals in the data.In addition,the probability of producing a dark-matter-like background per neutron is evaluated with a complete Monte Carlo generator,where the correlated emission of neutron(s)andγ(s)in the(α,n)reactions and spontaneous fissions is taken into consideration.With this method,the neutron backgrounds in the Run 9(26-ton-day)and Run 10(28-ton-day)data sets of PandaX-II are estimated to be(0.66±0.24)and(0.47±0.25)events,respectively. 相似文献
8.
Dr. Karl P. J. Gustafson Arnar Guðmundsson Dr. Éva G. Bajnóczi Dr. Ning Yuan Prof. Xiaodong Zou Prof. Ingmar Persson Prof. Jan-E. Bäckvall 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(15):3411-3419
The activation process of a known Ru-catalyst, dicarbonyl(pentaphenylcyclopentadienyl)ruthenium chloride, has been studied in detail using time resolved in situ X-ray absorption spectroscopy. The data provide bond lengths of the species involved in the process as well as information about bond formation and bond breaking. On addition of potassium tert-butoxide, the catalyst is activated and an alkoxide complex is formed. The catalyst activation proceeds via a key acyl intermediate, which gives rise to a complete structural change in the coordination environment around the Ru atom. The rate of activation for the different catalysts was found to be highly dependent on the electronic properties of the cyclopentadienyl ligand. During catalytic racemization of 1-phenylethanol a fast-dynamic equilibrium was observed. 相似文献
9.
Dr. Mykhaylo Dukh Walter A. Tabaczynski Sairaman Seetharaman Dr. Zhongping Ou Prof. Dr. Karl M. Kadish Prof. Dr. Francis D'Souza Prof. Dr. Ravindra K. Pandey 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(65):14996-15006
A series of chlorin-bacteriochlorin dyads (derived from naturally occurring chlorophyll-a and bacteriochlorophyll-a), covalently connected either through the meso-aryl or β-pyrrole position (position-3) via an ester linkage have been synthesized and characterized as a new class of far-red emitting fluorescence resonance energy transfer (FRET) imaging, and heavy atom-lacking singlet oxygen-producing agents. From systematic absorption, fluorescence, electrochemical, and computational studies, the role of chlorin as an energy donor and bacteriochlorin as an energy acceptor in these wide-band-capturing dyads was established. Efficiency of FRET evaluated from spectral overlap was found to be 95 and 98 % for the meso-linked and β-pyrrole-linked dyads, respectively. Furthermore, evidence for the occurrence of FRET from singlet-excited chlorin to bacteriochlorin was secured from studies involving femtosecond transient absorption studies in toluene. The measured FRET rate constants, kFRET, were in the order of 1011 s−1, suggesting the occurrence of ultrafast energy transfer in these dyads. Nanosecond transient absorption studies confirmed relaxation of the energy transfer product, 1BChl*, to its triplet state, 3Bchl*. The 3Bchl* thus generated was capable of producing singlet oxygen with quantum yields comparable to their monomeric entities. The occurrence of efficient FRET emitting in the far-red region and the ability to produce singlet oxygen make the present series of dyads useful for photonic, imaging and therapy applications. 相似文献
10.
Saba Seyedi Ben Ma Megan Groves Hal King Karl G. Linden 《Photochemistry and photobiology》2023,99(5):1293-1298
“Far UV-C” is an effective disinfection method that can be deployed in occupied areas. Commercially available Krypton Chloride (KrCl*) excimer lamps filtered to emit at 222 nm are effective in disinfecting pathogens and safe for human exposure up to an allowable threshold exposure, which is much longer than for conventional UV lamps emitting at 254 nm. Laboratory and controlled field testing of a filtered KrCl* excimer lamp for disinfection of a virus suspended in a thin film aqueous solution in an occupied office setting was conducted. Complete inactivation of almost 6 log (99.9999%) of Phi6 bacteriophage virus was achieved in ~20 min of exposure time in a field setting, equivalent to a dose of about 10 mJ cm−2. The Phi6 inactivation rate constant for the field test results were not statistically different from laboratory values (P > 0.05, paired t-test). When positioned at 1 m distance from possible human exposure, this device can be used safely for almost 4.5 h of continuous direct exposure without any acute or long-term adverse health effects. This study illustrates the applicability and deployment of Far UV-C for pathogen reduction and can help in decision making for implementation of Far UV-C for disinfection in human-occupied environments. 相似文献