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Fabio Cameli Prof. Dr. Joop H. ter Horst Dr. René R. E. Steendam Dr. Ir. Christos Xiouras Prof. Dr. Georgios D. Stefanidis 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(6):1344-1354
Herein, the pivotal role of secondary nucleation in a crystallization-enhanced deracemization process is reported. During this process, complete and rapid deracemization of chiral conglomerate crystals of an isoindolinone is attained through fast microwave-assisted temperature cycling. A parametric study of the main factors that affect the occurrence of secondary nucleation in this process, namely agitation rate, suspension density, and solute supersaturation, confirms that an enhanced stereoselective secondary nucleation rate maximizes the deracemization rate. Analysis of the system during a single temperature cycle showed that, although stereoselective particle production during the crystallization stage leads to enantiomeric enrichment, undesired kinetic dissolution of smaller particles of the preferred enantiomer occurs during the dissolution step. Therefore, secondary nucleation is crucial for the enhancement of deracemization through temperature cycles and as such should be considered in further design and optimization of this process, as well as in other temperature cycling processes commonly applied in particle engineering. 相似文献
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m‐Xylylene bismaleimide, Compimide ? ? Compimide® is a registered trademark.
MXBI (hereafter MXBI), was developed as a building block for formulating bismaleimide resins with improved processability. MXBI on its own, or in combination with 4,4′‐bismaleimidodiphenylmethane (Compimide MDAB, hereafter MDAB) and with 2,2′‐diallylbisphenol‐A as a co‐monomer, provides very low‐melting resin blends, which can be processed at temperatures around 60–80°C via RTM (Resin Transfer Moulding), VARIM (Vacuum Assisted Resin Infusion Moulding), prepregging, and wet filament winding (FW). Uncured and cured resin properties were evaluated. The mechanical property spectrum of the MXBI/MDAB/diallylbisphenol‐A system with varying MXBI/MDAB ratio shows almost equivalent contributions of MXBI and MDAB to the mechanical properties of a system. Higher MXBI proportions are responsible for lower resin viscosities and hence superior processability. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
MXBI (hereafter MXBI), was developed as a building block for formulating bismaleimide resins with improved processability. MXBI on its own, or in combination with 4,4′‐bismaleimidodiphenylmethane (Compimide MDAB, hereafter MDAB) and with 2,2′‐diallylbisphenol‐A as a co‐monomer, provides very low‐melting resin blends, which can be processed at temperatures around 60–80°C via RTM (Resin Transfer Moulding), VARIM (Vacuum Assisted Resin Infusion Moulding), prepregging, and wet filament winding (FW). Uncured and cured resin properties were evaluated. The mechanical property spectrum of the MXBI/MDAB/diallylbisphenol‐A system with varying MXBI/MDAB ratio shows almost equivalent contributions of MXBI and MDAB to the mechanical properties of a system. Higher MXBI proportions are responsible for lower resin viscosities and hence superior processability. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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Panagiotis Misaelides David Fellhauer Xavier Gaona Marcus Altmaier Horst Geckeis 《Journal of Radioanalytical and Nuclear Chemistry》2017,311(3):1665-1671
The 232Th-uptake ([Th(IV)]° = 9.7 × 10?5 M) from carbonate solutions ([CO 3 2 ]tot = 0.25 M, 9.0 < pHc < 10.8) by raw and HDTMA-modified HEU-type zeolitic-, chabazitic- and phillipsitic-tuffs was investigated. The strong uptake by the HDTMA-tuffs at pHc≈9 was assigned to the Th(CO3) 5 6? and ThOH(CO3) 4 5? predominance. The sorption coefficients (R d) decreased with increasing pHc indicating carbonate competition. Enhanced R d values for pHc > 10.5 are likely due to ThO2(am)-precipitation. The 237Np-uptake ([Np(V)]° = 2.6 × 10?5 M) from carbonate solutions ([CO 3 2 ]tot = 0.25 and 3.0 × 10?4 M) by raw and HDTMA-modified HEU-type zeolitic tuff and pulverized pure heulandite crystals was studied under Ar-atmosphere at 6 < pHc < 11. The R d values for both elements indicated the modified tuffs potential to remove tetravalent- and pentavalent actinides from environmental matrices. 相似文献
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A fully discrete Lagrangian scheme for numerical solution of the nonlinear fourth-order DLSS equation in one space dimension is analyzed. The discretization is based on the equation’s gradient flow structure in the \(L^2\)-Wasserstein metric. By construction, the discrete solutions are strictly positive and mass conserving. A further key property is that they dissipate both the Fisher information and the logarithmic entropy. Our main result is a proof of convergence of fully discrete to weak solutions in the limit of vanishing mesh size. Convergence is obtained for arbitrary nonnegative, possibly discontinuous initial data with finite entropy, without any CFL-type condition. The key estimates in the proof are derived from the dissipations of the two Lyapunov functionals. Numerical experiments illustrate the practicability of the scheme. 相似文献
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Stanislaw Urban Krzysztof Czuprynski Roman Dąbrowski Bo Gestblom Joanna Janik Horst Kresse 《Liquid crystals》2013,40(5):691-696
Results of the dielectric studies of nine members of the nBT (4-n-alkyl-4'-thiocyanatobiphenyl, n= 2-10) homologous series in the crystal E (E) and isotropic (I) phases are presented. The dependence of the static permittivity ?s in the isotropic phase, the longitudinal relaxation times τis and τ∥, and the activation enthalpies ΔH is and ΔH ∥ on the number of carbon atoms in the alkyl chain n are analysed. A considerable increase in the retardation factor g= τ∥/τis with decreasing n is observed. The results are compared with those obtained for similar two-ring homologous series. The parameters characterizing the molecular rotations around the short axis in the E phase (τ∥ and ΔH ∥) indicate a hardening of this solid-like phase with shortening of the alkyl chain. 相似文献
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Sibille Beerbaum Joachim Bergmann Horst Kehlen Margit T. Ratzsch 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(12):1445-1463
A determinant criterion for the critical state in solutions and mixtures of polydisperse polymers is established within the general framework of Gibbs theory. The treatment continues an earlier paper by considering more general Gibbs free energy relations: The function replacing the x-term in the classic Flory-Huggins equation is permitted to depend on a finite number of moments of the polymer distribution(s) so as to embrace most Gibbs free energy relations of practical use. The new criterion leads to a very large reduction of computer time and of needed storage capacity compared to the traditional Gibbs determinant criterion. Some relations known from the literature are shown to be special cases of the established new criterion. 相似文献
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