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排序方式: 共有1262条查询结果,搜索用时 15 毫秒
1.
This study investigates the effects of intermediate temperature heat release (ITHR) on autoignition reactivity of full boiling range gasolines with different octane sensitivity through intake temperature and simulated exhaust gas recirculation (EGR) sweeps in a homogenous charge compression ignition (HCCI) engine. To isolate the ITHR effects, low temperature reactivity was suppressed through the use of high intake temperature and low intake oxygen mole fraction. For quantification of ITHR, a new method was applied to the engine data by examining the maximum value of the second derivative of heat release rate. Combustion phasing comparisons of fuels with octane sensitivity showed that fuel with less octane sensitivity became more reactive as intake temperature and simulated EGR ratio decreased, while fuel with higher octane sensitivity had a reverse trend. For all of the fuels that were tested, the amount of ITHR increased as the intake temperature and oxygen mole fraction increased. These ITHR trends, depending on octane sensitivity, were almost identical with the trends of combustion phasing, showing that ITHR significantly affects fuel autoignition reactivity and determines octane sensitivity.  相似文献   
2.
We study two types of dynamical extensions of Lucas sequences and give elliptic solutions for them. The first type concerns a level-dependent (or discrete time-dependent) version involving commuting variables. We show that a nice solution for this system is given by elliptic numbers. The second type involves a non-commutative version of Lucas sequences which defines the non-commutative (or abstract) Fibonacci polynomials introduced by Johann Cigler. If the non-commuting variables are specialized to be elliptic-commuting variables the abstract Fibonacci polynomials become non-commutative elliptic Fibonacci polynomials. Some properties we derive for these include their explicit expansion in terms of normalized monomials and a non-commutative elliptic Euler–Cassini identity.  相似文献   
3.
A unique chain-rupturing transformation that converts an ether functionality into two hydrocarbyl units and carbon monoxide is reported, mediated by iridium(i) complexes supported by aminophenylphosphinite (NCOP) pincer ligands. The decarbonylation, which involves the cleavage of one C–C bond, one C–O bond, and two C–H bonds, along with formation of two new C–H bonds, was serendipitously discovered upon dehydrochlorination of an iridium(iii) complex containing an aza-18-crown-6 ether macrocycle. Intramolecular cleavage of macrocyclic and acyclic ethers was also found in analogous complexes featuring aza-15-crown-5 ether or bis(2-methoxyethyl)amino groups. Intermolecular decarbonylation of cyclic and linear ethers was observed when diethylaminophenylphosphinite iridium(i) dinitrogen or norbornene complexes were employed. Mechanistic studies reveal the nature of key intermediates along a pathway involving initial iridium(i)-mediated double C–H bond activation.

A unique chain-rupturing transformation that converts an ether functionality into two hydrocarbyl units and carbon monoxide is reported.  相似文献   
4.
5.
A simple and divergent synthetic strategy of bottlebrush polymers (BBPs) is presented, consisting of postpolymerization modification of a macromonomer and grafting-through polymerization. Beginning with a single macromonomer, its direct modification could build a library of macromonomers with an identical chain length, thus guaranteeing the precision in the synthesis of BBPs. In this study, a newly designed norbornenyl-terminated poly(methyl acrylate) (NB-PMA) is proposed as a chemically robust template. Ti-mediated transesterification of NB-PMA successfully produces structurally diverse polyacrylates while maintaining the terminal norbornenyl group intact. All macromonomers obtained from transesterification possess a good grafting-through ring-opening metathesis polymerization reactivity, furnishing homo, random, and block BBPs in a controllable manner. Moreover, atomic force microscopy analysis supports the controlled side-chain length distribution in the resulting BBPs.  相似文献   
6.
