首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1986篇
  免费   130篇
  国内免费   45篇
化学   1508篇
晶体学   10篇
力学   91篇
数学   195篇
物理学   357篇
  2023年   7篇
  2022年   29篇
  2021年   73篇
  2020年   109篇
  2019年   91篇
  2018年   128篇
  2017年   95篇
  2016年   157篇
  2015年   103篇
  2014年   149篇
  2013年   258篇
  2012年   165篇
  2011年   157篇
  2010年   139篇
  2009年   118篇
  2008年   115篇
  2007年   75篇
  2006年   44篇
  2005年   31篇
  2004年   26篇
  2003年   25篇
  2002年   18篇
  2001年   9篇
  2000年   6篇
  1999年   3篇
  1998年   2篇
  1997年   4篇
  1996年   1篇
  1995年   3篇
  1994年   2篇
  1993年   1篇
  1992年   1篇
  1990年   1篇
  1989年   1篇
  1988年   1篇
  1987年   1篇
  1985年   2篇
  1984年   1篇
  1983年   1篇
  1982年   4篇
  1981年   1篇
  1980年   1篇
  1979年   2篇
  1978年   1篇
排序方式: 共有2161条查询结果,搜索用时 31 毫秒
1.
A formal computation proving a new operator identity from known ones is, in principle, restricted by domains and codomains of linear operators involved, since not any two operators can be added or composed. Algebraically, identities can be modelled by noncommutative polynomials and such a formal computation proves that the polynomial corresponding to the new identity lies in the ideal generated by the polynomials corresponding to the known identities. In order to prove an operator identity, however, just proving membership of the polynomial in the ideal is not enough, since the ring of noncommutative polynomials ignores domains and codomains. We show that it suffices to additionally verify compatibility of this polynomial and of the generators of the ideal with the labelled quiver that encodes which polynomials can be realized as linear operators. Then, for every consistent representation of such a quiver in a linear category, there exists a computation in the category that proves the corresponding instance of the identity. Moreover, by assigning the same label to several edges of the quiver, the algebraic framework developed allows to model different versions of an operator by the same indeterminate in the noncommutative polynomials.  相似文献   
2.
3.
4.
5.
Journal of Thermal Analysis and Calorimetry - Effect of different chain extenders, silica nanoparticle loading, and using sol–gel method on the thermal properties of polyurethane (PU) hybrid...  相似文献   
6.
Journal of Thermal Analysis and Calorimetry - The purpose of this study is to numerically investigate flow field and turbulent heat transfer of hybrid nanofluid, water–DWCNT–TiO2 in a...  相似文献   
7.
8.
A mathematical method is presented for solving the Schr?dinger equation for a system of identical body forces. The N-body forces are more easily introduced and treated within the hyperspherical harmonics. The problem of the N-body potential has been used at the level of both classical and quantum mechanics. The hypercentral interacting potential is assumed to depend on the hyperradius x = (ξ12 + ξ22 + ⋯ + ξN−12)1/2 only, where ξ12,…,ξN−1 are Jacobi relative coordinates which are functions of N-particle relative positions r12,r23,…,rN1. The problem of the harmonic oscillator and the Coulomb-type potential has been widely studied in different contexts. Using the N-body potential V(x) = ax2 + bx − (c/x) as an example, and assuming an ansatz for the eigenfunction, an exact analytical solution of the Schr?dinger equation for an N-body system in three dimensions is obtained. This method is also applicable to some other types of potentials for N-identical interacting particles.  相似文献   
9.
Summary. A facile synthesis of quinoxaline derivatives catalyzed by KHSO4 in very high yields at room temperature is reported.  相似文献   
10.

A novel SBA-15-based fluorescent sensor, SBA-PI: mesoporous SBA-15 structure modified with iminostilbene groups, was designed, synthesized, and characterized by Fourier transform-infrared spectroscopy (FT-IR), ultraviolet–visible spectroscopy, field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), thermogravimetric analysis (TGA), low-angle X-ray diffraction techniques (low-angle XRD), and N2 adsorption–desorption techniques. The SBA-PI as a sensor with a selective behavior for detection of Cu2+ comprises iminostilbene carbonyl as the fluorophore group. The SBA-PI sensor displays an excellent fluorescence response in aqueous solutions and the fluorescence intensity quenches remarkably upon addition of Cu2+. Other common interfering ions even at high concentration ratio showed either no or very small changes in the fluorescence intensity of SBA-PI in the absence of Cu2+. A limit of detection of 8.7 × 10−9 M for Cu2+ indicated that this fluorescence sensor has a high sensitivity and selectivity toward the target copper (II) ion. The fabricated Cu2+ sensor was successfully applied for the determination of the Cu2+ in human blood samples without any significant interference. With the selective analysis of Cu2+ ions down to 0.9 nM in blood, the sensor is a promising and a novel detection candidate for Cu2+ and can be applied in the clinical laboratory. A reversibility and accuracy in the fluorescence behavior of the sensor was found in the presence of I¯ that was described as a masking agent for Cu2+.

Graphical abstract

  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号