This paper addresses the problem of global robust fault accommodation tracking for a class of uncertain nonlinear systems with unknown powers and actuator faults. It is assumed that the powers of the concerned system are unknown time-varying functions, all system nonlinearities are unknown, and unknown actuator faults depend on the time-varying power of a control input. A fault accommodation state-feedback controller is explicitly constructed based on the nonlinear error transformation technique using time-varying performance functions. Global tracking with the preselected performance bounds is established in the presence of unknown time-varying powers and unexpected actuator faults. Different from the previous results dealing with the problem of unknown time-varying powers, the proposed tracking strategy does not require the knowledge of the bounds of the time-varying powers and the nonlinear bounding functions of system nonlinearities. An underactuated mechanical system is simulated to validate the effectiveness of the proposed theoretical approach.  相似文献   
7.
In allogeneic transplantation, including the B6 anti-BALB.B settings, H60 and H4 are two representative dominant minor histocompatibility antigens that induce strong CD8 T-cell responses. With different distribution patterns, H60 expression is restricted to hematopoietic cells, whereas H4 is ubiquitously expressed. H60-specific CD8 T-cell response has been known to be dominant in most cases of B6 anti-BALB.B allo-responses, except in the case of skin transplantation. To understand the mechanism underlying the subdominance of H60 during allogeneic skin transplantation, we investigated the dynamics of the H60-specific CD8 T cells in B6 mice transplanted with allogeneic BALB.B tail skin. Unexpectedly, longitudinal bioluminescence imaging and flow cytometric analyses revealed that H60-specific CD8 T cells were not always subdominant to H4-specific cells but instead showed a brief dominance before the H4 response became predominant. H60-specific CD8 T cells could expand in the draining lymph node and migrate to the BALB.B allografts, indicating their active participation in the anti-BALB.B allo-response. Enhancing the frequencies of H60-reactive CD8 T cells prior to skin transplantation reversed the immune hierarchy between H60 and H4. Additionally, H60 became predominant when antigen presentation was limited to the direct pathway. However, when antigen presentation was restricted to the indirect pathway, the expansion of H60-specific CD8 T cells was limited, whereas H4-specific CD8 T cells expanded significantly, suggesting that the temporary immunodominance and eventual subdominance of H60 could be due to their reliance on the direct antigen presentation pathway. These results enhance our understanding of the immunodominance phenomenon following allogeneic tissue transplantation.  相似文献   
8.
9.
Barium octoborate has been synthesized by air firing of co-precipitated borates with additional boric acid. During the firing process, samarium ions doped into the matrix are reduced to the divalent state. Two different divalent samarium emission spectra have been observed from the material as a function of the firing history, even though the structure, as identified by powder X-ray diffraction remained consistent. A minor barium pentaborate impurity, in conjunction with significant thermal variability in the strength of the divalent samarium emission generated by the different sites in the two borate materials, appears to give rise to this phenomenon.  相似文献   
10.
Stability and compatibility between chemical components are essential parameters that need to be considered in the selection of functional materials in configuring a system. In configuring devices such as batteries or solar cells, not only the functionality of individual constituting materials such as electrodes or electrolyte but also an appropriate combination of materials which do not undergo unwanted side reactions is critical in ensuring their reliable performance in long-term operation. While the universal theory that can predict the general chemical reactivity between materials is long awaited and has been the subject of studies with a rich history, traditional ways proposed to date have been mostly based on simple electronic properties of materials such as electronegativity, ionization energy, electron affinity and hardness/softness, and could be applied to only a small group of materials. Moreover, prediction has often been far from accurate and has failed to offer general implications; thus it was practically inadequate as a selection criterion from a large material database, i.e. data-driven material discovery. Herein, we propose a new model for predicting the general reactivity and chemical compatibility among a large number of organic materials, realized by a machine-learning approach. As a showcase, we demonstrate that our new implemented model successfully reproduces previous experimental results reported on side-reactions occurring in lithium–oxygen electrochemical cells. Furthermore, the mapping of chemical stability among more than 90 available electrolyte solvents and the representative redox mediators is realized by this approach, presenting an important guideline in the development of stable electrolyte/redox mediator couples for lithium–oxygen batteries.

Stability and compatibility between chemical components are essential parameters that need to be considered in the selection of functional materials in configuring a system.  相似文献   
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